DMDO is known for its ability to perform Baeyer-Villiger oxidations, which involve the insertion of an oxygen atom between two carbon atoms. This can lead to the formation of lactones or other functional groups. Depending on the reaction conditions and substrate, this can be a useful transformation of 4-methylcoumarins.
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3,7-dihydroxy-4,8-dimethyl-2H-chromen-2-one
Propanedioic acid, [(dimethylphenylsilyl)methylene]-, diethyl ester
4-butyl-4-hydroxycyclohexanon
2-Oxepanone, 7-(2-propenyl)-
Cyclobutanone, 2-methyl-2-(4-methylphenyl)-, (S)-
