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128-80-3

Basic Information
CAS No.: 128-80-3
Name: Solvent Green 3
Article Data: 26
Molecular Structure:
Molecular Structure of 128-80-3 (Solvent Green 3)
Formula: C28H22N2O2
Molecular Weight: 418.495
Synonyms: 1,4-Bis(4'-methylanilino)anthraquinone;1,4-Bis[(4-methylphenyl)amino]anthraquinone;1,4-Di-p-toluidinoanthraquinone;AlizarineCyanine Green G Fat Soluble;Anthraquinone Green G Base;Arlosol Green BS;Brown 921;C.I. 61565;C.I. SolventGreen 3;Cyanine Green G base;C Green No. 6;FD and C Green no. 6;Fat SolubleAnthraquinone Green;Fat Soluble Green Anthraquinone;Green 6;Kayaset Green A-B;NSC 84207;Oil Green 530;Oil Green 5602;Oplas Green 533;Organol Green J;Quinazarin green;Quinizarine Green Base;Solvent Green3;Sumiplast Green G;Waxoline Green6GFW;
EINECS: 204-909-5
Density: 1.292 g/cm3
Melting Point: 220-221 °C
Boiling Point: 633.8 °C at 760 mmHg
Flash Point: 197 °C
Solubility: 10μg/L at 25℃
Appearance: black fine crystalline powder
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 24/25-22-26
PSA: 58.20000
LogP: 6.71200
Synthetic route
81-64-1

1,4-dihydroxy-9,10-anthracenedione

106-49-0

p-toluidine

128-80-3

D and C green 6

Conditions
ConditionsYield
With leucoquinizarin; boric acid; sodium hydrogensulfite In ethanol; benzene at 62 - 66℃; for 12h; Temperature; Solvent;97%
With 1-butyl-3-ethyl-1H-imidazolium tetrafluoroborate at 85 - 125℃; Reagent/catalyst; Temperature; Green chemistry; Large scale;95.9%
With boric acid; calcium carbonate; tin(ll) chloride at 110 - 130℃;
602-25-5

1,4-dichloroanthraquinone

106-49-0

p-toluidine

128-80-3

D and C green 6

Conditions
ConditionsYield
With potassium phosphate In ethylbenzene at 150℃; for 6h;90%
at 190℃;
6119-74-0

1,4-dimethoxyanthraquinone

106-49-0

p-toluidine

128-80-3

D and C green 6

17648-03-2

9,10-Dihydroxy-2,3-dihydro-anthracene-1,4-dione

106-49-0

p-toluidine

128-80-3

D and C green 6

Conditions
ConditionsYield
With boric acid
With 1,4-dihydroxy-9,10-anthracenedione
128-95-0

1,4-diamino-9,10-anthraquinone

106-49-0

p-toluidine

128-80-3

D and C green 6

Conditions
ConditionsYield
With tin(ll) chloride
5327-72-0

1,4-diamino-anthracene-9,10-diol

106-49-0

p-toluidine

128-80-3

D and C green 6

Conditions
ConditionsYield
Erhitzen unter Luftzutritt auf 150grad;
117499-93-1

1-chloro-4-dimethylamino-anthraquinone

106-49-0

p-toluidine

A

128-85-8

1-(methylamino)-4-[(4-methylphenyl)amino]anthraquinone

B

128-80-3

D and C green 6

Conditions
ConditionsYield
at 180℃;
6337-82-2

1-Nitro-4-chloroanthraquinone

106-49-0

p-toluidine

128-80-3

D and C green 6

Conditions
ConditionsYield
With boric acid; sodium carbonate; tin(ll) chloride
81-66-3

1-methoxy-4-nitro-anthraquinone

106-49-0

p-toluidine

128-80-3

D and C green 6

Conditions
ConditionsYield
at 160 - 180℃;
80490-02-4

1-methoxy-4-phenoxy-anthraquinone

106-49-0

p-toluidine

128-80-3

D and C green 6

Downstream Products
3443-90-1
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Chemistry

Product Name: Solvent green 3 (CAS NO.128-80-3)


Molecular Formula: C28H22N2O2
Molecular Weight: 418.49g/mol
Mol File: 128-80-3.mol
Einecs: 204-909-5
Appearance: Black fine crystalline powder
Melting Point: 220-221 °C
Boiling point: 633.8 °C at 760 mmHg
Flash Point: 197 °C
Density: 1.292 g/cm3
Water Solubility: Insoluble
Surface Tension: 63 dyne/cm
Enthalpy of Vaporization: 93.69 kJ/mol
Vapour Pressure: 5.73E-16 mmHg at 25°C
XLogP3-AA: 7.8
H-Bond Donor: 2
H-Bond Acceptor: 4
Product Categories: Aminoanthraquinones; Anthraquinones; Solvent Dyestuff

Uses

 Solvent green 3 (CAS NO.128-80-3) is used for adding greenish coloring to materials. It is used in cosmetics and medications. It is used in some colored smoke formulations, in both old and new ones; when inhaled, it clears very slowly from the lung, with half time of 280 days.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LD50 intratracheal 250mg/kg (250mg/kg)   "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 1330, 1986.
rat LD50 oral 3660mg/kg (3660mg/kg)   "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 1330, 1986.

Safety Profile

Safety Information of Solvent green 3 (CAS NO.128-80-3):
Hazard Codes: Xi
Risk Statements: 36/37/38
36:  Irritating to the eyes 
37:  Irritating to the respiratory system
38:  Irritating to the skin  
Safety Statements: 24/25-22-26
22:  Do not breathe dust  
24:  Avoid contact with skin 
25:  Avoid contact with eyes 
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 

Specification

 Solvent green 3 ,its CAS NO. is 128-80-3,the synonyms is Sudan green 4b ; Quinizarin green ss ; Quinazarine green base ; Quinizarin green ; Waxoline green g ; 1,4-Bis((4-methylphenyl)amino)-10-anthracenedione ; 1,4-Bis((4-methylphenyl)amino)-9,10-anthracenedione .