12122-67-7 Usage
Description
Zineb is a light-coloured powder/crystal and insoluble in water. Zineb is one of the nonsystemic
(surface-acting) fungicides of the group ethylenebisdithiocarbamates (EBDCs).
Zineb is a polymer of ethylene (bis)thiocarbamate units linked with zinc and used for the
control and prevention of crop damage in the field and also to protect harvested crops from
deterioration during storage or transport. Zineb was used to protect fruit and vegetable
crops from a wide range of foliar and other diseases. It was available in the United States
as wettable powder and dust formulations. Zineb can be formed by combining nabam and
zinc sulphate in the spray tank.
Chemical Properties
Pure product is white crystal, industrial product is white to light yellow powder. Soluble in carbon disulfide and pyridine, insoluble in most organic solvents, insoluble in water (10mg/L). It is unstable to light, heat and humidity, and decomposes easily when it meets alkaline substances or copper. The decomposition products of zineb include ethylene thiourea, which is more toxic.
Uses
Different sources of media describe the Uses of 12122-67-7 differently. You can refer to the following data:
1. Zineb is a contact fungicide that provides protection against a
wide variety of fungal diseases (including leaf spots, blights, rust, downy
mildew, scab, etc.) in field crops, fruits, vines, vegetables, ornamentals,
citrus and bananas.
2. Zineb is a light-colored powder or crystal. It is a polymer of ethylene (bis) thiocarbamate units linked with zinc. Zineb is used to prevent crop damage in the field and to protect harvested crops from deterioration during storage or transport. It was used to protect fruit and vegetable crops from a wide range of foliar and other diseases. It was available in the United States as wettable powder and dust formulations. Zineb can be formed by combining nabam and zinc sulfate in a spray tank.
Definition
ChEBI: Zineb is a polymeric complex of zinc with the ethylene bis(dithiocarbamate) anionic ligand. Formerly used as an agricultural fungicide for the control of downy mildews and rusts, its use is no longer permitted in the US or the EU. It has a role as an antifungal agrochemical. It is a macromolecule, a zinc coordination entity and a dithiocarbamate salt. It contains an ethylenebis(dithiocarbamate).
General Description
An off-white powder. Used as a fungicide.
Air & Water Reactions
Decomposes gradually, accelerated by exposure to air, moisture, and heat. Insoluble in water. Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids.
Reactivity Profile
Zineb is a zinc salt of a dithiocarbamic acid. May generate flammable gases with aldehydes, nitrides, and hydrides. Incompatible with acids, peroxides, and acid halides.
Hazard
Toxic by inhalation and ingestion; irritant
to eyes and mucous membranes. Questionable carcinogen.
Fire Hazard
Flash point data for Zineb are not available, but Zineb is probably combustible.
Contact allergens
Zineb is a pesticide of the dithiocarbamate group.
Sensitization can occur in gardeners and florists.
Metabolic pathway
Zineb and other alkylenebis( dithiocarbamate) fungicides are degraded
and metabolised via a common pathway. The primary degradation
reaction of zineb in water, soil, plants and animals involves the initial
dissociation of the metal complex and decomposition to numerous degradation
products including ethylenethiourea (ETU) and ethyleneurea (EU)
as major products (Scheme 1).
Purification Methods
Crystallise this herbicide several times from hot toluene or from hot CHCl3 by addition of EtOH. It is a skin irritant. [Beilstein 4 III 149, 4 IV 234.]
Degradation
[14C-ethylene]Zineb(1) was decomposed mainly to ETU (2) in an aqueous
suspension after 14 days via the 5,6-dihydro-3H-imidazo[2,1-c]-1,2,4-
dithiazole-3-thione (3) intermediate (Vonk, 1976). In dilute alkaline solution
and in the presence of light, heat and moisture, zineb decomposed
rapidly to compound 3 (Marshall, 1978). ETU (2) in aqueous solutions
was further converted into 2-imidazoline (4) and EU (5) (kaars Sijpesteijn
and Vonk, 1974). Zineb decomposed in sterile marine culture medium to
yield ETU (2) and compound 3. In the presence of copper, an additional
degradation product, ethylene diisothiocyanate (6), was also observed
(Hunter and Evans, 1991).
Check Digit Verification of cas no
The CAS Registry Mumber 12122-67-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,2,1,2 and 2 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 12122-67:
(7*1)+(6*2)+(5*1)+(4*2)+(3*2)+(2*6)+(1*7)=57
57 % 10 = 7
So 12122-67-7 is a valid CAS Registry Number.
InChI:InChI=1/C4H8N2S4.Zn/c7-3(8)5-1-2-6-4(9)10;/h1-2H2,(H2,5,7,8)(H2,6,9,10);/q;+2/p-1/rC4H6N2S4Zn/c7-3(8)5-1-2-6-4-9-11-10-4/h6H,1-2H2,(H-,5,7,8)/p+1
12122-67-7Relevant articles and documents
Iminoacetic acid amides and their use as pest control agents
-
, (2008/06/13)
PCT No. PCT/EP96/04345 Sec. 371 Date Apr. 15, 1998 Sec. 102(e) Date Apr. 15, 1998 PCT Filed Oct. 7, 1996 PCT Pub. No. WO97/14673 PCT Pub. Date Apr. 24, 1997Iminoacetamides of the formula (I) in which A represents a single bond or optionally substituted alkylene, Q represents oxygen or sulphur, R1 represents respectively optionally substituted cycloalkyl, cycloalkenyl, aryl or heterocyclyl, R2 represents respectively optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, aryl or heterocyclyl, R3 represents hydrogen or respectively optionally substituted alkyl, alkenyl, alkinyl or cycloalkyl, R4 represents respectively optionally substituted cycloalkyl, cycloalkenyl, aryl or heterocyclcyl a process for their preparation, pesticidal compositions containing them, and their use for controlling pests.
Halogen alkenyl azolyl microbicides
-
, (2008/06/13)
Novel halogenoalkenyl-azolyl derivatives of the formula STR1 in which R1 represents optionally substituted alkyl, optionally substituted alkenyl, optionally substituted cycloalkyl, optionally substituted aryl or represents optionally substituted heteroaryl, R2 represents alkyl, halogenoalkyl, 1-hydroxyalkyl, 2-hydroxyalkyl, 1-hydroxyhalogenalkyl, 1-alkenyl or 2-alkenyl, X1 represents fluorine, chlorine, bromine or iodine, X2 represents fluorine, chlorine, bromine or iodine, and Y represents nitrogen or a CH group, and addition products thereof with acids or metal salts are very active as microbicides in plant protection and in the protection of materials.
Acylated 5-aminopyrazoles and the use thereof to combat animal parasites
-
, (2008/06/13)
The present invention relates to new acylated 5-aminopyrazoles of the formula (I) STR1 in which R1, R2, R3, R4 and R5 have the meaning given in the description, to processes for their preparation and to their use as pesticides.
