Enediyne

a class of highly potent antitumor antibiotics that are known for their ability to cause DNA cleavage

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Enediyne antitumor antibiotic maduropeptin biosynthesis featuring a C-methyltransferase that acts on a COA-Tethered aromatic substrate
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Intramolecular 1,3-dipolar nitrone cycloaddition route to bicyclic fused enediyne
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Regioselectivity Yield Chromatography Antitumor Dipolarophile Protecting group Retrosynthetic analysis Intramolecular Reaction Stereoselectivity Cycloaddition Catalysis Substrate Reaction Optimization Kinetic Control Thermodynamic Control 1,3-Dipolar Cycloaddition Ring Strain Tethered Biosynthesis Antibiotic Aromatic Transition state Nitrone Spectroscopic analysis (NMR, IR, MS)

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