The palladium catalyst coordinates with the Fu-Phos ligand to form a chiral complex. The allylic substrate binds to the palladium catalyst. The nucleophile attacks the allylic carbon, displacing the leaving group. The chiral environment provided by the Fu-Phos ligand directs the nucleophile to attack the allylic carbon with high enantioselectivity, resulting in the formation of a chiral product.
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dimethyl (1R,2E)-(1-phenylbut-2-en-1-yl)malonate
Cyclohexanol, 5-methyl-2-(1-methylethyl)-, phenylcarbamate
(E)-hex-1-ene-1,6-diyldibenzene
N-benzylidene-bis(4-methoxy-3,5-di-tert-butylphenyl)methylamine
(2S,3R)-2,6,6-Trimethyl-5-oxo-3-phenyl-heptanoic acid tert-butyl ester
4-butyl-4-hydroxycyclohexanon
Pd2Br2(P(C4H9)(C(CH3)3)2)2(COC6H4CF3)2
ethyl (2R,3S)-3-(2,4-dinitrophenyl)-2-hydroxy-3-(4-methylphenylsulfonamido)propanoate
4-methyl-4-(3-methyl-2-butenyl)-2-phenyl-2-oxazolin-5-one
1-methyl-3-(2,4,5-triphenyl-cyclopenta-1,4-dienyl)-1H-indole
C27H45N3O2S
bis[2-(tert-butylsulfonyl)phenyl] diselenide
(5S,6R)-6-(N-benzylacetamido)-2,2-dimethyl-1,3-dioxepan-5-yl acetate.
2-(diphenylphosphonoyl)-2-[(1S,2S,3S,5S)-5-(diphenylphosphonoyl)-2,3-dimethoxycyclopentyl]-1-phenylethanol
Palladium, chloro(trichlorostannyl)bis(triphenylphosphine)-
3-(3,5-dimethoxybenzoyl)benzoic acid
Benzaldehyde, 2-(1,1-dimethylethyl)-3-hydroxy-
Benzene, 1,3-octadienyl-, (Z,E)-
C24H34O5Si
N-(4-methylphenyl)sulfonyl-2-(2(Z)-buten-1-yloxy)ethylamine
[(2-tert-butyl-6-(4-fluorophenyl)pyridine(-2H))Pt(PPh3)]
(E)-3-(m-tolyl)allyl acetate
(+)-(S)-allyl-p-toluenesulphinamide
4(2H)-Benzofuranone, 3,5,6,7-tetrahydro-2,6,6-trimethyl-2-phenyl-
2,6-di-tert-butyl-4-methylphenyl (cyclohexen-3-yl)acetate
(S)-3-(4-chlorophenyl)-4-nitrobutyraldehyde
2-Propenal, 3-(4-acetylphenyl)-
ethyl 2-oxo-4-(4-bromophenyl)-3-buten-1-oate
2-chloro-4-(4-tosylpiperazin-1-yl)pyrimidine
[Ru(H)2(N2)2(PCy3)2]
(Z)-1-(3-cyclohexenyl)-1-hexene
2-(1-tosylpiperidin-4-yl)pyridine
trans-bis(tricyclohexylphosphine)(2-methylphenyl)nickel(II) chloride
(E)-1-phenylpropan-1-one O-acetyl oxime
2,4-Pentanedione, 3-[(1S)-1,3-diphenyl-2-propenyl]-
4-(isochroman-1-yl)benzonitrile
4-((2-hydroxyphenyl)thio)benzonitrile
Ethanol, 2-[(1-methylethyl)(phenylmethyl)amino]-
5-[ISOCYANO-(TOLUENE-4-SULFONYL)-METHYL]-BENZO[1,3]DIOXOLE
(+)-2-methoxymethyl-1-(2-methyl-1-n-butyl-pentylideneamino)-pyrrolidine
3-[(TriMethylsilyl)ethynyl]aniline
(+)-2-[2-[(2R,5R)-2,5-diphenylpyrrolidin-1-yl]ethyl]pyridine
3-phenyl-2-(trimethylsilyl)-1H-indole
dimethyl-1,7 indoline
p-methoxybenzyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside
(E)-1,3-dimethyl-3-styrylindolin-2-one
