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108-31-6

Basic Information
CAS No.: 108-31-6
Name: Maleic anhydride
Article Data: 425
Molecular Structure:
Molecular Structure of 108-31-6 (Maleic anhydride)
Formula: C2H2(CO)2O
Molecular Weight: 98.0581
Synonyms: 2,5-Furandione;Nourymix MA 901;furan-2,5-dione;Dihydro-2,5-dioxofuran;BM 10;Maleic acid anhydride;Maleic Anhydride in Briquettes;cis-Butenedioic anhydride;Toxilic anhydride;
EINECS: 203-571-6
Density: 1.484 g/cm3
Melting Point: 52.8 °C, 326 K, 127 °F
Boiling Point: 202 °C, 475 K, 396 °F
Flash Point: 218°F
Solubility: reacts with water
Appearance: white crystals
Hazard Symbols: CorrosiveC
Risk Codes: 22-34-42/43
Safety: 22-26-36/37/39-45
Transport Information: UN 2215 8/PG 3
PSA: 43.37000
LogP: -0.37400
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    Synonyms: 2,5-Furandione CAS No.: 108-31-6 Molecular Formula: C4H2O3 Specification: Assay(as C4H2O3), %≥ 99.5 Molten Color/Hazen (Pt-Co),≤25 Crystallizing Point, °C≥52.5 Residue on Ignition, %≤0.005 Iron Content (as Fe), (ug/g)&le

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  • Maleic anhydride

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    108-31-6

    Maleic anhydride

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    Name Maleic anhydride Synonyms 2,5-Furandione; MA Molecular Structure Molecular Formula C4

    Hangzhou Jinlan Pharm-Drugs Technology Co.,Ltd is located in Hangzhou, Zhejiang Province. Neighboring Ningbo port, Shanghai port, Hangzhou Xiaoshan Int’l Airport and Shanghai Pudon

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  • Maleic anhydride

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    108-31-6

    Maleic anhydride

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    1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highl

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  • Maleic anhydride manufacture

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    Maleic anhydride manufacture

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    Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketing of chemicals. We have earned ourselves a good reputation at home an

    Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketi

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Consensus Reports

Community Right-To-Know List. Reported in EPA TSCA Inventory.

Standards and Recommendations

OSHA PEL: TWA 0.25 ppm
ACGIH TLV: TWA 0.1 ppm (skin, sensitizer); Not Classifiable as a Human Carcinogen
DFG MAK: 0.1 ppm (0.41 mg/m3)
DOT Classification:  8; Label: Corrosive

Analytical Methods

For occupational chemical analysis use OSHA: #25 or NIOSH: Maleic Anhydride, P&CAM 302.

Specification

Maleic anhydride, with the CAS registry number 108-31-6, is a colourless or white solid with an acrid odour. Its IUPAC name is called furan-2,5-dione. This chemical is an organic compound with the formula C2H2(CO)2O. Its EINECS registry number is 203-571-6. The substance is stable which is combustible, but incompatible with water, strong oxidizing agents, alkali metals, strong bases, amines, most common metals, polymerization catalysts and accelerators. You should keep it in a tightly closed container and store it in a cool, dry, ventilated area. In addition, Maleic anhydride should be protected against physical damage, and isolated from incompatible substances.

Properties: Maleic anhydride reacts slowly with water to form maleic acid and heat. When released into the air, Maleic anhydride is expected to exist in the aerosol phase with a short half-life. The substance is incompatible with alkali metals and alkaline earth metals. Maleic anhydride is a potent dienophile in Diels-Alder reactions. It is also a ligand for low-valent metal complexes, examples being Pt(PPh3)2(MA) and Fe(CO)4(MA).

In addition, Maleic anhydride dimerizes in a photochemical reaction to form cyclobutane tetracarboxylic dianhydride (CBTA). And it will react violently with bases which contact with strong oxidizers may cause fires and explosions. Maleic anhydride hydrolyzes to form maleic acid. With alcohols, the half-ester is generated, e.g., cis-HOOC–CH=CH–COOCH3.

Maleic anhydride undergoes violent exothermic decomposition reactions, in the presence of strong bases, alkali metals, aliphatic amines and aromatic amines at temperatures above 150 °C, to form carbon dioxide. Maleic anhydride undergoes a potentially explosive exothermic Diels-Alder reaction with 1-methylsilacyclopenta-2,4-diene at 150 °C.

Preparation: There are several mehods of producing Maleic anhydride, such as oxidation of benzene, oxidation of butene and oxidation of butane. Nowadays, oxidation of benzene is commonly used to manufacture Maleic anhydride, which use benzene as the raw material. And via catalytic oxidation, you can gain the end product. The reaction temperature is 365 °C.

C6H6 + 9/2 O2 → C2H2(CO)2O + 2 H2O + 2 CO2

Maleic anhydride was traditionally manufactured by the oxidation of benzene or other aromatic compounds. However, you can gain it use n-butane as a feedstock nowadays, the reaction equation is as the following:

2 CH3CH2CH2CH3 + 7 O2 → 2 C2H2(CO)2O + 8 H2O

Uses: Maleic anhydride can be used to prepare other chemicals, such as 1,4-butanediol, γ-butyrolactone, tetrahydrofuran, succinic acid, alkyd resin and UPR, and in medicine and pesticide. This compound is also used in the production of polyimides and as an alignment film for liquid crystal displays. It can also be used in organic synthesis, as intermediates in synthetic fiber and as collector in metal ore-dressing industry.

When you are using Maleic anhydride, you should be very cautious about it. This chemical is corrosive and harmful if swallowed. It can cause burns and cause sensitisation by inhalation and skin contact. You must not breathe its dust. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact or use it, you need wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell seek medical advice immediately.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: C1=CC(=O)OC1=O
(2)InChI: InChI=1S/C4H2O3/c5-3-1-2-4(6)7-3/h1-2H
(3)InChIKey: FPYJFEHAWHCUMM-UHFFFAOYSA-N

Toxicity of Maleic anhydride:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LD50 oral 390mg/kg (390mg/kg)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 79, 1982.
guinea pig LD50 skin > 20gm/kg (20000mg/kg)   Interagency Collaborative Group on Environmental Carcinogenesis, National Cancer Institute, Memorandum, June 17, 1974Vol. 17JUN1974,
mouse LD50 oral 465mg/kg (465mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 13(4), Pg. 42, 1969.
rabbit LD50 oral 875mg/kg (875mg/kg)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 79, 1982.
rabbit LD50 skin 2620mg/kg (2620mg/kg)   Toxicology and Applied Pharmacology. Vol. 42, Pg. 417, 1977.
rat LD50 intraperitoneal 97mg/kg (97mg/kg)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 79, 1982.
rat LD50 oral 400mg/kg (400mg/kg)   Interagency Collaborative Group on Environmental Carcinogenesis, National Cancer Institute, Memorandum, June 17, 1974Vol. 17JUN1974,