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CAS No.: | 1271-03-0 |
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Name: | Cyclopentadienyl allyl palladiuM |
Article Data: | 8 |
Molecular Structure: | |
Formula: | C8H10 Pd |
Molecular Weight: | 212.587 |
Synonyms: | Palladium,(h5-2,4-cyclopentadien-1-yl)(h3-2-propenyl)- (9CI); Palladium,allylcyclopentadienyl- (6CI); Palladium, p-allyl-p-cyclopentadienyl- (8CI); Palladium, p-allylcyclopentadienyl- (7CI); (h3-Allyl)(cyclopentadienyl)palladium;(h3-Allyl)(h5-cyclopentadienyl)palladium; (h5-h5-Cyclopentadienyl)(h3-cyclopropyl)palladium;Allyl(cyclopentadienyl)palladium; Allyl(h5-cyclopentadienyl)palladium; p-Allyl-p-cyclopentadienylpalladium; p-Cyclopentadienyl-p-allylpalladium |
Density: | g/cm3 |
Melting Point: | 60-62 °C |
Boiling Point: | 41.5°Cat760mmHg |
Flash Point: | °C |
PSA: | 0.00000 |
LogP: | 2.26300 |
Conditions | Yield |
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In tetrahydrofuran; benzene at -20 - 20℃; for 1.5h; Inert atmosphere; Schlenk technique; | 99% |
allyl(cyclopentadiene)palladium(II)
Conditions | Yield |
---|---|
In tetrahydrofuran at 20℃; for 0.5h; Inert atmosphere; | 95% |
With sodium In tetrahydrofuran; benzene at -10 - -2℃; for 2h; Inert atmosphere; Glovebox; | 92% |
In tetrahydrofuran at -60 - 20℃; for 0.75h; | |
In tetrahydrofuran at 0℃; Inert atmosphere; |
Conditions | Yield |
---|---|
In tetrahydrofuran at -78 - 20℃; Inert atmosphere; | 95% |
allyl(cyclopentadiene)palladium(II)
Conditions | Yield |
---|---|
In tetrahydrofuran; toluene addn. of LiC5H5 in THF to Pd-complex in toluene, stirring (several h); solvent removal (vac.), sublimation (45°C, 1E-3 Torr);; | 70% |
allyl(cyclopentadiene)palladium(II)
Conditions | Yield |
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With lithium cyclopentadienide In tetrahydrofuran; toluene at -30 - 20℃; for 1h; Inert atmosphere; |
polytetrafluoroethylene
allyl(cyclopentadiene)palladium(II)
1,4-bis(dicyclohexylphosphino)butane
(η2-tetrafluoroethylene)Pd(1,4-bis(dicyclohexylphosphino)butane)
Conditions | Yield |
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In toluene at 20℃; under 760.051 Torr; for 3h; Inert atmosphere; | 100% |
allyl(cyclopentadiene)palladium(II)
tert-butylisonitrile
bis(tert-butyl isocyanide) palladium(0)
Conditions | Yield |
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In pentane Ar-atmosphere; modified procedure from J. Am. Chem. Soc. 1969, 91, 6994;addn. of excess of isocyanide to soln. of Pd-complex at -10°C, s tirring for 10 min; evapn., washing (pentane), drying (vac.); | 99% |
In pentane (Ar); -10°C, 30 min; supernatant liq. removal, solid washing (pentane), drying (vac.); | 99% |
allyl(cyclopentadiene)palladium(II)
4-iodoanisol
triphenylphosphine
(2-methoxyphenyl)Pd(P(C6H5)3)2I
Conditions | Yield |
---|---|
In dichloromethane Ar-atmosphere; stirring (room temp., 5 - 15 min); filtering (PTFE membrane), crystn. on concg. and hexane addn. (-30°C, overnight), filtering, drying (vac.); elem. anal.; | 99% |
Conditions | Yield |
---|---|
In pentane Ar-atmosphere; modified procedure from J. Am. Chem. Soc. 1969, 91, 6994;addn. of excess of isocyanide to soln. of Pd-complex at -10°C, s tirring for 10 min; evapn., washing (pentane), drying (vac.); | 99% |
allyl(cyclopentadiene)palladium(II)
1,1,3,3-tetramethylbutyl isocyanide
Pd(CNC(CH3)2C(CH3)3)2
Conditions | Yield |
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In pentane Ar-atmosphere; modified procedure from J. Am. Chem. Soc. 1969, 91, 6994;addn. of excess of isocyanide to soln. of Pd-complex at -10°C, s tirring for 10 min; evapn., washing (pentane), drying (vac.); | 99% |