Rhodium(II) Acetate Catalysed Hydrosilylation of Enamides and N-Vinylureas leading to 1-(Trialkylsilyl)alkylamine Derivatives

DOI: 10.1039/c39940002143

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 2143 - 2144 (1994)

Update date:2022-07-30

Topics: Column chromatography Catalytic Reaction Substrate Scope Hydrosilylation Transition Metal Catalysis Enamides Mechanistic study NMR spectroscopy (1H/13C) Schlenk technique Solvent Optimization GC-MS (Gas Chromatography-Mass Spectrometry) Inert Atmosphere (N?/Ar)

Authors:

Murai, Toshiaki

Oda, Tatsuaki

Kimura, Fumihiro

Onishi, Hiroshi

Kanda, Takahiro

Kato, Shinzi

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Article abstract of DOI:10.1039/c39940002143

The catalysed hydrosilylation of enamides and N-vinylureas with dimethylphenylsilane proceeds smoothly in a regio- and site-selective manner to give 1-(trialkylsilyl)alkylamine derivatives in good to high yields.

Full text of DOI:10.1039/c39940002143

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