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1646-75-9

Basic Information
CAS No.: 1646-75-9
Name: ALDICARB-OXIME
Article Data: 4
Molecular Structure:
Molecular Structure of 1646-75-9 (ALDICARB-OXIME)
Formula: C5H11 N O S
Molecular Weight: 133.214
Synonyms: Propionaldehyde,2-methyl-2-(methylthio)-, oxime (7CI,8CI);2-(Methylthio)-2-methylpropionaldehyde oxime; 2-Methyl-2-(methylthio)propanaloxime; 2-Methyl-2-(methylthio)propionaldehyde oxime;2-Methyl-2-(methylthio)propionaldoxime; Aldicarb oxime; Temik oxime
Density: 1g/cm3
Melting Point: 21.1°C
Boiling Point: 210.5°Cat760mmHg
Flash Point: 81.1°C
Safety: Poison by intraperitoneal route. Moderately toxic by ingestion, skin contact and inhalation routes. Mutation data reported. When heated to decomposition it emits toxic vapors of SOx.
PSA: 57.89000
LogP: 1.58800
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Chemistry

Chemistry informtion about 2-Methyl-2-(Methylthio)Propanal Oxime (CAS NO.1646-75-9) is:
IUPAC Name: (Ne)-N-(2-Methyl-2-Methylsulfanylpropylidene)Hydroxylamine
Synonyms: 2-Methyl-2-(Methylthio)Propionaldehydeoxime ; Aldicarb-Oxime ; Propanal, 2-Methyl-2-(Methylthio)-, Oxime ; Propionaldehyde, 2-Methyl-2-(Methylthio)-, Oxime. ; 2-Methyl-2-(Methylthio)-Propanal Oxime
MF: C5H11NOS
MW: 133.21
EINECS: 216-709-5 
Density: 1 g/cm3
Flash Point: 81.1 °C
Boiling Point: 210.5 °C at 760 mmHg
Vapour Pressure: 0.0762 mmHg at 25°C 
Enthalpy of Vaporization: 49.23 kJ/mol
Storage temp.: 0-6°C
Following is the molecular structure of 2-Methyl-2-(Methylthio)Propanal Oxime (CAS NO.1646-75-9) is:

Production

Raw Materials are Isobutylene --> Isobutyraldehyde --> Hydroxylamine Sulfate --> Sodium Thiomethoxide --> Storage Tank --> 2-Chloro-2-Methyl Propanal Oxime Dimer --> Vacuum/Pressure Econo-Pump:Vacuum(In Hg),20:Max Pressure(Psig),18:Tubin Adapters(In),3/8:Lxwxh(In),7x4x5:Volt,115:Hz,60--> Nitrosyl Chloride .
Preparation Products is Aldicarb.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LDLo intraperitoneal 100mg/kg (100mg/kg)   Office of Toxic Substances Report. Vol. FYI-OTS-0885-0443,
rabbit LD50 skin 1900mg/kg (1900mg/kg)   Office of Toxic Substances Report. Vol. FYI-OTS-0885-0443,
rat LC50 inhalation 1230mg/m3/4H (1230mg/m3) sense organs and special senses: lacrimation: eye lungs, thorax, or respiration: dyspnea Office of Toxic Substances Report. Vol. FYI-OTS-0885-0443,
rat LD50 oral 742mg/kg (742mg/kg) sense organs and special senses: lacrimation: eye sense organs and special senses: chromodacyrorrea: eye behavioral: food intake (animal) Office of Toxic Substances Report. Vol. FYI-OTS-0885-0443,

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion, skin contact and inhalation routes. Mutation data reported. When heated to decomposition it emits toxic vapors of SOx.

Specification

2-Methyl-2-(Methylthio)Propanal Oxime (CAS NO.1646-75-9) is a clear colorless,viscous liquid with an unpleasant sulfurous or musty odor.It is sensitive to heat and water soluble. It may decompose with prolonged exposure to moisture.It is incompatible with oxidizers, acids and alkalis [(NTP, 1992]. Several explosions or violent decompositions have occurred during distillation of alkoxides, which may be attributable to the formation of peroxides of various types. This is especially the case in the presence of acid, Chem. Eng. News, 1974, 52(35), 3. A nickel catalyzed aldoxime rearrangement to an amide, went out of control after changing the solvent employed, J. Loss Prev., 1993, 6(2), 69.Also it is combustible.