The Diels-Alder reaction is a powerful tool for constructing decalin rings with high stereoselectivity. By carefully choosing the diene and dienophile, as well as reaction conditions, you can control the stereochemistry of the newly formed stereocenters. For example, using chiral catalysts or auxiliaries can enable control over the absolute configuration.
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(2R,3S)-3-[(p-tolyl)sulfenyl]-7-oxabicyclo[2.2.1]hept-5-ene-2-carboxamide
(3aR,4R,7S,7aS)-2-phenyl-3a,4,7,7a-tetrahydro-1H-4,7-methanoisoindole-1,3(2H)-dione
2-benzyl-2H,6H-pyrrolo[3,4-e]indole-1,3-dione
Benzene, [(2-nitro-1-heptenyl)thio]-, (Z)-
1,3-dimethyl-7-phenyl-1,2,3,4,6,7-hexahydrofuro<3',2':5,6>pyrido<2,3-d>pyrimidine-2,4-dione
3-(2-PYRIDYL)-5,6-DIPHENYL-1,2,4-TRIAZINE
4-METHYL-2-PHENYL-1,3-THIAZOLE-5-CARBALDEHYDE
4-AMINO-2-ISOPROPYL-5-METHYLPHENOL
