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11076-19-0

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Basic Information
CAS No.: 11076-19-0
Name: BONGKREKIC ACID
Article Data: 8
Molecular Structure:
Molecular Structure of 11076-19-0 (BONGKREKIC ACID)
Formula: C28H38 O7
Molecular Weight: 486.606
Synonyms: 2,4,8,10,14,18,20-Docosaheptaenedioicacid, 20-(carboxymethyl)-6-methoxy-2,5,17-trimethyl-,[R-[R*,S*-(E,Z,Z,E,E,Z,E)]]-; Bongkrekic acid (6CI,8CI)
Density: 1.114g/cm3
Melting Point: 50-60°
Boiling Point: 715.1°Cat760mmHg
Flash Point: 231°C
Safety:
WGK Germany -
PSA: 121.13000
LogP: 5.88560
Related products
Synthetic route

(6R,17S)-bis(methoxymethyl) 20-(2-hydroxyethyl)-6-methoxy-2,5,17-trimethyldocosa-2,4,8,10,14,18,20-heptaenedioate

11076-19-0

bongkrekic acid

Conditions
ConditionsYield
With hydrogenchloride; water In tetrahydrofuran at 0 - 20℃; for 1h;92%
1196458-46-4

(Z)-3-[(1E,3S,5E,9E,11Z,14R,15Z,17E)-19-tert-butoxy-14-methoxy-3,15,18-trimethyl-19-oxononadeca-1,5,9,11,15,17-hexaenyl]pent-2-enedioic acid

11076-19-0

bongkrekic acid

Conditions
ConditionsYield
With hydrogenchloride; water In tetrahydrofuran at 20℃; for 3h;83%
88304-12-5, 88335-55-1

(2E,4Z,8Z,10E,14E)-(6R,17S)-17-(4-Carboxymethyl-6-oxo-3,6-dihydro-2H-pyran-2-yl)-6-methoxy-2,5-dimethyl-octadeca-2,4,8,10,14-pentaenoic acid

11076-19-0

bongkrekic acid

Conditions
ConditionsYield
With potassium methanolate In tetrahydrofuran; methanol at 0℃; for 0.0833333h;65%

C31H44O7

A

11076-19-0

bongkrekic acid

B

60132-21-0

isobongkrekic acid

Conditions
ConditionsYield
Stage #1: C31H44O7 With water; potassium hydroxide In 1,2-dimethoxyethane at 20℃; for 8h;
Stage #2: With hydrogenchloride In 1,2-dimethoxyethane; water optical yield given as %de; Further stages;		A 17%
B 35%
1204313-06-3

IBAMe3

BAMe3

A

11076-19-0

bongkrekic acid

B

60132-21-0

isobongkrekic acid

Conditions
ConditionsYield
With potassium hydroxide In 1,2-dimethoxyethane; water at 20℃; for 8h;A 35%
B 17%
...Expand
808771-36-0

(2E,4Z,8Z,10E,14E,18E,20Z)-(6R,17S)-20-Carboxymethyl-6-methoxy-2,5,17-trimethyl-docosa-2,4,8,10,14,18,20-heptaenedioic acid 1-tert-butyl ester 22-(tert-butyl-diphenyl-silanyloxymethyl) ester

11076-19-0

bongkrekic acid

Conditions
ConditionsYield
With hydrogenchloride In methanol; water at 20℃;

(Z)-4-((R)-3-Methyl-5-oxo-2,5-dihydro-furan-2-yl)-but-2-enal

11076-19-0

bongkrekic acid

Conditions
ConditionsYield
Multi-step reaction with 11 steps
1.1: 86 percent / BuLi; HMPA / tetrahydrofuran
2.1: DIBAH / tetrahydrofuran
2.2: 70 percent / NaBH4 / tetrahydrofuran; H2O
3.1: Dess-Martin reagent / benzene; CH2Cl2
4.1: 80 percent / benzene
5.1: 82 percent / HCl / H2O; tetrahydrofuran
6.1: MnO2 / benzene; CH2Cl2
6.2: NaClO2; NaH2PO4; 2-methyl-2-butene / tetrahydrofuran; 2-methyl-propan-2-ol; H2O
6.3: 40 percent / Et3N / tetrahydrofuran
7.1: Dess-Martin reagent / benzene; CH2Cl2
7.2: NaClO2; NaH2PO4; 2-methyl-2-butene / tetrahydrofuran; 2-methyl-propan-2-ol; H2O
8.1: HCl / H2O; methanol / 20 °C
View Scheme
Multi-step reaction with 14 steps
1.1: 86 percent / BuLi; HMPA / tetrahydrofuran
2.1: DIBAH / tetrahydrofuran
2.2: 70 percent / NaBH4 / tetrahydrofuran; H2O
3.1: 93 percent / Na-Hg; Na2HPO4 / methanol
4.1: 96 percent / Et3N / CH2Cl2
5.1: 83 percent / 2,6-di-tert-butylpyridine / benzene
6.1: 81 percent / DIBAH / tetrahydrofuran
7.1: Dess-Martin reagent / benzene; CH2Cl2
8.1: 80 percent / benzene
9.1: 82 percent / HCl / H2O; tetrahydrofuran
10.1: MnO2 / benzene; CH2Cl2
10.2: NaClO2; NaH2PO4; 2-methyl-2-butene / tetrahydrofuran; 2-methyl-propan-2-ol; H2O
10.3: 40 percent / Et3N / tetrahydrofuran
11.1: Dess-Martin reagent / benzene; CH2Cl2
11.2: NaClO2; NaH2PO4; 2-methyl-2-butene / tetrahydrofuran; 2-methyl-propan-2-ol; H2O
12.1: HCl / H2O; methanol / 20 °C
View Scheme
808771-43-9

(R)-5-((Z)-4-Hydroxy-but-2-enyl)-4-methyl-5H-furan-2-one

11076-19-0

bongkrekic acid

Conditions
ConditionsYield
Multi-step reaction with 12 steps
1.1: MnO2 / CH2Cl2
2.1: 86 percent / BuLi; HMPA / tetrahydrofuran
3.1: DIBAH / tetrahydrofuran
3.2: 70 percent / NaBH4 / tetrahydrofuran; H2O
4.1: Dess-Martin reagent / benzene; CH2Cl2
5.1: 80 percent / benzene
6.1: 82 percent / HCl / H2O; tetrahydrofuran
7.1: MnO2 / benzene; CH2Cl2
7.2: NaClO2; NaH2PO4; 2-methyl-2-butene / tetrahydrofuran; 2-methyl-propan-2-ol; H2O
7.3: 40 percent / Et3N / tetrahydrofuran
8.1: Dess-Martin reagent / benzene; CH2Cl2
8.2: NaClO2; NaH2PO4; 2-methyl-2-butene / tetrahydrofuran; 2-methyl-propan-2-ol; H2O
9.1: HCl / H2O; methanol / 20 °C
View Scheme
Multi-step reaction with 15 steps
1.1: MnO2 / CH2Cl2
2.1: 86 percent / BuLi; HMPA / tetrahydrofuran
3.1: DIBAH / tetrahydrofuran
3.2: 70 percent / NaBH4 / tetrahydrofuran; H2O
4.1: 93 percent / Na-Hg; Na2HPO4 / methanol
5.1: 96 percent / Et3N / CH2Cl2
6.1: 83 percent / 2,6-di-tert-butylpyridine / benzene
7.1: 81 percent / DIBAH / tetrahydrofuran
8.1: Dess-Martin reagent / benzene; CH2Cl2
9.1: 80 percent / benzene
10.1: 82 percent / HCl / H2O; tetrahydrofuran
11.1: MnO2 / benzene; CH2Cl2
11.2: NaClO2; NaH2PO4; 2-methyl-2-butene / tetrahydrofuran; 2-methyl-propan-2-ol; H2O
11.3: 40 percent / Et3N / tetrahydrofuran
12.1: Dess-Martin reagent / benzene; CH2Cl2
12.2: NaClO2; NaH2PO4; 2-methyl-2-butene / tetrahydrofuran; 2-methyl-propan-2-ol; H2O
13.1: HCl / H2O; methanol / 20 °C
View Scheme
808771-29-1

(R)-5-((2Z,4E)-6-Bromo-hexa-2,4-dienyl)-4-methyl-5H-furan-2-one

11076-19-0

bongkrekic acid

Conditions
ConditionsYield
Multi-step reaction with 9 steps
1.1: 86 percent / BuLi; HMPA / tetrahydrofuran
2.1: DIBAH / tetrahydrofuran
2.2: 70 percent / NaBH4 / tetrahydrofuran; H2O
3.1: Dess-Martin reagent / benzene; CH2Cl2
4.1: 80 percent / benzene
5.1: 82 percent / HCl / H2O; tetrahydrofuran
6.1: MnO2 / benzene; CH2Cl2
6.2: NaClO2; NaH2PO4; 2-methyl-2-butene / tetrahydrofuran; 2-methyl-propan-2-ol; H2O
6.3: 40 percent / Et3N / tetrahydrofuran
7.1: Dess-Martin reagent / benzene; CH2Cl2
7.2: NaClO2; NaH2PO4; 2-methyl-2-butene / tetrahydrofuran; 2-methyl-propan-2-ol; H2O
8.1: HCl / H2O; methanol / 20 °C
View Scheme
Multi-step reaction with 12 steps
1.1: 86 percent / BuLi; HMPA / tetrahydrofuran
2.1: DIBAH / tetrahydrofuran
2.2: 70 percent / NaBH4 / tetrahydrofuran; H2O
3.1: 93 percent / Na-Hg; Na2HPO4 / methanol
4.1: 96 percent / Et3N / CH2Cl2
5.1: 83 percent / 2,6-di-tert-butylpyridine / benzene
6.1: 81 percent / DIBAH / tetrahydrofuran
7.1: Dess-Martin reagent / benzene; CH2Cl2
8.1: 80 percent / benzene
9.1: 82 percent / HCl / H2O; tetrahydrofuran
10.1: MnO2 / benzene; CH2Cl2
10.2: NaClO2; NaH2PO4; 2-methyl-2-butene / tetrahydrofuran; 2-methyl-propan-2-ol; H2O
10.3: 40 percent / Et3N / tetrahydrofuran
11.1: Dess-Martin reagent / benzene; CH2Cl2
11.2: NaClO2; NaH2PO4; 2-methyl-2-butene / tetrahydrofuran; 2-methyl-propan-2-ol; H2O
12.1: HCl / H2O; methanol / 20 °C
View Scheme
808771-19-9

(2E,6E)-(S)-5-Methyl-7-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-hepta-2,6-dien-1-ol

11076-19-0

bongkrekic acid

Conditions
ConditionsYield
Multi-step reaction with 11 steps
1.1: 92 percent / Et3N / PdCl2(PPh3)2 / methanol
2.1: MsCl; iPr2EtN; 4-DMAP / CH2Cl2
2.2: 81 percent / dimethylformamide
3.1: 86 percent / BuLi; HMPA / tetrahydrofuran
4.1: DIBAH / tetrahydrofuran
4.2: 70 percent / NaBH4 / tetrahydrofuran; H2O
5.1: Dess-Martin reagent / benzene; CH2Cl2
6.1: 80 percent / benzene
7.1: 82 percent / HCl / H2O; tetrahydrofuran
8.1: MnO2 / benzene; CH2Cl2
8.2: NaClO2; NaH2PO4; 2-methyl-2-butene / tetrahydrofuran; 2-methyl-propan-2-ol; H2O
8.3: 40 percent / Et3N / tetrahydrofuran
9.1: Dess-Martin reagent / benzene; CH2Cl2
9.2: NaClO2; NaH2PO4; 2-methyl-2-butene / tetrahydrofuran; 2-methyl-propan-2-ol; H2O
10.1: HCl / H2O; methanol / 20 °C
View Scheme
Multi-step reaction with 14 steps
1.1: 92 percent / Et3N / PdCl2(PPh3)2 / methanol
2.1: MsCl; iPr2EtN; 4-DMAP / CH2Cl2
2.2: 81 percent / dimethylformamide
3.1: 86 percent / BuLi; HMPA / tetrahydrofuran
4.1: DIBAH / tetrahydrofuran
4.2: 70 percent / NaBH4 / tetrahydrofuran; H2O
5.1: 93 percent / Na-Hg; Na2HPO4 / methanol
6.1: 96 percent / Et3N / CH2Cl2
7.1: 83 percent / 2,6-di-tert-butylpyridine / benzene
8.1: 81 percent / DIBAH / tetrahydrofuran
9.1: Dess-Martin reagent / benzene; CH2Cl2
10.1: 80 percent / benzene
11.1: 82 percent / HCl / H2O; tetrahydrofuran
12.1: MnO2 / benzene; CH2Cl2
12.2: NaClO2; NaH2PO4; 2-methyl-2-butene / tetrahydrofuran; 2-methyl-propan-2-ol; H2O
12.3: 40 percent / Et3N / tetrahydrofuran
13.1: Dess-Martin reagent / benzene; CH2Cl2
13.2: NaClO2; NaH2PO4; 2-methyl-2-butene / tetrahydrofuran; 2-methyl-propan-2-ol; H2O
14.1: HCl / H2O; methanol / 20 °C
View Scheme
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    Business Type:Trading Company

    Tel:+8617316470195

    Address:333 Songze Avenue, Qingpu District, Shanghai

       Inquiry Now

  • BONGKREKIC ACID

  • Casno:

    11076-19-0

    BONGKREKIC ACID

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

    Zhejiang Jiuzhou Chemical Co.,Ltd is a market-oriented and innovation-driven biopharmaceutical company. The company is focusing on the R&D, manufacturing and sales of pharmaceutica

  •  ZHEJIANG JIUZHOU CHEM CO.,LTD

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86 19334956669

    Address:Waisha Road,Jiaojiang

       Inquiry Now

  • bongkrekic acid

  • Casno:

    11076-19-0

    bongkrekic acid

    Min.Order: 1 Gram

    FOB Price:  USD $ 0.0-0.0

    Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

    Changzhou Extraordinary Pharmatech co., LTD. Is a full technical team and for the development of hardware and software facilities manufacturing enterprises,The company is located i

  • Changzhou Extraordinary Pharmatech co.,LTD

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86 519 82111935

    Address:Chinese Jiangsu Province Changzhou City Jintan District Jincheng Town Miaotou NO4（Pharmaceutical Park）

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  • Bongkrekic acid solution CAS NO.11076-19-0

  • Casno:

    11076-19-0

    Bongkrekic acid solution CAS NO.11076-19-0

    Min.Order: 1 Gram

    FOB Price:  USD $ 1.0-1.0

    HuBei ipure is a diversified product production and operation enterprise, with API, pharma intermediates, and other fine chemicals as well as R&D and pigments development and sales as one of the large enterprises, with more than 130 acres of pl

    Hubei Ipure biotech Co., Ltd. is Established in 2011,which is located in Wuhan, Hubei Province where is the largest city in central China. The company is a diversified product pr

  • HuBei Ipure Biotech CO.,ltd

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:18062427325

    Address:NO 18. 81F street Future city ,Hongshan district ,WuHan city ,Hubei province ,China

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  • Bongkrekic acid solution

  • Casno:

    11076-19-0

    Bongkrekic acid solution

    Min.Order: 10 Gram

    FOB Price:  USD $ 1.0-2.0

    1,Best Quality: Our products have exported to Germany, Spain, UK, USA, Australia, Middle East, and so on other countries, and we have got very good feedback from our customers.so you can trust us. 2,

    Hubei Jusheng Technology Co., Ltd., is a large group corporation which engaged in the R&D and manufacture of chemicals, Pharmaceuticals and intermediates. We have earned ourselves

  • Hubei Jusheng Technology Co., Ltd.,

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-18871490254

    Address:High-tech Industrial Park,Tianmen city,Hubei province.

       Inquiry Now

  • BONGKREKIC ACID

  • Casno:

    11076-19-0

    BONGKREKIC ACID

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    Shanghai, Run-Biotech Co., Ltd is a leading domestic pharmaceutical, biopharmaceutical, and health care products R & D outsourcing services company. As an innovation-driven and customer-focused company, Run Biotech provides a broad and integrated por

    Shanghai fine pharma co., Ltd. is a professional enterprise with chemical reagents and fine chemical products development, development and trade. The company has a sound research a

  • Shanghai Run-Biotech Co., Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-21-31576854/57171705 / 57171706

    Address:second floor, building 3, No.999, jiangyue Road, minghang District, Shanghai, China

       Inquiry Now

  • Bongkrekic acid solution

  • Casno:

    11076-19-0

    Bongkrekic acid solution

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    We are a trading company aiming at providing high-quality services to customers. Established for many years, with good reputation in the industry Storage:Sealed and preserved Application:Fine chemical intermediates, used as the main raw material for

    Our company has been engaged in the Pharmaceutical raw material and pharmaceutical intermediates medicine material intermediates and related chemical industry for more than ten ye

  • Taizhou volsen chemical Co., Ltd

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-576-88869393

    Address:Jiaojiang District, Taizhou, Zhejiang, China.

       Inquiry Now

  • 11076-19-0

  • Casno:

    11076-19-0

    11076-19-0

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    Bongkrekic acid solution Application:intermediates

    We are Hebei minshang biotechnology co. LTD., mainly deal in pharmaceutical intermediates and various chemicals. We are manufacturers and have our own factory. Products & Usage Ph

  • Hebei Minshang Biotechnology Co., Ltd

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:18032092709

    Address:hebei

       Inquiry Now

  • Bongkrekic acid solution

  • Casno:

    11076-19-0

    Bongkrekic acid solution

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    Bongkrekic acid solution Application:Bongkrekic acid solution

    Hangzhou Fenjunchem Co.,Ltd dedicated to the development, production and marketing of chemicals which is specialized in Organic compounds; Active Pharmaceutical Ingredient(s); Nutr

  • Hangzhou Fenjun Chemical Co Ltd.

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-0571-56263321

    Address:hangzhou

       Inquiry Now

  • 11076-19-0

  • Casno:

    11076-19-0

    11076-19-0

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    Supply top quality products with a reasonable price Application:api

    Hebei Ruishun Trade Co.,Ltd registered capital one million, we have a production of pharmaceutical raw materials, pharmaceutical raw materials factory reagent r&d center, we do

  • Hebei Ruishun Trade Co.,Ltd

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-311-68037669

    Address:WanDa commerce building ,yuhua district

       Inquiry Now

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