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CAS No.: | 1086-00-6 |
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Name: | 1-CHLOROMETHYLPYRENE |
Article Data: | 25 |
Molecular Structure: | |
Formula: | C17H11 Cl |
Molecular Weight: | 250.727 |
Synonyms: | 1-Chloromethylpyrene;1-Pyrenylmethyl chloride; 3-(Chloromethyl)pyrene; NSC 133487 |
Density: | 1.321g/cm3 |
Boiling Point: | 434.1°Cat760mmHg |
Flash Point: | 201.2°C |
PSA: | 0.00000 |
LogP: | 5.32280 |
1-pyrenemethanol
1-chloromethylpyrene
Conditions | Yield |
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With thionyl chloride In toluene for 12h; Heating; | 100% |
With hydrogenchloride; sodium sulfate In toluene for 5h; | 97% |
With thionyl chloride In benzene Ambient temperature; | 96% |
Conditions | Yield |
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Multi-step reaction with 2 steps 1: NaBH4 / CHCl3; ethanol 2: SOCl2 / pyridine; diisopropyl ether View Scheme | |
Multi-step reaction with 2 steps 1: 86 percent / NaBH4 / ethanol / 6 h / Ambient temperature 2: 96 percent / SOCl2 / benzene / Ambient temperature View Scheme | |
Multi-step reaction with 2 steps 1: NaBH4 2: 85 percent / PCl3 View Scheme |
(2-nitrophenyl)(pyren-1-ylmethyl)selane
A
1-pyrenemethanol
B
1-chloromethylpyrene
Conditions | Yield |
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With sodium hypochlorite In chloroform-d1; water |
(2-nitrophenyl)(pyren-1-ylmethyl)selane
1-chloromethylpyrene
Conditions | Yield |
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With sodium hypochlorite; tetrabutyl-ammonium chloride In chloroform-d1; water |
Conditions | Yield |
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Multi-step reaction with 2 steps 1.1: sodium tetrahydroborate / methanol / Inert atmosphere 1.2: 20 h / 20 °C / Inert atmosphere 2.1: sodium hypochlorite / chloroform-d1; water View Scheme |
Conditions | Yield |
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Multi-step reaction with 2 steps 1.1: sodium tetrahydroborate / methanol / Inert atmosphere 1.2: 20 h / 20 °C / Inert atmosphere 2.1: sodium hypochlorite; tetrabutyl-ammonium chloride / chloroform-d1; water View Scheme |
1-chloromethylpyrene
phosphoric acid dibenzyl ester
dibenzyl pyren-1-ylmethyl phosphate
Conditions | Yield |
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With silver(l) oxide In acetonitrile at 20℃; for 6h; | 99% |
Conditions | Yield |
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With potassium fluoride In N,N-dimethyl-formamide at 20℃; | 99% |
Conditions | Yield |
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With potassium fluoride In N,N-dimethyl-formamide at 20℃; | 99% |
1-chloromethylpyrene
methyl 3-hydroxy-5-hexadecoxy benzoate
methyl 3-hexadecoxy-5-pyrenemethoxyl benzoate
Conditions | Yield |
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With 18-crown-6 ether; potassium carbonate In tetrahydrofuran; acetonitrile for 20h; Heating; | 98% |