The term "radical-polar crossover" refers to the fact that this reaction proceeds through a combination of radical and polar mechanisms. This means that both radical species (with unpaired electrons) and polar species (with charged or partially charged atoms) are involved in the reaction.
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N-([1,1'-biphenyl]-4-yl)-1'-(methylsulfonyl)spiro[cyclohexane-1,3'-indoline]-4-carboxamide
Toluene
4-methyl-N-(2,2,5-trimethylhex-4-en-1-yl)benzenesulfonamide
