Highly congested β-diketones are characterized by the presence of multiple bulky substituents around the central ketone group. These bulky groups create steric congestion, which can influence the reactivity and properties of the compound. Steric congestion can lead to unique reactivity patterns and can be useful in controlling the selectivity of reactions.
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3,5-heptanedione, 2,2,6,6-tetramethyl-4-tricyclo[3.3.1.1~3,7~]dec-1-yl-
Stannane, tributyl(phenylseleno)-
2-Cyano-3-methyl-3-(3-methyl-2-oxo-cyclohexyl)-butyric acid ethyl ester
