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CAS No.: | 215788-65-1 |
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Name: | 1,1 bis(di-isopropylphosphine)ferrocene palladium dichloride |
Molecular Structure: | |
Formula: | C22H36 Cl2 Fe P2 Pd |
Molecular Weight: | 595.648 |
Synonyms: | (1,1'-Bis(diisopropylphosphino)ferrocene)dichloropalladium;Dichloro(1,1'-bis(diisopropylphosphino)ferrocene)palladium;Dichloro[Ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II) |
Melting Point: | 282-287 °C |
PSA: | 27.18000 |
LogP: | 1.89170 |
1,1'-bis(diisopropylphosphino)ferrocene
dichloro[ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II)
Conditions | Yield |
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With HCl In diethyl ether; ethanol PdCl2 suspn. in EtOH treated with conc. HCl, stirred at 50°C for30 min, filtered, Fe complex (1 equiv.) soln. in Et2O added at 20°C, stirred for 10 min; crystd. at -35°C, filtered, washed (H2O), dried (vac.); elem. anal.; | 38% |
dichloromethane
dichloro[ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II)
4-mercaptopyridine-3-carboxylic acid
Conditions | Yield |
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With triethylamine In dichloromethane byproducts: (C2H5)3NHCl; (N2), mixed, stirred at room temp. for 3 h; filtered, pptd.(hexane), recrystd.(CH2Cl2/hexane), elem. anal., IR, NMR,MAS, XRD; | 79% |
dichloro[ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II)
Thiosalicylic acid
[1,1'-bis(diisopropylphosphino)ferrocene]palladium(II) thiosalicylate
Conditions | Yield |
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With triethylamine In dichloromethane byproducts: (C2H5)3NHCl; (N2), mixed, stirred at room temp. for 3 h; filtered, pptd.(hexane), recrystd.(CH2Cl2/hexane), elem. anal., IR, NMR,MAS, XRD; | 68% |
ortho-mercaptophenol
dichloromethane
dichloro[ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II)
Conditions | Yield |
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With triethylamine In dichloromethane byproducts: (C2H5)3NHCl; (N2), mixed, stirred at room temp. for 3 h; filtered, pptd.(hexane), recrystd.(CH2Cl2/hexane), elem. anal., IR, NMR,MAS, XRD; | 70% |
3,4-dimercaptotoluene
dichloromethane
dichloro[ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II)
[1,1'-bis(diisopropylphosphino)ferrocene]palladium(II) 3,4-toluenedithiolate * CH2Cl2
Conditions | Yield |
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With triethylamine In dichloromethane byproducts: (C2H5)3NHCl; (N2), mixed, stirred at room temp. for 3 h; filtered, pptd.(hexane), recrystd.(CH2Cl2/hexane), elem. anal., IR, NMR,MAS, XRD; | 56% |
3,6-dichlorobenzene-1,2-dithiol
dichloro[ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II)
[1,1'-bis(diisopropylphosphino)ferrocene]palladium(II) 3,6-dichloro-1,2-benzenedithiolate
Conditions | Yield |
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With triethylamine In dichloromethane byproducts: (C2H5)3NHCl; (N2), mixed, stirred at room temp. for 3 h; filtered, pptd.(hexane), recrystd.(CH2Cl2/hexane), elem. anal., IR, NMR,MAS, XRD; | 49% |
dichloro[ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II)
1,2-benzenedithiole
[1,1'-bis(diisopropylphosphino)ferrocene]palladium(II) 1,2-benzenedithiolate
Conditions | Yield |
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With triethylamine In dichloromethane byproducts: (C2H5)3NHCl; (N2), mixed, stirred at room temp. for 3 h; filtered, pptd.(hexane), recrystd.(CH2Cl2/hexane), elem. anal., IR, NMR,MAS, XRD; | 52% |
dichloro[ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II)
sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate
Conditions | Yield |
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In dichloromethane at 20℃; for 0.5h; Inert atmosphere; Schlenk technique; | 69% |
dichloromethane
dichloro[ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II)
thiophenol
Conditions | Yield |
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With Et3N In toluene byproducts: Et3NHCl; under N2, Pd-complex was added to toluene soln. of thiophenol; Et3NHCl was filtered off, filtrate was evapd. to dryness, residue was recrystd. from CH2Cl2/hexane (1:2), hexane was layered onto CH2Cl2 soln., slow diffusion of hexane at 258 K; elem. anal.; | 68% |
bis(acetonitrile)dichloroplatinum(II)
dichloro[ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II)
[Pt(dippf)Cl2]
Conditions | Yield |
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In dichloromethane under Ar atm. mixt. (PtCl2(MeCN)2) and dippf in CH2Cl2 was stirred at room temp. for 1 h; soln. was concd., hexane was added, ppt. was filtered, washed with etherand dried in vacuo; elem. anal.; | 32% |