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2167-23-9

Basic Information
CAS No.: 2167-23-9
Name: 2,2-Di(tert-butylperoxy)butane
Article Data: 9
Molecular Structure:
Molecular Structure of 2167-23-9 (2,2-Di(tert-butylperoxy)butane)
Formula: C12H26O4
Molecular Weight: 234.336
Synonyms: Peroxide,(1-methylpropylidene)bis[(1,1-dimethylethyl) (9CI);Peroxide,sec-butylidenebis[tert-butyl (6CI,7CI,8CI);2,2-Bis(tert-butyldioxy)butane;2,2-Bis(tert-butylperoxy)butane;3,4,6,7-Tetraoxanonane, 5-ethyl-2,2,5,8,8-pentamethyl-;Chaloxyd P 1200AL;Chaloxyd P 1293AL;DB 50;Lupersol 220;NSC 5626;Perhexa 22;Trigonox D;Trigonox D-C 50;Trigonox D-E 50;Trigonox DM 50;VP 1200;sec-Butylidenebis[tert-butyl peroxide];
EINECS: 218-507-2
Density: 0.929 g/cm3
Melting Point: ≥80 °C (SADT)
Boiling Point: 227.818 °C at 760 mmHg
Flash Point: 70.497 °C
Solubility: immiscible with water
Appearance: (usually handled as a solution in mineral oil)
Hazard Symbols: OxidizingO, IrritantXi
Risk Codes: 8-41-7-36/38-10-37/38
Safety: 16-17-26-36/37/39-3/7-14A-14
Transport Information: UN 3103 5.2
PSA: 36.92000
LogP: 3.60600
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Chemistry

IUPAC Name: 2,2-Bis(tert-butylperoxy)butane
Product Name: 2,2-Di(tert-butylperoxy)butane
The MF of 2,2-Bis(tert-butylperoxy)butane (CAS NO.2167-23-9) is C12H26O4.

                                    
The MW of 2,2-Bis(tert-butylperoxy)butane (CAS NO.2167-23-9) is 234.33.
Synonyms of 2,2-Bis(tert-butylperoxy)butane (CAS NO.2167-23-9): 2,2-Bis(tert-butylperoxy)butane ; 2,2-Di(tert-Butylperoxy)butane ; 3,4,6,7-Tetraoxanonane, 5-ethyl-2,2,5,8,8-pentamethyl- ; Butane, 2,2-bis(tert-butyldioxy)- ; 3, 4,6,7-Tetraoxanonane, 5-ethyl-2,2,5,8,8-pentamethyl- ; Butane, 2,2-bis(tert-butylperoxy)- 
Product Categories: Free Radical Initiators;Polymerization Initiators
Appearance: (usually handled as a solution in mineral oil)
Storage temp: Refrigerator (+4°C) + Flammables area
Water Solubility: immiscible
Index of Refraction: 1.425 
EINECS: 218-507-2
Density: 0.929 g/ml 
Flash Point: 70.5 °C
Boiling Point: 227.8 °C
Stability: Unstable

Safety Profile

Pure material explodes on heating to 130°C, sparking or on impact. When heated to decomposition it emits acrid smoke and fumes. See also PEROXIDES, INORGANIC; PEROXIDES, ORGANIC.Safety information of 2,2-Bis(tert-butylperoxy)butane (CAS NO.2167-23-9):
Hazard Codes  OxidizingO,IrritantXi
Risk Statements 
8 Contact with combustible material may cause fire
41 Risk of serious damage to eyes
7 May cause fire
10 Flammable
36/37/38 Irritating to eyes, respiratory system and skin
Safety Statements 
16 Keep away from sources of ignition - No smoking
17 Keep away from combustible material
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39 Wear suitable protective clothing, gloves and eye/face protection
3/7 Keep container tightly closed in a cool place
14 Keep away from ... (incompatible materials to be indicated by the manufacturer)
RIDADR  UN 3103 5.2
WGK Germany  2
HazardClass  5.2
PackingGroup  II

Specification

Peroxides, such as 2,2-Di(tert-butylperoxy)butane, are good oxidizing agents. Organic compounds can ignite on contact with concentrated peroxides. Strongly reduced material such as sulfides, nitrides, and hydrides may react explosively with peroxides. There are few chemical classes that do not at least produce heat when mixed with peroxides. Many produce explosions or generate gases (toxic and nontoxic). Generally, dilute solutions of peroxides (<70%) are safe, but the presence of a catalyst (often a transition metal such as cobalt, iron, manganese, nickel, or vanadium) as an impurity may even then cause rapid decomposition, a buildup of heat, and even an explosion. Solutions of peroxides often become explosive when evaporated to dryness or near-dryness. Danger of explosion when dry. May explode from heat, shock, friction or contamination. May ignite combustibles (wood, paper, oil, clothing, etc.). May be ignited by heat, sparks or flames.