Enantioselective synthesis involves the creation of a specific enantiomer of a molecule with high selectivity, avoiding the formation of its mirror-image enantiomer. Total synthesis means the complete synthesis of a complex organic molecule, typically a natural product, from simple starting materials. C-2′′′ epimers refer to isomers of a molecule that differ in the stereochemistry at the carbon atom labeled as C-2′′′.
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(R)-ethyl 2-benzyl-4-methyl-3-oxopentanoate
(1R,2R,4aS,5S,8aR)-2-[(5E,7E,9E)-9-(tert-Butyl-diphenyl-silanyloxymethyl)-undeca-5,7,9-trienyl]-5-methoxymethoxy-1-methyl-4-trimethylsilanyl-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid allyl ester
