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124-94-7

Basic Information
CAS No.: 124-94-7
Name: Pregna-1,4-diene-3,20-dione,9-fluoro-11,16,17,21-tetrahydroxy-, (11b,16a)-
Molecular Structure:
Molecular Structure of 124-94-7 (Pregna-1,4-diene-3,20-dione,9-fluoro-11,16,17,21-tetrahydroxy-, (11b,16a)-)
Formula: C21H27FO6
Molecular Weight: 434.50
Synonyms: 11b,16a,17a,21-Tetrahydroxy-9a-fluoro-1,4-pregnadiene-3,20-dione;9-Fluoro-11b,16a,17,21-tetrahydroxypregna-1,4-diene-3,20-dione;9a-Fluoro-16a-hydroxyprednisolone;Adcortyl;CL 19823;Cinolone;Fluoxyprednisolone;Kenacort;Ledercort;Mycolog;NSC13397;Omicilon;Polcortolon;Rodinolone;Triamcinlon;Triamcinolone;Tricortale;Volon;
EINECS: 204-718-7
Density: 1.42 g/cm3
Melting Point: 262-263 °C(lit.)
Boiling Point: 587.5 °C at 760 mmHg
Flash Point: 309.1 °C
Solubility: 79.99mg/L(25 oC)
Appearance:
Hazard Symbols: HarmfulXn
Risk Codes: 40
Safety: 22-36
Transport Information:
PSA: 115.06000
LogP: 0.62050
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Chemistry

Molecular Formula: C21H27FO6
Molar mass: 394.44 g/mol
EINECS: 204-718-7
Density: 1.42 g/cm3
Flash Point: 309.1 °C
Index of Refraction: 1.617
Boiling Point: 587.5 °C at 760 mmHg
Vapour Pressure: 3E-16 mmHg at 25°C
Melting point: 260-263 ºC (dec.)
Synonyms of Triamcinolone (124-94-7): (8S,9R,10S,11S,13S,14S,16R,17S)-9-fluoro-11,16,17-trihydroxy-17-(2-hydroxyacetyl)-10,13-dimethyl-6,7,8,9,10,11,12,13,14,15,16,17-dodecahydro-3H-cyclopenta[a]phenanthren-3-one ;  (1R,2S,10S,11S,13R,14S,15S,17S)-1-fluoro-13,14,17-trihydroxy-14-(2-hydroxyacetyl)-2,15-dimethyltetracyclo[8.7.0.02,7.011,15]heptadeca-3,6-dien-5-one
Structure of Triamcinolone (124-94-7):

XLogP3-AA: 1.2
H-Bond Donor: 4
H-Bond Acceptor: 7
IUPAC Name: (8S,9R,10S,11S,13S,14S,16R,17S)-9-Fluoro-11,16,17-trihydroxy-17-(2-hydroxyacetyl)-10,13-dimethyl-6,7,8,11,12,14,15,16-octahydrocyclopenta[a]phenanthren-3-one
Canonical SMILES: CC12CC(C3(C(C1CC(C2(C(=O)CO)O)O)CCC4=CC(=O)C=CC43C)F)O
Isomeric SMILES: C[C@]12C[C@@H]([C@]3([C@H]([C@@H]1C[C@H]([C@@]2(C(=O)CO)O)O)CCC4=CC(=O)C=C[C@@]43C)F)O
InChI: InChI=1S/C21H27FO6/c1-18-6-5-12(24)7-11(18)3-4-13-14-8-15(25)21(28,
17(27)10-23)19(14,2)9-16(26)20(13,18)22/h5-7,13-16,23,25-26,28H,3-4,8-10H2,1-2H3/t13-,14-,15+,16-,18-,19-,20-,21-/m0/s1 
InChIKey: GFNANZIMVAIWHM-OBYCQNJPSA-N

Uses

 Triamcinolone (124-94-7) is used in the post-operative period of certain cosmetic surgery procedures, notably rhinoplasty. Injected into the subcutaneous area, it may help to alleviate stubborn swelling, scar tissue, and inflamed sebaceous cysts.It is occasionally used to treat lichen planus and severe cases of hayfever, and may also be used to treat diabetic retinopathy.It is highly effective in the most severe cases of eczema, but may require a waiting period before subsequent treatments.Inaddition, it can be used in case of severe arthritis, Lumbago sciatica.

Toxicity Data With Reference

1.    

oms-hmn-orl 428 µg/kg

    ARDEAC    Archives of Dermatology. 103 (1971),39.
2.    

scu-rat LD50:99 mg/kg

    TXAPA9    Toxicology and Applied Pharmacology. 8 (1966),250.

Safety Profile

Poison by subcutaneous route. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits toxic fumes of F. An anti-inflammatory and antiallergic agent.
 

Hazard Codes: Xn
Risk Statements:
40:  Limited evidence of a carcinogenic effect
Safety Statements:
22:  Do not breathe dust
36:  Wear suitable protective clothing

Specification

Triamcinolone (124-94-7) (trade names Kenalog, Aristocort, Nasacort, Tri-Nasal, Triderm, Azmacort, Trilone, Volon A, Tristoject, Fougera, Tricortone,Triesence) is a synthetic corticosteroid given orally, by inhalation, injection, or as a topical ointment or cream.
Its side effects include nosebleeds, a sore throat, increased headache, coughing, and runny nose. White patches in the throat or nose indicates a serious side effect. Symptoms of an allergic reaction include itch, rash, severe dizziness, swelling, trouble breathing.