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CAS No.: | 19853-09-9 | ||||||||||||||
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Name: | 2-PHENYLBENZYL BROMIDE | ||||||||||||||
Article Data: | 28 | ||||||||||||||
Molecular Structure: | |||||||||||||||
Formula: | C13H11 Br | ||||||||||||||
Molecular Weight: | 247.134 | ||||||||||||||
Synonyms: | Biphenyl,2-(bromomethyl)- (6CI,8CI);1-Bromomethyl-2-phenylbenzene; 2-(Bromomethyl)biphenyl;2-Bromomethyl-1,1'-biphenyl; 2-Phenylbenzyl bromide; Biphenyl-2-ylmethylbromide; NSC 97772; o-Phenylbenzyl bromide | ||||||||||||||
Density: | 1.341g/cm3 | ||||||||||||||
Melting Point: | 45-46 °C | ||||||||||||||
Boiling Point: | 374.7°Cat760mmHg | ||||||||||||||
Flash Point: | 169°C | ||||||||||||||
Hazard Symbols: | |||||||||||||||
Risk Codes: | 34 | ||||||||||||||
Safety: |
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PSA: | 0.00000 | ||||||||||||||
LogP: | 4.24850 |
2-biphenylmethanol
2-phenylbenzyl bromide
Conditions | Yield |
---|---|
With hydrogen bromide for 21h; Heating; | 96.6% |
With carbon tetrabromide; triphenylphosphine In acetonitrile at 0 - 20℃; for 0.5h; | 55% |
With phosphorus tribromide |
2-methylbiphenyl
2-phenylbenzyl bromide
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; N-Bromosuccinimide In cyclohexane at 50℃; for 4h; Reagent/catalyst; Temperature; | 96.5% |
With tert.-butylhydroperoxide; N-Bromosuccinimide In cyclohexane at 42 - 45℃; for 2h; Green chemistry; | 91.2% |
With N-Bromosuccinimide In tetrachloromethane for 3h; Irradiation; | 85% |
Conditions | Yield |
---|---|
With N-Bromosuccinimide In nitrogen; water; chlorobenzene | 86% |
Conditions | Yield |
---|---|
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium carbonate In 1,4-dioxane at 100℃; for 3h; | 79% |
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium carbonate In 1,4-dioxane at 100℃; for 3h; Suzuki Coupling; | 79% |
2-biphenylmethanol
o-bromobenzyl alcohol
A
2-phenylbenzyl bromide
B
1-Bromo-2-bromomethyl-benzene
Conditions | Yield |
---|---|
With bromine; triphenylphosphine In dichloromethane at -78 - 20℃; for 18h; Inert atmosphere; | A 75% B 10% |
Conditions | Yield |
---|---|
With hydrogen bromide |
biphenyl-2-carboxylic acid methyl ester
2-phenylbenzyl bromide
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 98.7 percent / LAH / diethyl ether 2: 96.6 percent / 48percent HBr / 21 h / Heating View Scheme |
biphenyl-2-carbonitrile
2-phenylbenzyl bromide
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: nickel / 120 - 130 °C / 11400 - 15200 Torr / Hydrogenation 2: sodium nitrite; acetic acid 3: hydrobromic acid / 100 °C View Scheme |
2-phenylbenzylamine
2-phenylbenzyl bromide
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: sodium nitrite; acetic acid 2: hydrobromic acid / 100 °C View Scheme | |
Multi-step reaction with 2 steps 1: NaNO2; aqueous acetic acid 2: PBr3 View Scheme |
biphenyl-2-ylmagnesium iodide
2-phenylbenzyl bromide
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: diethyl ether; benzene 2: aqueous HBr View Scheme |