2167-23-9 Usage
Chemical Properties
(usually handled as a solution in mineral oil)
Reactivity Profile
Peroxides, such as 2,2-Di(tert-butylperoxy)butane, are good oxidizing agents. Organic compounds can ignite on contact with concentrated peroxides. Strongly reduced material such as sulfides, nitrides, and hydrides may react explosively with peroxides. There are few chemical classes that do not at least produce heat when mixed with peroxides. Many produce explosions or generate gases (toxic and nontoxic). Generally, dilute solutions of peroxides (<70%) are safe, but the presence of a catalyst (often a transition metal such as cobalt, iron, manganese, nickel, or vanadium) as an impurity may even then cause rapid decomposition, a buildup of heat, and even an explosion. Solutions of peroxides often become explosive when evaporated to dryness or near-dryness. Danger of explosion when dry. May explode from heat, shock, friction or contamination. May ignite combustibles (wood, paper, oil, clothing, etc.). May be ignited by heat, sparks or flames.
Flammability and Explosibility
Notclassified
Check Digit Verification of cas no
The CAS Registry Mumber 2167-23-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,1,6 and 7 respectively; the second part has 2 digits, 2 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 2167-23:
(6*2)+(5*1)+(4*6)+(3*7)+(2*2)+(1*3)=69
69 % 10 = 9
So 2167-23-9 is a valid CAS Registry Number.
InChI:InChI=1/C12H26O4/c1-9-12(8,15-13-10(2,3)4)16-14-11(5,6)7/h9H2,1-8H3
2167-23-9Relevant articles and documents
Lithographic printing method
-
, (2008/06/13)
A lithographic printing plate precursor comprising a support and an image-recording layer containing at least one infrared absorbing agent of a cyanine dye in which a HOMO energy level of each of substituents present on both terminal nitrogen atoms is -10.0 eV or higher. An infrared absorbing agent of a cyanide dye represented by formula (V) shown below: wherein Z 1 and Z 2 each independently represents an aromatic ring which may have a substituent or a hetero aromatic ring which may have a substituent; R 10 and R 20 each independently represents a phenyl group, a naphtyl group, an anthracenyl group, a carbazolyl group or a phenothiazinyl group each of which may have a substituent; A - represents an anion which exists in case of being necessary for neutralizing a charge and is selected from a halogen ion, a perchlorate ion, a tetrafluoroborate ion, a hexafluorophosphate ion and a sulfonate ion; and n represents 1 or 2.
EFFECT OF STERIC FACTORS ON THE EQUILIBRIUM IN THE FORMATION OF TERT-BUTYLPEROXY KETALS FROM ALIPHATIC KETONES
Antonovskii, V. L.,Fedorova, E. V.,Shtivel', N. E.,Emelin, Yu. D.
, p. 704 - 706 (2007/10/02)
The equilibrium in the formation of tert-butylperoxy ketals from aliphatic ketones and tert-butyl hydroperoxide is determined by the steric factors of the substituents at the carbonyl group of the ketones.The dependence of the equilibrium constant on the steric parameters of the substituents is described by the Taft equation log K/KO = δΣEs0 with δ = 1.37 (r = 0.970).
