Rhodium(II) Acetate Catalysed Hydrosilylation of Enamides and N-Vinylureas leading to 1-(Trialkylsilyl)alkylamine Derivatives

DOI: 10.1039/c39940002143

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 2143 - 2144 (1994)

Update date:2022-07-30

Topics: Column chromatography Catalytic Reaction Substrate Scope Hydrosilylation Transition Metal Catalysis Enamides Mechanistic study NMR spectroscopy (1H/13C) Schlenk technique Solvent Optimization GC-MS (Gas Chromatography-Mass Spectrometry) Inert Atmosphere (N?/Ar)

Authors:

Murai, Toshiaki

Oda, Tatsuaki

Kimura, Fumihiro

Onishi, Hiroshi

Kanda, Takahiro

Kato, Shinzi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39940002143

The catalysed hydrosilylation of enamides and N-vinylureas with dimethylphenylsilane proceeds smoothly in a regio- and site-selective manner to give 1-(trialkylsilyl)alkylamine derivatives in good to high yields.

Full text of DOI:10.1039/c39940002143

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Ethanol, 1-(dimethylphenylsilyl)-, acetate

Cas No:143370-45-0

R&D Labs maybe for 143370-45-0

Shanghai Rainbow Chemistry Co., Ltd.

Contact:+86-21-64968086-5815/5812

Address:3rd floor, Building 7, 251 Faladi Road, Zhangjiang Hi-Tech Park, Pudong District, Shanghai, P.R. China
Shanghai KFSL Pharmaceutical Technology Co.,Ltd.

Contact:+86-21-39971718

Address:859 jiadingchengliu shanghai
MENGNA

Contact:18698110882

Address:1303 No2 building,LuoMa Garden,YongAn Road,Hexi District,Tianjin city
Xiamen Huasing Chemicals Co.Ltd.

Contact:0086-592-6228397

Address:NO.24, Xinglin North 2nd Road,Jimei district
Feis International Trade Co,. Ltd

Contact:13961823444-18235944442

Address:Wuxi jiangsu

Relevant to this article

Wingtip substituents tailor the catalytic activity of ruthenium triazolylidene complexes in base-free alcohol oxidation

Doi:10.1039/c3dt32939a
(2013)
Microwave heating in conjunction with UV irradiation: A tool for the oxidation of 1,4-dihydropyridines to pyridines

Doi:10.1071/CH08414
(2009)
The synthesis of chiral isotetronic acids with amphiphilic imidazole/pyrrolidine catalysts assembled in oil-in-water emulsion droplets

Doi:10.1002/anie.201206438
(2012)
A Boron Activating Effect Enables Cobalt-Catalyzed Asymmetric Hydrogenation of Sterically Hindered Alkenes

Doi:10.1021/jacs.9b12214
(2020)
Synthesis of novel 2,4-disubstituted 3H-pyrido[3,2-e][1,4]diazepin-5-ones and 2,4-disubstituted 3H-pyrido[2,3-e][1,4]diazepin-5-ones derivatives via regioselective thionation and nucleophilic substitutions reactions

Doi:10.1016/j.tet.2013.04.089
(2013)
Nucleophilic addition to coordinated polyenes: A novel method for the liberation of the trimethylenemethane ligand involving C-C bond formation

Doi:10.1016/S0040-4039(00)74664-8
(1992)

Article Doi