Tetrahedron p. 8031 - 8042 (1991)
Update date:2022-08-03
Topics: Radical reactions Generation of Radicals Steric Congestion Synthetic Strategies
Lloris, Maria E.
Galvez, Nicanor
Marquet, Jorge
Moreno-Manas, Marcial
Copper(II) β-diketonates react with alkyl bromides under free radical conditions to give highly congested β-diketones such as 3-(1-adamantyl)-3-alkylpentane-2,4-diones. Another typical free radical reagent: benzoyl peroxide, reacts also functionalizing the intercarbonyl positions.
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