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Uranyl acetate dihydrate

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  • Name Uranyl acetate dihydrate
  • EINECS208-767-5
  • CAS No. 541-09-3
  • Densityg/cm3
  • PSA86.74000
  • LogP-0.21000
  • SolubilityN/A
  • Melting Point110°C
  • FormulaC4H6 O6 U
  • Boiling Point117.1°Cat760mmHg
  • Molecular Weight424.19
  • Flash Point40°C
  • Transport InformationN/A
  • AppearanceN/A
  • SafetyPoison by intraperitoneal route. A radioactive material. See also URANIUM.
  • Risk CodesN/A
  • Molecular Structure
    Molecular Structure of 541-09-3 (URANYL ACETATE)
  • Hazard SymbolsN/A
  • SynonymsN/A

Uranyl acetate dihydrate Synthetic route

1078691-95-8

(+)-D-glucosamine hydrochloride

541-09-3

uranyl acetate

534-17-8

caesium carbonate

90-02-8

salicylaldehyde

C39H45N3O25U3*2CsH

Conditions
ConditionsYield
Stage #1: uranyl acetate; salicylaldehyde In methanol at 20℃; for 2h;
Stage #2: (+)-D-glucosamine hydrochloride In methanol; water at 20℃; for 1.5h;
Stage #3: caesium carbonate In methanol; water at 20℃; for 18.5h;
91%
541-09-3

uranyl acetate

95-54-5

1,2-diamino-benzene

708-06-5

2-hydroxynaphthalene-1-carbaldehyde

C28H20N2O5U

Conditions
ConditionsYield
Stage #1: 1,2-diamino-benzene; 2-hydroxynaphthalene-1-carbaldehyde In methanol Reflux;
Stage #2: uranyl acetate at 65℃; for 5h; Reflux;
Stage #3: water
85%
67-56-1

methanol

541-09-3

uranyl acetate

99-56-9

4-Nitrophenylene-1,2-diamine

708-06-5

2-hydroxynaphthalene-1-carbaldehyde

C29H21N3O7U

Conditions
ConditionsYield
Stage #1: methanol; 4-Nitrophenylene-1,2-diamine; 2-hydroxynaphthalene-1-carbaldehyde Reflux;
Stage #2: uranyl acetate at 65℃; for 5h; Reflux;
85%
67-56-1

methanol

541-09-3

uranyl acetate

90-02-8

salicylaldehyde

99-56-9

4-Nitrophenylene-1,2-diamine

C21H17N3O7U

Conditions
ConditionsYield
Stage #1: methanol; salicylaldehyde; 4-Nitrophenylene-1,2-diamine Reflux;
Stage #2: uranyl acetate at 65℃; for 5h; Reflux;
75%
67-56-1

methanol

541-09-3

uranyl acetate

97-51-8

5-Nitrosalicylaldehyde

95-54-5

1,2-diamino-benzene

C21H16N4O9U

Conditions
ConditionsYield
Stage #1: methanol; 5-Nitrosalicylaldehyde; 1,2-diamino-benzene Reflux;
Stage #2: uranyl acetate at 65℃; for 5h; Reflux;
70%
67-56-1

methanol

541-09-3

uranyl acetate

97-51-8

5-Nitrosalicylaldehyde

99-56-9

4-Nitrophenylene-1,2-diamine

C21H15N5O11U

Conditions
ConditionsYield
Stage #1: methanol; 5-Nitrosalicylaldehyde; 4-Nitrophenylene-1,2-diamine Reflux;
Stage #2: uranyl acetate at 65℃; for 5h; Reflux;
60%
6967-98-2

1-(D-glucopyranosyl-2'-deoxy-2'-iminomethyl)-2-hydroxybenzene

541-09-3

uranyl acetate

534-17-8

caesium carbonate

C39H45N3O25U3*2CsH

Conditions
ConditionsYield
Stage #1: 1-(D-glucopyranosyl-2'-deoxy-2'-iminomethyl)-2-hydroxybenzene; uranyl acetate In methanol at 20℃; for 2h; Inert atmosphere;
Stage #2: caesium carbonate In methanol Inert atmosphere;
57%

N-(4-((Z)-(6-oxo-2-thioxo-1,2,3,4-tetrahydro-6l5-pyrimidin-5-yl)diazenyl)phenyl)-4-((E)-(6-oxo-2-thioxo-1,2,5,6-tetrahydropyrimidin-5-yl)diazenyl)benzamide

541-09-3

uranyl acetate

C29H25N9O17S2U3*H2O

Conditions
ConditionsYield
With ammonia

Uranyl acetate dihydrate Chemical Properties

Chemistry informtion about Uranium Oxyacetate (CAS NO.541-09-3) is:
IUPAC Name: Acetic Acid; Dioxouranium
Synonyms: Uranylacetate,A.C.S.Grade ; Uranium, Bis(Acetato-.Kappa.O)Dioxo-, (T-4)- ; Uranium,Bis(Aceto)Dioxo- ; Uranylethanoate ; Uranyl Acetate, Anhydrous ; Uranium, Bis(Acetato-O)Dioxo- ; Uranyl Acetate: (Uranium Oxyacetate) ; Bis(Acetato)Dioxo-Uraniu
Product Categories: Organic-metal salt
MF: C4H8O6U
MW: 388.12
EINECS: 208-767-5 
Density: 2.89 g / cm3
Flash Point: 40 °C
Boiling Point: 117.1 °C at 760 mmHg Vapour Pressure: 13.9 mmHg at 25°C 
Enthalpy of Vaporization: 23.7 kJ/mol
Following is the molecular structure of Uranium Oxyacetate (CAS NO.541-09-3) is:

Uranyl acetate dihydrate Uses

Uranium Oxyacetate (CAS NO.541-09-3) is used as a negative stain in electron microscopy. In fact, most procedures in electron microscopy for biology require the use of uranyl acetate. In the negative staining method 1 or 2% aqueous solution is normally being used. One of the most advantage of the type of staining is its simplicity, one can examine the sample within a few minutes after staining. Some biological samples may be adversely affected by uranyl acetate staining and, in these cases, a low voltage electron microscopy technique may be more suitable due to the improved resolution of low atomic number materials. 1% and 2% Uranyl Acetate solutions are used as an indicator, and a titrant in stronger concentrations in analytical chemistry, as it forms an insoluble salt with sodium (the vast majority of sodium salts are water-soluble). Uranyl Acetate solutions show evidence of being sensitive to light, especially UV and will precipitate if exposed. Uranyl Acetate is also used in a standard test—American Association of State Highway and Transportation Officials (AASHTO) Designation T 299—for alkali-silica reactivity in aggregates (crushed stone or gravel) being considered for use in cement concrete.

Uranyl acetate dihydrate Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 24mg/kg (24mg/kg)   Journal of Toxicology and Environmental Health. Vol. 11, Pg. 237, 1983.

Uranyl acetate dihydrate Consensus Reports

Reported in EPA TSCA Inventory.

Uranyl acetate dihydrate Safety Profile

Poison by intraperitoneal route. A radioactive material. See also URANIUM
RIDADR: 2912
HazardClass: 7
PackingGroup: III

Uranyl acetate dihydrate Standards and Recommendations

OSHA PEL: TWA 0.05 mg(U)/m3
ACGIH TLV: TWA 0.2 mg(U)/m3

Uranyl acetate dihydrate Specification

Uranium Oxyacetate (CAS NO.541-09-3) is a yellow crystals with a slight odor of vinegar. It can soluble in water and reacting to give a milky solution. The reaction is not hazardous. It reacts weakly as an acid. Usually does not react as either oxidizing agents or reducing agents but such behavior is not impossible. May catalyze organic reactions. Inhalation of dust may irritate nose and throat. Contact with eyes causes irritation.

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