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Selectivity Control

Careful design of the reaction conditions and choice of ligands can help control the stereochemistry of the reaction and guide the formation of desired stereoisomers.

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Articles of Selectivity Control

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Elemental analysis Asymmetric synthesis Regioselectivity Diastereoselectivity Green chemistry Solid-phase synthesis Lewis acid Microwave-assisted synthesis Distillation Catalyst Terminal alkynes Thin-layer chromatography (TLC) Ligand Molecular docking Stereochemistry Lead compound Enantioselectivity Steric hindrance Enantiomeric excess (ee) Recrystallization Mass spectrometry (MS) Nucleophilic substitution Differential scanning calorimetry (DSC) Atom economy Pharmacophore Cyclization Kinetics High-performance liquid chromatography (HPLC) Infrared spectroscopy (IR) Electrochemistry Deprotection Filtration Solvent polarity Protecting group Dimerization Nuclear Magnetic Resonance (NMR) Resolution X-ray crystallography Leaving group Density functional theory (DFT) Enzyme inhibition High-Throughput Screening Workup and Purification Scale-up Steric Effects Oxidative Addition Chemoselectivity Nucleophilic Attack Reaction Mechanism Electronic effects