Name: Cyclopentadienyl allyl palladiuM
SKU: 1271-03-0

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Pharmaceutical (32)
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Basic Information

Molecular Structure:
CAS No.:	1271-03-0
Name:	Cyclopentadienyl allyl palladiuM

Formula:	C8H10 Pd
Molecular Weight:	212.587
Synonyms:	Palladium,(h5-2,4-cyclopentadien-1-yl)(h3-2-propenyl)- (9CI); Palladium,allylcyclopentadienyl- (6CI); Palladium, p-allyl-p-cyclopentadienyl- (8CI); Palladium, p-allylcyclopentadienyl- (7CI); (h3-Allyl)(cyclopentadienyl)palladium;(h3-Allyl)(h5-cyclopentadienyl)palladium; (h5-h5-Cyclopentadienyl)(h3-cyclopropyl)palladium;Allyl(cyclopentadienyl)palladium; Allyl(h5-cyclopentadienyl)palladium; p-Allyl-p-cyclopentadienylpalladium; p-Cyclopentadienyl-p-allylpalladium
Density:	g/cm³
Melting Point:	60-62 °C
Boiling Point:	41.5°Cat760mmHg
Flash Point:	°C
PSA:	0.00000
LogP:	2.26300

Synthetic route

: bis(η3-allyl-μ-chloropalladium(II))

: 4984-82-1
sodium cyclopentadienylide

: 1271-03-0
allyl(cyclopentadiene)palladium(II)

Conditions

Conditions	Yield
In tetrahydrofuran; benzene at -20 - 20℃; for 1.5h; Inert atmosphere; Schlenk technique;	99%

: bis(η3-allyl-μ-chloropalladium(II))

: sodium cyclopentadienide

: 1271-03-0
allyl(cyclopentadiene)palladium(II)

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; for 0.5h; Inert atmosphere;	95%
With sodium In tetrahydrofuran; benzene at -10 - -2℃; for 2h; Inert atmosphere; Glovebox;	92%
In tetrahydrofuran at -60 - 20℃; for 0.75h;
In tetrahydrofuran at 0℃; Inert atmosphere;

: bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]

: 4984-82-1
sodium cyclopentadienylide

: 1271-03-0
allyl(cyclopentadiene)palladium(II)

Conditions

Conditions	Yield
In tetrahydrofuran at -78 - 20℃; Inert atmosphere;	95%

: bis(η3-allyl-μ-chloropalladium(II))

: lithium cyclopentadienide

: 1271-03-0
allyl(cyclopentadiene)palladium(II)

Conditions

Conditions	Yield
In tetrahydrofuran; toluene addn. of LiC5H5 in THF to Pd-complex in toluene, stirring (several h); solvent removal (vac.), sublimation (45°C, 1E-3 Torr);;	70%

: bis(η3-allyl-μ-chloropalladium(II))

: 1271-03-0
allyl(cyclopentadiene)palladium(II)

Conditions

Conditions	Yield
With lithium cyclopentadienide In tetrahydrofuran; toluene at -30 - 20℃; for 1h; Inert atmosphere;

: 116-14-3
polytetrafluoroethylene

: 1271-03-0
allyl(cyclopentadiene)palladium(II)

: 65038-36-0
1,4-bis(dicyclohexylphosphino)butane

: 1445270-22-3
(η2-tetrafluoroethylene)Pd(1,4-bis(dicyclohexylphosphino)butane)

Conditions

Conditions	Yield
In toluene at 20℃; under 760.051 Torr; for 3h; Inert atmosphere;	100%

...Expand

: 1271-03-0
allyl(cyclopentadiene)palladium(II)

: 119072-55-8, 7188-38-7
tert-butylisonitrile

: 24859-25-4
bis(tert-butyl isocyanide) palladium(0)

Conditions

Conditions	Yield
In pentane Ar-atmosphere; modified procedure from J. Am. Chem. Soc. 1969, 91, 6994;addn. of excess of isocyanide to soln. of Pd-complex at -10°C, s tirring for 10 min; evapn., washing (pentane), drying (vac.);	99%
In pentane (Ar); -10°C, 30 min; supernatant liq. removal, solid washing (pentane), drying (vac.);	99%

: 1271-03-0
allyl(cyclopentadiene)palladium(II)

: 529-28-2
4-iodoanisol

: 603-35-0
triphenylphosphine

: 180891-47-8
(2-methoxyphenyl)Pd(P(C6H5)3)2I

Conditions

Conditions	Yield
In dichloromethane Ar-atmosphere; stirring (room temp., 5 - 15 min); filtering (PTFE membrane), crystn. on concg. and hexane addn. (-30°C, overnight), filtering, drying (vac.); elem. anal.;	99%

...Expand

: 1271-03-0
allyl(cyclopentadiene)palladium(II)

: 598-45-8
i-propyl isocyanide

: 93224-59-0
Pd(CN-i-Pr)2

Conditions

Conditions	Yield
In pentane Ar-atmosphere; modified procedure from J. Am. Chem. Soc. 1969, 91, 6994;addn. of excess of isocyanide to soln. of Pd-complex at -10°C, s tirring for 10 min; evapn., washing (pentane), drying (vac.);	99%

: 1271-03-0
allyl(cyclopentadiene)palladium(II)

: 150043-29-1
1,1,3,3-tetramethylbutyl isocyanide

: 176104-88-4
Pd(CNC(CH3)2C(CH3)3)2

Conditions

Conditions	Yield
In pentane Ar-atmosphere; modified procedure from J. Am. Chem. Soc. 1969, 91, 6994;addn. of excess of isocyanide to soln. of Pd-complex at -10°C, s tirring for 10 min; evapn., washing (pentane), drying (vac.);	99%

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