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111-83-1

Basic Information
CAS No.: 111-83-1
Name: 1-Bromooctane
Molecular Structure:
Molecular Structure of 111-83-1 (1-Bromooctane)
Formula: C8H17Br
Molecular Weight: 193.12
Synonyms: 1-Bromo Octane;1-Octylbromide;Octyl bromide;Octane, 1-bromo-;N-bromooctane;
EINECS: 203-912-9
Density: 1.111 g/cm3
Melting Point: -55 °C
Boiling Point: 200.9 °C at 760 mmHg
Flash Point: 78.3 °C
Solubility: insoluble
Appearance: clear colourless to yellow-brown liquid
Hazard Symbols: 36/37/38:;
Risk Codes: 36/37/38
Safety: 23-24/25
Transport Information:
PSA: 0.00000
LogP: 3.74180
Synthetic route
463-11-6

1-Fluoro-octane

111-83-1

1-bromo-octane

Conditions
ConditionsYield
With dibromobis(cyclopentadienyl)titanium(IV); triisobutylaluminum; 1,2-dibromomethane In hexane at 20℃; for 24h; Reagent/catalyst;99%
With hydrogen bromide; cetyltributylphosphonium bromide at 130℃; for 8.5h;86%
With magnesium bromide In diethyl ether at 25℃; for 10h;41 % Chromat.
With aluminum tri-bromide In chlorobenzene at 20℃; for 1h;
111-87-5

octanol

111-83-1

1-bromo-octane

Conditions
ConditionsYield
With carbon tetrabromide; polystyrene-supported triphenylphosphine In chloroform at 20℃; for 0.333333h;98%
With sulfuric acid; hydrogen bromide In water at 60℃; Temperature; Flow reactor; Green chemistry;98%
With 1-(2-OPPh2-propyl)-3-methylimidazolium hexafluorophosphate; bromine at 80℃; for 2h;96%
103514-65-4

C14H35N3PS(1+)

111-83-1

1-bromo-octane

Conditions
ConditionsYield
With bromide In N,N-dimethyl-formamide96%
16156-52-8

n-octyl methanesulfonate

111-83-1

1-bromo-octane

Conditions
ConditionsYield
With potassium bromide; O3Si(CH2)3P(C4H9)3Br; silica gel In carbon dioxide; water at 70℃; under 97509.8 Torr; for 5h;95%
With potassium bromide; tributylphosphonium salts bonded to .. In water; toluene at 60℃; Rate constant; variation of catalists;
With 2-hexadecyl-1,3-bis-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)propane; sodium bromide In toluene at 50℃; Rate constant; also with KBr; further phase-transfer catalysts;
111-66-0

oct-1-ene

A

111-83-1

1-bromo-octane

B

557-35-7, 60251-57-2

2-bromooctane

Conditions
ConditionsYield
With hydrogen bromide In hexane at 24.9℃; for 48h; Mechanism; Product distribution; other reagent concentrations and other reaction temperatures;A 95%
B 5%
With borane; bromine; sodium methylate 1.) THF, 0 deg C, 2.) 0 deg C, 3.) MeOH, 0 deg C; Yield given. Multistep reaction;
3386-35-4

1-octyl p-toluenesulfonate

111-83-1

1-bromo-octane

Conditions
ConditionsYield
With 1-n-butyl-3-methylimidazolim bromide at 50℃; for 5h; Inert atmosphere; Green chemistry;93%
With lithium bromide
88738-43-6

methoxymethyl octyl ether

111-83-1

1-bromo-octane

Conditions
ConditionsYield
With phosphotungstic acid; tetrabutylammomium bromide at 130 - 142℃; for 0.0333333h; Microwave irradiation; Ionic liquid; chemoselective reaction;91%
With tetrabutylammomium bromide; 1-(n-butyl)-3-methylimidazolium tetrachloroindate at 135 - 140℃; for 0.0666667h; Microwave irradiation; Neat (no solvent); chemoselective reaction;82%
929-56-6

1-methoxyoctane

111-83-1

1-bromo-octane

Conditions
ConditionsYield
With hydrogen bromide; phosphorus tribromide at 125℃; for 0.666667h;90%
111-85-3

1-Chlorooctane

111-83-1

1-bromo-octane

Conditions
ConditionsYield
With calcium bromide; tetrahexylammonium bromide at 110℃; for 24h;89%
With pyridine; tributyltin bromide at 100℃; Thermodynamic data; Equilibrium constant; Δ G;
With lithium bromide; tetrahexylammonium bromide In water at 98℃; for 72h; various metal halide salts; bromine-chloride exchange;
796965-95-2

ethoxymethyl octyl ether

111-83-1

1-bromo-octane

Conditions
ConditionsYield
With phosphotungstic acid; tetrabutylammomium bromide at 130 - 142℃; for 0.0333333h; Microwave irradiation; Ionic liquid; chemoselective reaction;89%
With tetrabutylammomium bromide; 1-(n-butyl)-3-methylimidazolium tetrachloroindate at 135 - 140℃; for 0.0666667h; Microwave irradiation; Neat (no solvent); chemoselective reaction;83%
629-27-6

1-Iodooctane

111-83-1

1-bromo-octane

Conditions
ConditionsYield
With iodobenzene dibromide In dichloromethane for 1h; Ambient temperature;85%
With pyridine; tributyltin bromide at 100℃; Thermodynamic data; Equilibrium constant; Δ G;36 % Spectr.
With n-hexylzirconocene chloride; [nickel(II) (4,4'-di-tert-butyl-2,2'-bipyridine)(bromide)2]; tetrabutylammonium p-toluenesulfonate In tetrahydrofuran at 20℃; for 24h; Inert atmosphere; Irradiation; Sealed tube;
14246-16-3

trimethyl(oct-1-yloxy)silane

111-83-1

1-bromo-octane

Conditions
ConditionsYield
With trimethylsilyl bromide; iodine(I) bromide for 6h; Heating;85%
54384-75-7

1-methoxy-4-octyloxymethyl benzene

111-83-1

1-bromo-octane

Conditions
ConditionsYield
With carbon tetrabromide; triphenylphosphine In dichloromethane at 0 - 30℃; for 2.5h;85%
52770-75-9

1,3-Diisopropyl-2-octyl-isourea

A

4128-37-4

1,3-diisopropylurea

B

111-83-1

1-bromo-octane

Conditions
ConditionsYield
With trifluorormethanesulfonic acid; tetrabutylammomium bromide In chloroform at 65℃; for 7.5h;A n/a
B 83%
111-66-0

oct-1-ene

111-83-1

1-bromo-octane

Conditions
ConditionsYield
Stage #1: oct-1-ene With dibenzoyl peroxide at 30℃; for 0.5h;
Stage #2: With hydrogen bromide at 20℃; for 0.5h; Temperature;
82.2%
With hydrogenchloride; borane; chloroamine-T; sodium bromide 1.) 0 deg C, 1 h, THF, 2.) 0 deg C, 15 min, H2O, THF; Yield given. Multistep reaction;
With hydrogen bromide In hexane at -78.1℃; for 48h; Yield given;
Multi-step reaction with 2 steps
1: bis(1,5-cyclooctadiene)diiridium(I) dichloride / dichloromethane / 16 h / 0 - 20 °C / Inert atmosphere; Glovebox
2: benzenesulfonyl bromide; trimethylsilyl trifluoromethanesulfonate; 2-methoxybenzo[d][1,3,2]dioxaborole / dichloromethane; benzene; methanol / 16 h / 70 °C / Inert atmosphere
View Scheme
76207-90-4

5,6,8,9-tetrahydro-14-octyl-7-phenyldibenzoacridinium bromide

A

57366-68-4

5,6,8,9-tetrahydro-7-phenyldibenzolacridine

B

111-83-1

1-bromo-octane

Conditions
ConditionsYield
With acetonitrile 1.) reflux, 4 h, 2.) 0 deg C, 6 h;A n/a
B 80%
111-87-5

octanol

A

1809-14-9

di(n-octyl)phosphite

B

111-83-1

1-bromo-octane

Conditions
ConditionsYield
With phosphorus tribromide In diethyl ether at 0 - 25℃; for 6h;A 12.2%
B 77.3%
111-88-6

Octanethiol

111-83-1

1-bromo-octane

Conditions
ConditionsYield
With N-Bromosuccinimide; triphenylphosphine In dichloromethane at 20℃; for 12h;75%
66217-56-9

4,4,5,5-tetramethyl-2-octyl-[1,3,2]dioxaborolane

111-83-1

1-bromo-octane

Conditions
ConditionsYield
With trimethylsilyl trifluoromethanesulfonate; 2-methoxybenzo[d][1,3,2]dioxaborole; benzenesulfonyl bromide In methanol; dichloromethane; benzene at 70℃; for 16h; Inert atmosphere;66%
929-56-6

1-methoxyoctane

A

111-83-1

1-bromo-octane

B

35103-75-4

mono-1-methylheptyl phosphonate

Conditions
ConditionsYield
With hydrogen bromide; phosphorus tribromide at 50℃; for 0.666667h;A 15%
B 50%
7333-16-6

4-hydroxybutyl octyl sulfoxide

A

111-83-1

1-bromo-octane

B

33036-62-3

4-Bromo-1-butanol

C

octyl cyclobutyl sulfonium bromide

D

80623-45-6

4-bromobutyl octyl sulfone

Conditions
ConditionsYield
With bromine In acetonitrile at -25℃; for 2h; Further byproducts given;A n/a
B n/a
C 24%
D 46%
68975-45-1

1-(methylethoxy)octane

A

111-83-1

1-bromo-octane

B

35103-75-4

mono-1-methylheptyl phosphonate

Conditions
ConditionsYield
With hydrogen bromide; phosphorus tribromide at 80℃; for 0.666667h;A 45%
B 9%
7333-16-6

4-hydroxybutyl octyl sulfoxide

A

111-83-1

1-bromo-octane

B

33036-62-3

4-Bromo-1-butanol

C

4-hydroxybutanesulfinyl bromide

D

octanesulfinyl bromide

E

octane-1-sulfonyl bromide

F

octyl cyclobutyl sulfonium bromide

Conditions
ConditionsYield
With bromine In acetonitrile at -25℃; for 2h; Product distribution;A n/a
B n/a
C n/a
D n/a
E n/a
F 24%
67007-46-9

n-octylsilatrane

111-83-1

1-bromo-octane

Conditions
ConditionsYield
With N-Bromosuccinimide In dichloromethane for 78h; Ambient temperature;15%
111-66-0

oct-1-ene

75-26-3

isopropyl bromide

A

7642-04-8

cis-2-octene

B

13389-42-9

trans-2-Octene

C

111-83-1

1-bromo-octane

Conditions
ConditionsYield
mit UV-Licht.Irradiation;
16156-52-8

n-octyl methanesulfonate

14866-33-2

tetraoctyl ammonium bromide

A

111-83-1

1-bromo-octane

B

70098-05-4

tetraoctylammonium methanesulfonate

Conditions
ConditionsYield
In chlorobenzene at 60℃; Rate constant;
In water; chlorobenzene at 60℃; Kinetics;
16156-52-8

n-octyl methanesulfonate

92958-33-3

3-Tetradecyl-4,10,15-trioxa-1,7-diaza-bicyclo[5.5.5]heptadecane; hydrobromide

A

111-83-1

1-bromo-octane

B

80322-81-2

3-Tetradecyl-4,10,15-trioxa-1,7-diaza-bicyclo[5.5.5]heptadecane; compound with methanesulfonic acid

Conditions
ConditionsYield
In chlorobenzene at 60℃; Rate constant;
16156-52-8

n-octyl methanesulfonate

A

111-83-1

1-bromo-octane

B

629-82-3

di-n-octyl ether

C

2386-56-3

potassium mesylate

Conditions
ConditionsYield
With potassium bromide; perhydrodibenzo-18-crown-6 In potassium hydroxide; chlorobenzene at 60℃; for 1h;A 94.4 % Chromat.
B 3 % Chromat.
C n/a
16156-52-8

n-octyl methanesulfonate

A

111-83-1

1-bromo-octane

B

2386-56-3

potassium mesylate

Conditions
ConditionsYield
With potassium bromide In water; benzene at 45℃; gaschromatographic determination of formation of octyl bromide in dependence on time, addition of various quaternary onium salts; also with solvent CHCl3/H2O; two phase system and homogeneous system;
With potassium bromide; (C16H33)Bu3P(1+)*Br(1-) In water; chlorobenzene at 60℃; Rate constant; other quaternary ammonium or phosphonium;
With potassium bromide; (C8H17)4N(1+)*Br(1-) In water; chlorobenzene at 35℃; Rate constant; other solvents;
111-87-5

octanol

81106-32-3

dimethylamino-2,N,N' diphenyl-1,3 diazaphospholane-1,3,2

111-83-1

1-bromo-octane

Conditions
ConditionsYield
With bromine 1.) toluene, 85 deg C, 18 h 12.) CH2Cl2, 0 deg C; Yield given. Multistep reaction;
188290-36-0

thiophene

111-83-1

1-bromo-octane

880-36-4

2-octylthiophene

Conditions
ConditionsYield
Stage #1: thiophene With n-butyllithium In tetrahydrofuran; hexane at -80℃; for 0.25h; Inert atmosphere;
Stage #2: 1-bromo-octane In tetrahydrofuran; hexane at -80 - 20℃;
Stage #3: With water In tetrahydrofuran; hexane
100%
Stage #1: thiophene With n-butyllithium In tetrahydrofuran; hexane at -78℃;
Stage #2: 1-bromo-octane In tetrahydrofuran; hexane at -78 - 20℃;
95%
Stage #1: thiophene With n-butyllithium In tetrahydrofuran; hexane at 0 - 20℃; Inert atmosphere;
Stage #2: 1-bromo-octane In tetrahydrofuran; hexane for 4h; Inert atmosphere; Reflux;
84.6%
111-83-1

1-bromo-octane

333-20-0

potassium thioacyanate

19942-78-0

octyl thiocyanate

Conditions
ConditionsYield
C(CH2S(=O)C6H13)4 at 100℃; for 0.5h;100%
With silica gel at 80℃; for 8h;97%
With 2-methylsulfinylpyridine In xylene at 100℃; for 40h;96%
111-83-1

1-bromo-octane

139-02-6

sodium phenoxide

1818-07-1

octyloxybenzene

Conditions
ConditionsYield
poly<1-hydroxyethylene-co-1-(2-ethylsulf In 1,4-dioxane at 75℃; for 23h; Product distribution; Rate constant; other catalysts;100%
Sucrose-ethyleneoxide adducts In toluene at 110℃; for 8h; Product distribution; further catalysts: PEG, DB18K6; further objects of study: phase-transfer catalysis;100%
dodecyldimethylsulfonium methyl sulfate In water at 40℃; for 6h;25%
111-83-1

1-bromo-octane

151-50-8

potassium cyanide

2243-27-8

nonanonitrile

Conditions
ConditionsYield
Sucrose-ethyleneoxide adducts In acetonitrile at 83℃; for 24h; Product distribution; further catalysts: PEG, DB18K6; further objects of study: phase-transfer catalysis; further solvents: toluene/H2O;100%
tetraoctyl ammonium bromide In water; toluene at 90℃; for 24h; Product distribution; other phase-transfer catalysts, time;99%
tetraoctyl ammonium bromide In water; toluene at 90℃; for 24h;99%
111-83-1

1-bromo-octane

629-27-6

1-Iodooctane

Conditions
ConditionsYield
With potassium iodide; Sucrose-ethyleneoxide adducts In toluene at 110℃; for 24h; Product distribution; further catalysts: PEG, DB18K6; further objects of study: phase-transfer catalysis; further solvents: toluene/H2O;100%
With potassium iodide; polymeric crown ethers In water; toluene at 79.9℃; for 5h; Product distribution; catalysts with other crown-ether groups; or NaI, other reaction times;98%
With potassium iodide; tetraoctyl ammonium bromide In water; toluene at 90℃; for 24h;97%
111-83-1

1-bromo-octane

7438-05-3

1-azidooctane

Conditions
ConditionsYield
With sodium azide In N,N-dimethyl-formamide at 20℃; for 12h;100%
With sodium azide In water; acetone Reflux;100%
With sodium azide In methanol at 20℃; for 24h;100%
111-83-1

1-bromo-octane

603-35-0

triphenylphosphine

42036-78-2

n-octyltriphenylphosphoniumbromide

Conditions
ConditionsYield
In chlorobenzene for 48h; Heating;100%
In toluene Reflux;100%
In o-xylene Heating;98.7%
868-84-8

S,S-dimethyl dithiocarbonate

111-83-1

1-bromo-octane

3698-95-1

methyl octyl sulfide

Conditions
ConditionsYield
With potassium hydroxide; tetrabutylammomium bromide for 0.25h; Heating;100%
106-41-2

4-bromo-phenol

111-83-1

1-bromo-octane

96693-05-9

1-bromo-4-octyloxybenzene

Conditions
ConditionsYield
With potassium carbonate Williamson's etherification;100%
With potassium carbonate In acetone for 43h; Heating;98%
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 48h; Inert atmosphere;96%
111-83-1

1-bromo-octane

623-80-3

S,S-diethyl dithiocarbonate

3698-94-0

ethyl octyl sulfide

Conditions
ConditionsYield
With potassium hydroxide; tetrabutylammomium bromide for 0.5h; Heating;100%
111-83-1

1-bromo-octane

55716-09-1

S,S'-di-n-butyl dithiocarbonate

16900-07-5

1-butyl 1-octyl sulphide

Conditions
ConditionsYield
With potassium hydroxide; tetrabutylammomium bromide for 1.5h; Heating;100%
111-83-1

1-bromo-octane

69422-58-8

S,S-dioctyl dithiocarbonate

2690-08-6

di-n-octyl sulfide

Conditions
ConditionsYield
With potassium hydroxide; tetrabutylammomium bromide for 3h; Heating;100%
111-83-1

1-bromo-octane

127-08-2

potassium acetate

112-14-1

n-octyl acetate

Conditions
ConditionsYield
Sucrose-ethyleneoxide adducts In acetonitrile at 83℃; for 24h; Product distribution; further catalysts: PEG, DB18K6; further objects of study: phase-transfer catalysis; further solvents: toluene/H2O;100%
With aluminum oxide at 196℃; for 0.0333333h; Irradiation; other long chain halides;99%
With aluminum oxide at 196℃; for 0.0333333h; Irradiation;99%
111-83-1

1-bromo-octane

534-18-9

sodium trithiocarbonate

89622-57-1

dioctyl trithiocarbonate

Conditions
ConditionsYield
Aliquat 336 at 70℃; for 1.5h;100%
111-83-1

1-bromo-octane

119289-79-1

3-(4-hydroxy-2-nitrophenyl)pyridine

158461-43-9

3-(2-nitro-4-n-octyloxyphenyl)pyridine

Conditions
ConditionsYield
With potassium carbonate; potassium iodide In N,N-dimethyl-formamide at 70℃; for 1h;100%
111-83-1

1-bromo-octane

100-83-4

meta-hydroxybenzaldehyde

24083-12-3

3-(n-Octyloxy)benzaldehyde

Conditions
ConditionsYield
With potassium hydroxide In ethanol Heating;100%
With potassium carbonate In N,N-dimethyl-formamide at 160℃; for 0.5h;90%
111-83-1

1-bromo-octane

95-13-6

1-indene

43130-63-8

3-octylindene

Conditions
ConditionsYield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride for 0.5h; Irradiation;100%
111-83-1

1-bromo-octane

94-09-7

p-aminoethylbenzoate

55791-74-7

4-octylamino-benzoic acid ethyl ester

Conditions
ConditionsYield
In N,N,N,N,N,N-hexamethylphosphoric triamide at 125℃; for 10h; Addition;100%
In N,N,N,N,N,N-hexamethylphosphoric triamide at 125℃; for 24h;65%
111-83-1

1-bromo-octane

74-88-4

methyl iodide

929-56-6

1-methoxyoctane

Conditions
ConditionsYield
With aluminum oxide; potassium fluoride; potassium hydroxide In acetonitrile at 20℃; for 2h; Product distribution; effect of various catalyst and solvents;100%
With potassium hydroxide; Aliquat 336 at 20℃; for 2h;100%
111-83-1

1-bromo-octane

1707-03-5

diphenyl-phosphinic acid

3389-73-9

octyl phenyl(phenyl)phosphinate

Conditions
ConditionsYield
With potassium carbonate at 140℃; for 10h;100%
With caesium carbonate In acetonitrile at 100℃; for 12h; Inert atmosphere;93%
111-83-1

1-bromo-octane

156747-01-2

5,17,29-tri-tert-butyl-37,39,41-trihydroxy-38,40,42-trimethoxycalix[6]arene

5,17,29-tris(1,1-dimethylethyl)-37,39,41-trimethoxy-38,40,42-tris-(n-octyloxy)calix[6]carene

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide at 90℃; for 16h;100%
108-89-4

picoline

111-83-1

1-bromo-octane

1-(n-octyl)-4-methylpyridinium bromide

Conditions
ConditionsYield
Darkness;100%
Darkness;100%
In acetonitrile at 70℃;97%
111-83-1

1-bromo-octane

2150-44-9

1-carbomethoxy-3,5-dihydroxybenzene

87963-84-6

methyl 3,5-bis(octyloxy)benzoate

Conditions
ConditionsYield
With 18-crown-6 ether; potassium carbonate In acetone for 60h; Etherification; Heating;100%
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 15h; Inert atmosphere;98%
With adogen 464; potassium carbonate In acetone Heating;96%
111-83-1

1-bromo-octane

119-36-8

methyl salicylate

255062-85-2

2-octyloxybenzoic acid methyl ester

Conditions
ConditionsYield
With potassium carbonate In methanol; N,N-dimethyl-formamide at 100℃; for 72h;100%
With potassium carbonate In acetonitrile at 85℃; Sealed tube; Inert atmosphere;100%
With sodium methylate In methanol for 48h; Alkylation; Heating;79%
With potassium carbonate In N,N-dimethyl-formamide at 90℃; for 24h;71%
With sodium hydroxide In acetonitrile at 20℃; for 24h; Reagent/catalyst;76 g
616-47-7

1-methyl-1H-imidazole

111-83-1

1-bromo-octane

1-octyl-3-methyl-imidazolium bromide

Conditions
ConditionsYield
In neat (no solvent) at 60℃; for 24h; Inert atmosphere;100%
In neat (no solvent) for 5h; Sonication; Reflux;98%
at 80℃; for 72h;97%
111-83-1

1-bromo-octane

4-(dimethylamino)-1-octylpyridinium bromide

Conditions
ConditionsYield
In acetonitrile for 15h; Heating;100%
In acetone for 9h; Heating;50%
In ethyl acetate at 70℃; for 48h;
111-83-1

1-bromo-octane

6089-04-9

3-(tetrahydropyran-2'-yloxy)propyne

88517-99-1

2-undecynyltetrahydro-2H-pyran-2-yl ether

Conditions
ConditionsYield
Stage #1: 3-(tetrahydropyran-2'-yloxy)propyne With n-butyllithium In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide at -78℃;
Stage #2: 1-bromo-octane In tetrahydrofuran
100%
Stage #1: 3-(tetrahydropyran-2'-yloxy)propyne With sodium hydride In tetrahydrofuran; dimethyl sulfoxide; mineral oil at 20℃; for 15h;
Stage #2: 1-bromo-octane In tetrahydrofuran; dimethyl sulfoxide; mineral oil at 20℃; for 29h;
82%
With n-butyllithium In tetrahydrofuran
Stage #1: 3-(tetrahydropyran-2'-yloxy)propyne With n-butyllithium In tetrahydrofuran at -78℃; for 0.25h; Inert atmosphere;
Stage #2: 1-bromo-octane In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide at -78 - 20℃; Inert atmosphere;
280-57-9

1,4-diaza-bicyclo[2.2.2]octane

111-83-1

1-bromo-octane

1‐octyl‐1,4‐diazabicyclo[2.2.2]octan‐1‐ium bromide

Conditions
ConditionsYield
In dichloromethane for 12h; Reflux;100%
In tetrahydrofuran at 60℃; for 24h;95%
In ethyl acetate at 20℃; for 24h;91%
111-83-1

1-bromo-octane

86-74-8

9H-carbazole

4041-19-4

9-octylcarbazole

Conditions
ConditionsYield
With tetrabutylammomium bromide; sodium hydroxide In toluene at 120℃;100%
With sodium hydroxide; triethylamine hydrochloride In water; dimethyl sulfoxide at 80℃; for 8h;97.4%
With tetrabutylammomium bromide; sodium hydroxide In water; toluene for 24h; Inert atmosphere; Reflux;96%
6825-20-3

3,6-dibromo-9H-carbazole

111-83-1

1-bromo-octane

79554-93-1

3,6-dibromo-9-octyl-9H-carbazole

Conditions
ConditionsYield
With tetrabutylammomium bromide; sodium hydroxide In toluene at 120℃;100%
With tetrabutylammomium bromide; potassium hydroxide In acetone for 6h; Reflux;95%
With tetrabutylammomium bromide; potassium hydroxide In water; toluene for 24h; Heating;95%
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  • 1-Bromooctane

  • Casno:

    111-83-1

    1-Bromooctane

    Min.Order: 1 Gram

    FOB Price:  USD $ 0.0-0.0/Gram

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  •  Dayang Chem (Hangzhou) Co.,Ltd.

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    Address:9/F, Unit 2 Changdi Torch Building, 259# WenSan Road, Xihu District, Hangzhou City 310012, P.R.China

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  • 1-Bromooctane

  • Casno:

    111-83-1

    1-Bromooctane

    Min.Order: 1 Kilogram

    FOB Price:  USD $ 0.0-0.0/Kilogram

    We are very strong on this product. Package:As requirement Application:111-83-1 Port:SHANGHAI

    CHANGZHOU HANGYU PHARMACEUTICAL TECHNOLOGY CO., LTD., founded in 1984, engages in pharmaceutical research, development, production, process design and technical consultation of syn

  •  CHANGZHOU HANGYU PHARMACEUTICAL TECHNOLOGY CO., LTD

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    Tel:0086-519-88802789

    Address:No.300,Yanling Middle Road, Changzhou, Jiangsu, China

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  • 1-Bromooctane

  • Casno:

    111-83-1

    1-Bromooctane

    Min.Order: 1 Gram

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    Product Description Product website: http://www.finerchem.com/pro01en/id/2047.html Product Name 1-Bromooctane CAS No. 111-83-1

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  •  Jinan Finer Chemical Co., Ltd

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    Business Type:Lab/Research institutions

    Tel:+86-531-88989536

    Address:New Material Industry Park, Jinan Ciyt, China

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  • High quality 1-Bromo Octane supplier in China

  • Casno:

    111-83-1

    High quality 1-Bromo Octane supplier in China

    Min.Order: 1 Metric Ton

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    Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

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  •  Simagchem Corporation

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    Tel:+86-592-2680277

    Address:21/F Hualong Office Building,No.6 Hubin East Road, Xiamen,China

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  • 111-83-1  1-Bromooctane

  • Casno:

    111-83-1

    111-83-1 1-Bromooctane

    Min.Order: 1 Gram

    FOB Price:  USD $ 40.0-50.0/Gram

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    Business Type:Trading Company

    Tel:+8619831967063

    Address:Office1201#, Block C, Hanjie Headquarters International Plaza, Zhongbei Rd, Wuchang District, Wuhan

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  • n-Octyl bromide

  • Casno:

    111-83-1

    n-Octyl bromide

    Min.Order: 1 Metric Ton

    FOB Price:  USD $ 1.0-2.0/Metric Ton

    Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

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    Business Type:Manufacturers

    Tel:86-0311-66561638

    Address:Zhang zhe, guangzong county, xingtai city, hebei province

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  • 1-Bromooctane

  • Casno:

    111-83-1

    1-Bromooctane

    Min.Order: 1 Kilogram

    FOB Price:  USD $ 0.0-0.0/Kilogram

    high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

    Located in Zhengdong New District,?Zhengzhou of Henan province, Henan Allgreen Chemical Co.,Ltd is a comprehensive high-tech modern enterprises integrating professional R&D, pro

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    Tel:+86-0371-87507775

    Address:No 260 Dongming Road,Jinshui District

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  • Amadis Chemical offer CAS#111-83-1;CAT#A15118

  • Casno:

    111-83-1

    Amadis Chemical offer CAS#111-83-1;CAT#A15118

    Min.Order: 10 Milligram

    FOB Price:  USD $ 0.0-0.0/Milligram

    1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

    Founded in 2011, Amadis Chemical Company Limited is an innovative manufacturer of chemical products and technical service providers. Our business includes sales, manufacture, and s

  •  Amadis Chemical Co., Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:86-571-89925085

    Address:Watts Cosine.No.166.Xiangmao Road.

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  • Supply good quality 1-Bromooctane

  • Casno:

    111-83-1

    Supply good quality 1-Bromooctane

    Min.Order: 1 Metric Ton

    FOB Price:  USD $ 0.0-0.0/Metric Ton

    Used in organic synthesis. Appearance:Colorless liquid Storage:Stored in the ventilated, low temperature and dry room away from direct sunlight. Package:200kg/drum Application:Used in organic synthesis. Port:QINGDAO

    Founded in 2008, East Chemsources Limited is a professional manufacturer of supplier in food and beverage, pharmaceuticals, cosmetics and other industries. pharmaceutical field in

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    China (Mainland)  |  Contact Details

    Business Type:Manufacturers

    Tel:86-532-81906761

    Address:No.1581-12,Jinshui Road, Licang, Qingdao,China

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  • 1-Bromooctane

  • Casno:

    111-83-1

    1-Bromooctane

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    Chemwill Asia co.,Ltd is one of the leading manufacturer in CHINA.Our main production base is located in Xuzhou industry park. We produce a wide range of organics including Active pharmaceutical ingredients(APIs), Veterinary, Indole derivatives, Aro

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  •  Chemwill Asia Co., Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Manufacturers

    Tel:021-51086038

    Address:High-Tech Industrial park,Chemical Economical Development Zone,Xuzhou, Jiangsu-Province, P.R.China

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  • 1-Bromooctane     CAS: 111-83-1

  • Casno:

    111-83-1

    1-Bromooctane CAS: 111-83-1

    Min.Order: 5 Metric Ton

    FOB Price:  USD $ 1.0-2.0/Metric Ton

    Product Name: 1-Bromooctane Synonyms: 1-Bromoctan;1-Bromo-n-octane;1-bromo-octan;1-Octylbromid;Caprylbromide;Caprylicbromide;Octane,1-bromo-;Octoicbromide CAS: 111-83-1 M

    Welcome to Henan Sinotech! Sinotech Corporation has exceptional sourcing ability for chemicals used in Organic Fine Chemicals and APIs; Inorganic chemicals; Flame Retardants;OLED

  •  Henan Sinotech Import&Export Corporation

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    Business Type:Other

    Tel:86-371-86181678

    Address:No. 260, Dongming Road,Jinshui District

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  • 111-83-1 1-Bromooctane

  • Casno:

    111-83-1

    111-83-1 1-Bromooctane

    Min.Order: 1 Gram

    FOB Price:  USD $ 8900.0-8900.0/Gram

    Product Name: 1-Bromooctane Synonyms: 1-Bromooctane, 98+%;1-bromoctane;1-BROMOOCTANE pure;1-Bromooctane ,99%;8-Bromooctane;n-octyl nroMide;1-BroMooctane, 99% 500ML;1-BROMOOCTANE FOR SYNTHESIS 250 ML CAS: 111-83-1 MF

    Our company engages in Electronic chemicals such as OLED,Photoresist chemical,Electrolyte additive and Intermediate Pharmaceutical production; development of noble metal catalysts,

  •  Henan Tianfu Chemical Co., Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:86-371-55170693/55170694

    Address:Zhengzhou International Trade New Territory,Jinshui District,Zhengzhou ,China

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  • 1-Bromooctane/high quality/best price

  • Casno:

    111-83-1

    MSDS/COA Download

    1-Bromooctane/high quality/best price

    Min.Order: 10 Gram

    FOB Price:  USD $ 0.0-0.0/Gram

    1, High quality with competitive price: We are manufacturer and can provide high quality products with factory price. 2, Fast and safe delivery 1) Parcels can be sent out within 24 hours after payment. Tracking number is available. 2)

    Hubei Jusheng Technology Co., Ltd., is a large group corporation which engaged in the R&D and manufacture of chemicals, Pharmaceuticals and intermediates. We have earned ourselves

  •  Hubei Jusheng Technology Co., Ltd.,

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-18871490254

    Address:High-tech Industrial Park,Tianmen city,Hubei province.

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  • Factory supply top quality 99% 1-Bromooctane in stock

  • Casno:

    111-83-1

    Factory supply top quality 99% 1-Bromooctane in stock

    Min.Order: 1 Kilogram

    FOB Price:  USD $ 0.0-0.0/Kilogram

    Long-term export and transportation experience, 100% processing your order! Fast and safe delivery! Packing: 1kg, 25kg..or base on your inquiy. Appearance: Colorless liquid CAS NO.: 111-83-1 Formula: C8H17Br M.W.: 193.12

    Shaanxi Mingqi Chemical Co., Ltd is committed to the development of import and export trade in the production, operation and plant extracts of pharmaceutical raw materials and inte

  •  Shaanxi Mingqi Chemical Co., Ltd

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    Business Type:Lab/Research institutions

    Tel:18092428356

    Address:Weiyang District

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  • Top Purity CAS 111-83-1 with fast shipping

  • Casno:

    111-83-1

    Top Purity CAS 111-83-1 with fast shipping

    Min.Order: 1 Kilogram

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    WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

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  •  Zhuozhou Wenxi import and Export Co., Ltd

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-13111626072

    Address:Room 1710, Baoxin International Phase I, 19 Guanyun East Road, Zhuozhou, Hebei

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  • BLOOM TECH Advanced API/Technology support 1-Bromooctane CAS 111-83-1

  • Casno:

    111-83-1

    MSDS/COA Download

    BLOOM TECH Advanced API/Technology support 1-Bromooctane CAS 111-83-1

    Min.Order: 1 Gram

    FOB Price:  USD $ 0.0-0.0/Gram

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  •  Shaanxi BLOOM TECH Co.,Ltd

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    Business Type:Lab/Research institutions

    Tel:+86-29-86470566

    Address:Block A of Central Mansion, No.113 of Weiyang Rd, ETDZ, Xi'an, Shaanxi 710016, China

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  • CAS NO.111-83-1 1-Bromooctane

  • Casno:

    111-83-1

    MSDS/COA Download

    CAS NO.111-83-1 1-Bromooctane

    Min.Order: 10 Gram

    FOB Price:  USD $ 4.0-10.0/Gram

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    Business Type:Trading Company

    Tel:+86-27-52345788

    Address:28F,China Construction Third Bureau,Wuhan,Hubei Province, China

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  • Manufacturer of 1-Bromooctane at Factory Price

  • Casno:

    111-83-1

    Manufacturer of 1-Bromooctane at Factory Price

    Min.Order: 1 Metric Ton

    FOB Price:  USD $ 0.0-0.0/Metric Ton

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    Business Type:Trading Company

    Tel:+86-551-65418695

    Address:B911 Xincheng Business Center, Qianshan Road, Hefei Anhui China

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  • 1-Bromooctane 111-83-1

  • Casno:

    111-83-1

    1-Bromooctane 111-83-1

    Min.Order: 1 Kilogram

    FOB Price:  USD $ 0.0-0.0/Kilogram

    1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

    Shanghai Upbio Tech Co.,Ltd (Former Onchem (China)Co.,Ltd) is a comprehensive manufacturer and an international distribution of chemicals throughout the world, The predecessor of

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-21-52196435

    Address:No.2 Floor,No.979 Yunhan Rd,Nicheng,Pudong New Area,Shanghai,China

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  • 1-Bromooctane/ LIDE PHARMA- Factory supply / Best price

  • Casno:

    111-83-1

    1-Bromooctane/ LIDE PHARMA- Factory supply / Best price

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

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  •  LIDE PHARMACEUTICALS LIMITED

    China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-25-58409506

    Address:11F, Building A1, No.288 North Zhongshan Road, Gulou District, Nanjing,210003, P.R.China.

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  • Bromooctane CAS NO.111-83-1

  • Casno:

    111-83-1

    MSDS/COA Download

    Bromooctane CAS NO.111-83-1

    Min.Order: 10 Gram

    FOB Price:  USD $ 1.0-2.0/Gram

    Price, Service, Company and Transport Advantage: 1.Place of Origin China with Super quality by reasonable price. 2.Fast delivery by safe express way to all the country. 3.Has a number of highly qualified engineers a

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-431-81915458

    Address:Room 302, 47 Changping Street, Chaoyang District, Changchun, Jilin Province,China

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  • 1-Bromooctane CAS NO.: 111-83-1

  • Casno:

    111-83-1

    1-Bromooctane CAS NO.: 111-83-1

    Min.Order: 20 Metric Ton

    FOB Price:  USD $ 0.0-0.0/Metric Ton

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    Tel:+86-0431-80543058

    Address:Dianshi Plazza,Chaoyang District

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  • High purity 1-Bromooctane CAS NO.111-83-1

  • Casno:

    111-83-1

    MSDS/COA Download

    High purity 1-Bromooctane CAS NO.111-83-1

    Min.Order: 10 Milliliter

    FOB Price:  USD $ 4.0-10.0/Milliliter

    Our Service: 1. Mixed container: We can mix different items in one container. 2. Quality control: Before shipment, we can provide free sample for test. Inspection before shipping. 3. Packing: We can pack according to your requirements and als

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    Business Type:Trading Company

    Tel:+8615871419939

    Address:Guanggu Road

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  • 1-Bromooctane

  • Casno:

    111-83-1

    1-Bromooctane

    Min.Order: 1 Gram

    FOB Price:  USD $ 0.0-0.0/Gram

    Product Name: 1-Bromooctane CAS: 111-83-1 MF: C8H17Br MW: 193.12 EINECS: 203-912-9 Mol File: 111-83-1.mol 1-Bromooctane Structure 1-Bromooctane Chemical Properties Melting point -55 °C Boiling point 201 °C (lit.) d

    SHANGHAI MINSTAR CHEMICAL CO., LTD. is a leading, experienced, professional supplier of API & intermediates, plant extract, food additive, fine chemicals and industry chemicals, et

  •  Shanghai Minstar Chemical Co., Ltd

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:0086-21-18019205509

    Address:BUILDING 8, NO.1098, CHUANSHA ROAD, SHANGHAI, CHINA

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  • 1-Bromooctane,

  • Casno:

    111-83-1

    1-Bromooctane,

    Min.Order: 1 Kilogram

    FOB Price:  USD $ 1550.0-1600.0/Kilogram

    1.Coreychem focus on high complex new type intermediates and fine chemical custom synthesis,scale-up production and rare chemicals trade.Product category including Intermediates&API,Catalyst and Electronic Chemicals.Covering 811 square meters R

    Career Henan Chemical Co, based on the original Zhengzhou Cote Chemical Research Institute, be brave in absorbing highly educated talents & overseas returnees; actively responded t

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-371-86658258

    Address:Building 10 of Innovation Park, East District of the National University Science Park

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  • 1-BROMOOCTANE

  • Casno:

    111-83-1

    1-BROMOOCTANE

    Min.Order: 1 Gram

    FOB Price:  USD $ 0.0-0.0/Gram

    Betterbiochem is specialized in APIs, pharmaceutical intermediates & fine chemicals. 1. The best quality, competitive price. 2. The best service before or after shipment. 3. Rich experience in export operation. 4. Rich experience in

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-18013506594

    Address:No. 8 Building, 18 nong, Xi Yingnan Road, Pudong, Shanghai,China

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  • ISO 9001   National Research Platform CAS No.  111-83-1

  • Casno:

    111-83-1

    ISO 9001 National Research Platform CAS No. 111-83-1

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    1. Subsidiary of Institute of Chemistry, Henan Academy of Sciences, national research platform;2. About 30 years’ experience in this field since 1983;3. An experienced R&D team consisting of Doctors and Masters;4. Various types of analytical instrume

    Zhengzhou Kingorgchem Chemical Technology Co., Ltd. was founded on the basis of Organophosphorus Chemistry Lab of Institute of Chemistry Henan Academy of Sciences in 2015. The

  •  Zhengzhou Kingorgchem Chemical Technology Co., Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-371-65511936

    Address:NO.56,Hongzhuan Road

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  • 1-Bromooctane

  • Casno:

    111-83-1

    1-Bromooctane

    Min.Order: 0 Metric Ton

    FOB Price:  USD $ 0.0-0.0/Metric Ton

    Appearance:white or yellowish white flaky crystal Storage:Keep the sun from direct sunlight ;prevention against high temperature Package:As customer request Application:Used for research and industrial manufacture. Transportatio

    Triumph International Development Limilted is engaged in the API, pharmaceutical intermediates research and developmen.Adhering to the "customer first" business philosophy,we suppl

  •  Triumph International Development Limilted

    China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-536-7971999

    Address:Yinhai Road,Shouguang

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  • 1-Bromooctane

  • Casno:

    111-83-1

    1-Bromooctane

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

    Shandong Hanjiang Chemical Co., Ltd. is located in Qilu Petrochemical Industrial Park, Zibo City, Shandong Province, involving pesticide, medicine, chemical industry, coating, dy

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:18369939125

    Address:95A, Xingyuan East Road, Zhangdian District

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  • 1-Bromooctane

  • Casno:

    111-83-1

    1-Bromooctane

    Min.Order: 1 Kilogram

    FOB Price:  USD $ 0.0-0.0/Kilogram

    1,10 years exporting experience; 2.Competitive price and quality; 3,Free sample can be provided; 4,We are sincerely responsible for the"sample quality" , "product quality" and "After Service"; 5. prompt deliver

    Enbridge PharmTech Co., Ltd. is an innovative company integrated with R&D, manufacturing, marketing and distribution of intermediates and fine chemicals, mainly used to pharmaceuti

  •  EnBridge PharmTech Co., Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Manufacturers

    Tel:+86-510-83591909

    Address:Huishan Zone, Wuxi City, Jiangsu Province, P.R.China

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  • 1-Bromooctane

  • Casno:

    111-83-1

    1-Bromooctane

    Min.Order: 0

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  • 1-Bromooctane

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    1-Bromooctane

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  • 1-Bromooctane

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    1-Bromooctane

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  • Hot Sale 1-Bromo Octane

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Consensus Reports

Reported in EPA TSCA Inventory.

Specification

The IUPAC name of this chemical is 1-Bromooctane. With the CAS registry number 111-83-1 and EINECS registry number 203-912-9, it is also named as 2-Octyl bromide. In addition, the molecular formula is C8H17Br and the molecular weight is 193.12. It is a kind of clear colourless to yellow-brown liquid and belongs to the classes of Bromine Compounds; Alkyl Bromides; Monofunctional & alpha,omega-Bifunctional Alkanes; Monofunctional Alkanes; Bromine chemicals.

Physical properties about this chemical are: (1)ACD/LogP: 4.87; (2)ACD/LogD (pH 5.5): 4.87; (3)ACD/LogD (pH 7.4): 4.87; (4)ACD/BCF (pH 5.5): 2946.56; (5)ACD/BCF (pH 7.4): 2946.56; (6)ACD/KOC (pH 5.5): 10590.85; (7)ACD/KOC (pH 7.4): 10590.85; (8)#Freely Rotating Bonds: 6; (9)Polar Surface Area: 0 Å2; (10)Index of Refraction: 1.451; (11)Molar Refractivity: 46.84 cm3; (12)Molar Volume: 173.7 cm3; (13)Polarizability: 18.57 ×10-24cm3; (14)Surface Tension: 28.8 dyne/cm; (15)Density: 1.111 g/cm3; (16)Flash Point: 78.3 °C; (17)Enthalpy of Vaporization: 41.92 kJ/mol; (18)Boiling Point: 200.9 °C at 760 mmHg; (19)Vapour Pressure: 0.45 mmHg at 25°C.

Preparation of 1-Bromooctane: it can be prepared by octanol and hydrobromic acid. At first, use sulfuric acid to dissolve the sodium bromide. Then add octanol into the solution and heat it about 7-8 hours with refluxing. After the reaction, seperate the organic phase and wash it with water and concentrated sulfuric acid. You can get the product via drying and distillation. The yield is above 90%.

1-Bromooctane can be prepared by octanol and hydrobromic acid

Uses of 1-Bromooctane: it can be used in organic synthesis.And it can react with quinolin-8-ol to get 8-octyloxy-quinoline. This reaction will need reagents KOH and 2 percent Aliquat. The reaction time is 2 hours at reaction temperature of 85 °C. The yield is about 90%.

1-Bromooctane can react with quinolin-8-ol to get 8-octyloxy-quinoline

When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin. During using it, you should avoid contact with skin and eyes. And you should not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer).

You can still convert the following datas into molecular structure:
(1)SMILES: BrCCCCCCCC
(2)InChI: InChI=1/C8H17Br/c1-2-3-4-5-6-7-8-9/h2-8H2,1H3
(3)InChIKey: VMKOFRJSULQZRM-UHFFFAOYAC

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rabbit LD50 skin 8mL/kg (8mL/kg)   American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969.
rat LD50 oral 4490uL/kg (4.49mL/kg)   American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969.