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| CAS No.: | 1916-59-2 |
|---|---|
| Name: | 3-aminophenoxazone |
| Article Data: | 32 |
| Molecular Structure: | |
|
|
|
| Formula: | C12H8 N2 O2 |
| Molecular Weight: | 212.208 |
| Synonyms: | 2-Amino-3-phenoxazone;2-Amino-3H-phenoxazin-3-one; 2-Aminophenoxazin-3-one; 2-Aminophenoxazon;2-Aminophenoxazone; AV Toxin C; Acrospermum viticola toxin C; NSC 94945;Questiomycin A |
| Density: | 1.45g/cm3 |
| Melting Point: | 249-250 °C |
| Boiling Point: | 362°Cat760mmHg |
| Flash Point: | 172.7°C |
| Safety: | Poison by intraperitoneal route. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. |
| PSA: | 69.12000 |
| LogP: | 2.45620 |
- 483366-12-7(2S,4R)-1-Boc-2-cyano-4-hydroxypyrrolidine
- 361456-36-2METHYL (R)-(+)-ISOCYANATO-3-PHENYLPROPI&
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- 82993-81-5D-threo-Ritalinic acid hydrochloride
- 47087-37-6Z-D-Glu-OMe
- 73441-42-6METHYL-5-CHLORO-2,2-DIMETHYLVALERATE
- 211914-50-0N-[[2-[[[4-(Aminoiminomethyl)phenyl]amino]methyl]-1-methyl-1H-benzimidazol-5-yl]carbonyl]-N-(2-pyridinyl)-beta-alanine ethyl ester hydrochloride
- 240444-70-62,3,5,6-Tetrafluor-4-(methoxymethyl)benzyl-2,2-dimethyl-3-(prop-1-en-1-yl)cyclopropancarboxylat
| Conditions | Yield |
|---|---|
| With oxygen In methanol; water at 20℃; for 24h; | 99% |
| With dihydrogen peroxide; oxygen In ethanol at 27℃; under 760.051 Torr; for 2h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; | 97% |
| With cyclopentyl methyl ether; dihydrogen peroxide; oxygen In water at 50℃; under 3750.38 Torr; for 3h; Reagent/catalyst; Concentration; Temperature; Time; Sealed tube; | 97% |
- 95-55-6
2-amino-phenol
- 59587-26-7
4a-hydroperoxy-N5-ethyl-N3-methyllumiflavin
- 1916-59-2
2-aminophenoxazin-3-one
| Conditions | Yield |
|---|---|
| With potassium tert-butylate In tert-butyl alcohol at 30℃; Product distribution; Rate constant; Mechanism; var. aminophenols and aminonaphthols; | 80% |
- 24541-44-4
2-azidophenol
- 1916-59-2
2-aminophenoxazin-3-one
| Conditions | Yield |
|---|---|
| With cobalt(II) 5,10,15,20-tetraphenylporphyrin In chlorobenzene at 50℃; for 18h; Mechanism; Schlenk technique; Inert atmosphere; | 80% |
- 117-80-6
2,3-Dichloro-1,4-naphthoquinone
- 67-56-1
methanol
- 95-55-6
2-amino-phenol
A
- 1916-59-2
2-aminophenoxazin-3-one
B
- 258-72-0
triphenodioxazine
C
- 73396-99-3
6-chloro-12a-hydroxy-5H-benzophenoxazin-5-one
D
- 73397-05-4
6-chloro-12a-methoxy-5H-benzophenoxazin-5-one
| Conditions | Yield |
|---|---|
| In methanol for 2h; Heating; Further byproducts given; | A 2.5% B 4.5% C 18% D 61% |
- 117-80-6
2,3-Dichloro-1,4-naphthoquinone
- 64-17-5
ethanol
- 95-55-6
2-amino-phenol
A
- 1916-59-2
2-aminophenoxazin-3-one
B
- 73397-07-6
6-chloro-5H-benzophenoxazin-5-one
C
- 258-72-0
triphenodioxazine
D
- 73396-99-3
6-chloro-12a-hydroxy-5H-benzophenoxazin-5-one
E
- 73397-05-4
6-chloro-12a-methoxy-5H-benzophenoxazin-5-one
| Conditions | Yield |
|---|---|
| In methanol at 95 - 100℃; for 3h; Product distribution; | A 2.5% B 1.4% C 4.5% D 18% E 61% |
| Conditions | Yield |
|---|---|
| In ethanol for 0.416667h; | 51% |
- 117-80-6
2,3-Dichloro-1,4-naphthoquinone
- 64-17-5
ethanol
- 95-55-6
2-amino-phenol
A
- 1916-59-2
2-aminophenoxazin-3-one
B
- 73397-07-6
6-chloro-5H-benzophenoxazin-5-one
C
- 258-72-0
triphenodioxazine
D
- 73396-99-3
6-chloro-12a-hydroxy-5H-benzophenoxazin-5-one
E
- 73397-02-1
6-chloro-12a-ethoxy-5H-benzophenoxazin-5-one
| Conditions | Yield |
|---|---|
| In ethanol at 95 - 100℃; for 3h; Product distribution; | A 3% B 1.5% C 4.8% D 10.5% E 50% |
- 117-80-6
2,3-Dichloro-1,4-naphthoquinone
- 64-17-5
ethanol
- 95-55-6
2-amino-phenol
A
- 1916-59-2
2-aminophenoxazin-3-one
B
- 258-72-0
triphenodioxazine
C
- 73396-99-3
6-chloro-12a-hydroxy-5H-benzophenoxazin-5-one
D
- 73397-02-1
6-chloro-12a-ethoxy-5H-benzophenoxazin-5-one
| Conditions | Yield |
|---|---|
| In ethanol at 95 - 100℃; for 3h; Further byproducts given; | A 3% B 4.8% C 10.5% D 50% |
- 117-80-6
2,3-Dichloro-1,4-naphthoquinone
- 95-55-6
2-amino-phenol
A
- 1916-59-2
2-aminophenoxazin-3-one
B
- 258-72-0
triphenodioxazine
C
- 73396-99-3
6-chloro-12a-hydroxy-5H-benzophenoxazin-5-one
D
- 73397-02-1
6-chloro-12a-ethoxy-5H-benzophenoxazin-5-one
| Conditions | Yield |
|---|---|
| In ethanol at 95 - 100℃; for 3h; Further byproducts given; | A 3% B 4.8% C 10.5% D 50% |
| Conditions | Yield |
|---|---|
| In ethanol Condensation; Heating; | 40% |
- Total:31 Page 1 of 1 1
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Chemistry
Structure of Rho3-aminophenoxazone(1916-59-2):
Synonyms of 3-aminophenoxazone(1916-59-2):3-aminophenoxazone;2-Aminophenoxazon;Phx-3;2-Amino-3-oxo-3H-phenoxazine;Questiomycin
Toxicity Data With Reference
| 1. | dni-mus:ast 20 µmol/L | CPBTAL Chemical and Pharmaceutical Bulletin. 17 (1969),105. | ||
| 2. | dnd-mam lym 100 µmol/L | CPBTAL Chemical and Pharmaceutical Bulletin. 17 (1969),105. | ||
| 3. | ipr-mus LD50:200 mg/kg | 85GDA2 CRC Handbook of Antibiotic Compounds. 5 (1981),174. |