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12122-67-7

Basic Information
CAS No.: 12122-67-7
Name: Zineb
Article Data: 64
Cas Database
Molecular Structure:
Molecular Structure of 12122-67-7 (Zineb)
Formula: C4H6N2S4Zn
Molecular Weight: 275.759
Synonyms: Blizene;Zebenide;Carbadine;Hexathane;[2-(sulfidocarbothioylamino)ethylamino]methanedithioate; zinc(+2) cation;Zebtox;Lonacol;Bonzeb;Zinosan;ENT 14,874;ZIDAN;Aspor;Novozir N;Parzate zineb;Discon;Turbair Zineb Fungicide;Dipher;Zinc,[[2-[(dithiocarboxy)amino]ethyl]- carbamodithioato(2-)-kS,kS']-;Funjeb;Tritoftorol;Curit;Perozin;Crittox;Dithane Z 78;Phytox;Tiezene;Unizeb;Polyram Z;Lirotan;Fungo-Pulvit;Indofil Z 78;Cynkotox;
EINECS: 235-180-1
Density: 1.74 g/cm3
Melting Point: 157ºC (decomposes)
Boiling Point: 308.2 °C at 760 mmHg
Flash Point: 140.2 °C
Solubility: ca.10 mg l-1 (room temperature)
Appearance: off-white powder
Hazard Symbols: IrritantXi
Risk Codes: 37-43
Safety: 8-24/25-46
Transport Information: N/A
PSA: 88.24000
LogP: 0.60850
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    Common Name: Zineb Molecular Formula: (C4H6N2S4Zn)x Molecular Weight: 275.75 Chemical Name: zinc ethylenebis(dithiocarbamate) Structure Formula: CAS RN: 12122-67-7 Physical & Chemical Character: Greyis

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Chemistry

Structure of Zineb (CAS NO.12122-67-7):

Molecular Formula: C4H6N2S4Zn
Molar mass: 275.7728 g/mol
Flash Point: 140.2 °C
Boiling Point: 308.2 °C at 760 mmHg
Vapour Pressure: 0.000692 mmHg at 25°C
Appearance: Light colored powder
H-Bond Donor: 2
H-Bond Acceptor: 2
IUPAC Name: Zinc N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate 
Canonical SMILES: C(CNC(=S)[S-])NC(=S)[S-].[Zn+2]
InChI: InChI=1S/C4H8N2S4.Zn/c7-3(8)5-1-2-6-4(9)10;/h1-2H2,(H2,5,7,8)(H2,6,9,10);/q;+2/p-2 
InChIKey: AMHNZOICSMBGDH-UHFFFAOYSA-L
Polarizability:10-24cm3
Boiling point: 308.2°C
Flash point: 140.2°C
Solubility in water:  Insoluble in water 
Storage temp:  2-8°C   

Uses

 Uses of Zineb (CAS NO.12122-67-7) include control of downy mildews, rusts and redfire disease. In the US it was once registered as a "General Use Pesticide", however all registrations were voluntarily cancelled following an EPA special review. It continues to be used in many other countries.

Production

  Zineb (CAS NO.12122-67-7) is produced by reacting Ethylene bis(dithiocarbamate) sodium salt, Nabam, with Zinc sulfate . This can be carried out by mixing nabam and zinc sulfate in the spray tank.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
human LDLo oral 5gm/kg (5000mg/kg)   "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A420, Pg. 1984,
mammal (species unspecified) LD50 unreported 1350mg/kg (1350mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 45(5), Pg. 29, 1980.
mouse LD50 intraperitoneal 1940mg/kg (1940mg/kg)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 121, 1982.
mouse LD50 oral 7600mg/kg (7600mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
BEHAVIORAL: EXCITEMENT
BEHAVIORAL: ATAXIA
Journal of Toxicology and Environmental Health. Vol. 4, Pg. 93, 1978.
 
rabbit LD50 oral 4450mg/kg (4450mg/kg)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 121, 1982.
rat LCLo inhalation 800mg/m3/4H (800mg/m3)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 121, 1982.
rat LD50 oral 1850mg/kg (1850mg/kg) BEHAVIORAL: EXCITEMENT
GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 31(10), Pg. 25, 1966.
rat LD50 skin > 2500mg/kg (2500mg/kg)   Toxicology and Applied Pharmacology. Vol. 14, Pg. 515, 1969.
rat LD50 unreported 1850mg/kg (1850mg/kg)   Environmental Quality and Safety, Supplement. Vol. 3, Pg. 618, 1975.

Safety Profile

Hazard Codes: Xi 
Risk Statements: 37-43
R37: Irritating to the respiratory system 
R43: May cause sensitization by skin contact
Safety Statements:  8-24/25-46
S8: Keep container dry
S24: Avoid contact with skin 
S25: Avoid contact with eyes
S46: If swallowed, seek medical advice immediately and show this container or label.  

Specification

 Zineb ,its cas register number is 12122-67-7. It also can be called Carbamodithioic acid, N,N'-1,2-ethanediylbis-, zinc salt (1:1) ; Zinc 1,2-ethanediyldicarbamodithioate ; Zinc ethane-1,2-diylbis(dithiocarbamate) ; 1,2-Ethanediylbiscarbamodithioic acid zinc complex and carbamodithioic acid, 1,2-ethanediylbis-, zinc salt (1:1) . Zineb (CAS NO.12122-67-7) is a foliate fungicide and is a polymeric complex of zinc with the ethylene bis(dithiocarbamate) anionic ligand. Ethylene bis(dithiocarbamate) (Maneb) was included in a biocide ban proposed by the Swedish Chemicals Agency and approved by the European Parliament in January 13, 2009.