Stereoselective access to polyfunctionalized decalins

DOI: 10.1016/S0040-4039(00)78252-9

Source and publish data:

Tetrahedron Letters p. 6485 - 6488 (1994)

Update date:2022-07-30

Topics: Asymmetric synthesis Organocatalysis Computational Chemistry Chiral Pool Synthesis Dynamic Kinetic Resolution Ring-Closing Metathesis Diels-Alder Reactions

Authors:

Poirel, Celine

Renard, Pierre-Yves

Lallemand, Jean-Yves

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Article abstract of DOI:10.1016/S0040-4039(00)78252-9

As a model of a stereoselective approach to ajugareptansin 1, a versatile and straightforward access to polyfunctionalized cis or trans decalins is presented. It is based on a Lewis acid-mediated addition of furan to the unsaturated ketoester 3 followed b

Full text of DOI:10.1016/S0040-4039(00)78252-9

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Product name:3,3,4-Trimethyl-6-oxo-cyclohex-1-enecarboxylic acid methyl ester

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