Transition metal-catalyzed processes can also be used for radical cyclizations. For example, palladium or copper catalysts can be employed to activate arylboronic acids, facilitating the formation of aryl radicals that then undergo intramolecular cyclization reactions.
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(2-((2-methylallyl)oxy)phenyl)boronic acid
dimethyl (S)-3-formyl-4-methylene-3-phenylcyclopentane-1,1-dicarboxylate
3-(1H-indol-3-yl)-2-methyl-3-phenylpropan-1-ol
6-hydroxy-4-(4-methoxyphenyl)-2-(2-pyridil)pyridine
(2R,5R)-1-(tert-butoxycarbonyl)-5-[(S)-methoxycarbonyl(4-bromophenyl)methyl]-2-[tert-butyldiphenylsilyloxymethyl]pyrrolidine
1-(tert-butyl)-4-(methoxymethylene)cyclohexane
3a,4-dihydro-6-(4-methylphenyl)-1H-cyclopenta[c]furan-5(3H)-one
(2-methoxyphenyl)-n-octylsilane
(R)-4,4,5,5-tetramethyl-2-(1-phenylpropyl)-1,3,2-dioxaborolane
3-(1H-indol-3-yl)-2-methyl-3-phenylpropan-1-ol
1’-(4-(4-propylphenyl)-[1,2,3]-triazol-1-yl)-2’,3’,4’,6’-tetra-O-acetyl-β-D-glucopyranose
9-Oxa-2,4-diaza-10-siladodeca-2,6-dienoic acid, 3-[[(1,1-dimethylethoxy)carbonyl]amino]-7,11,11-trimethyl-10,10-diphen yl-, 1,1-dimethylethyl ester, (6E)-
2,6-di-tert-butyl-4-methylphenyl (cyclohexen-3-yl)acetate
1-(4-hydroxy-3-methoxyphenyl)-2-{4-[(E)-3-hydroxy-1-propenyl]-2-methoxyphenoxy}-1,3-propanediol
(S)-2-((S,E)-1,3-diphenylallyl)cyclopentanone
(+)-(S)-allyl-p-toluenesulphinamide
di-tert-butyl 1-(4-(tosyloxy)phenyl)hydrazine-1,2-dicarboxylate
3-(3,5-dimethylphenyl)quinoline
(+)-2-methoxymethyl-1-(2-methyl-1-n-butyl-pentylideneamino)-pyrrolidine
(2Z,3Z)-3-ethoxy-1,4-diphenyl-2-(phenylimino)but-3-en-1-one
