Reactions of copper(II) β-diketonates under free radical conditions. Preparation of highly congested β-diketones

DOI: 10.1016/S0040-4020(01)81955-4

Source and publish data:

Tetrahedron p. 8031 - 8042 (1991)

Update date:2022-08-03

Topics: Radical reactions Generation of Radicals Steric Congestion Synthetic Strategies

Authors:

Lloris, Maria E.

Galvez, Nicanor

Marquet, Jorge

Moreno-Manas, Marcial

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Article abstract of DOI:10.1016/S0040-4020(01)81955-4

Copper(II) β-diketonates react with alkyl bromides under free radical conditions to give highly congested β-diketones such as 3-(1-adamantyl)-3-alkylpentane-2,4-diones. Another typical free radical reagent: benzoyl peroxide, reacts also functionalizing the intercarbonyl positions.

Full text of DOI:10.1016/S0040-4020(01)81955-4

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