CAS No.2217-02-9,(+)-Fenchol Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	2217-02-9
Name:	(+)-Fenchol
Article Data:	48

Formula:	C10H18 O
Molecular Weight:	154.252
Synonyms:	Bicyclo[2.2.1]heptan-2-ol,1,3,3-trimethyl-, (1R-endo)-; (+)-Fenchol; (+)-Fenchyl alcohol; (+)-a-Fenchol; (+)-a-Fenchyl alcohol;(1R)-endo-(+)-Fenchol; (1R)-endo-(+)-Fenchyl alcohol; (1R-endo)-Fenchol;D-Fenchol; D-Fenchyl alcohol; a-(+)-Fenchol; a-Fenchol, (+)-
EINECS:	216-639-5
Density:	0.992g/cm³
Melting Point:	39-45 ºC
Boiling Point:	201-202 °C(lit.)
Flash Point:	165 ºF
Solubility:	Insoluble in water.
Risk Codes:	36/38
Safety:	S22;S24/25
PSA:	20.23000
LogP:	2.19350

Synthetic route

: (1R)-1,3,3-trimethyl-2-(2-methylprop-2-enyl)bicyclo[2.2.1]heptan-2-ol

A: 2217-02-9
(1R)-endo-(+)-fenchol

B: (1R,2R)-2-[(2S)-2-hydroxypropyl]-1,3,3-trimethylbicyclo[2.2.1]heptan-2-ol

Conditions

Conditions	Yield
Stage #1: (1R)-1,3,3-trimethyl-2-(2-methylprop-2-enyl)bicyclo[2.2.1]heptan-2-ol With oxygen; ozone In diethyl ether at -78℃; Oxidation; Stage #2: With lithium aluminium tetrahydride In diethyl ether at -78 - 20℃; Reduction;	A 0.18 g B 79%

: 7787-20-4
(1R)-fenchone

: 2217-02-9
(1R)-endo-(+)-fenchol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride; diethyl ether
With ethanol; sodium
With ammonia; lithium; ammonium chloride In tetrahydrofuran at -75℃; for 0.916667h; Yield given;

: 10467-10-4
ethylmagnesium iodide

: 7787-20-4
(1R)-fenchone

A: 2217-02-9
(1R)-endo-(+)-fenchol

B: 137255-07-3
(1R)-endo-2-ethylfenchol

Conditions

Conditions	Yield
In diethyl ether for 8h; Heating;	A 84 % Chromat. B 13 % Chromat.

...Expand

: 7787-20-4
(1R)-fenchone

A: 64439-31-2
(1R)-endo-(+)-fenchylalcohol

B: 2217-02-9
(1R)-endo-(+)-fenchol

Conditions

Conditions	Yield
With aluminum oxide; sodium; isopropyl alcohol In tetrahydrofuran for 5h; Heating;	A 44.0 % Chromat. B 56.0 % Chromat.
With aluminum isopropoxide; isopropyl alcohol for 420h; Heating;	A 1.02 g B n/a
With tropinone reductase of Cochlearia officinalis; NADPH In methanol at 30℃; for 1h; pH=5; Kinetics; Reagent/catalyst; Enzymatic reaction;

: 146203-05-6
(+)-8-bromo-α-fenchol

: 2217-02-9
(1R)-endo-(+)-fenchol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In diethyl ether for 6h; Ambient temperature;

: 251319-23-0
1-[(1R,2R)-2-hydroxy-1,3,3-trimethylbicyclo[2.2.1]hept-2-yl]propan-2-one

A: 2217-02-9
(1R)-endo-(+)-fenchol

B: (1R,2R)-2-[(2S)-2-hydroxypropyl]-1,3,3-trimethylbicyclo[2.2.1]heptan-2-ol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride Reduction;

: 64-17-5
ethanol

: 7787-20-4
(1R)-fenchone

sodium: sodium

A: 64439-31-2
(1R)-endo-(+)-fenchylalcohol

B: 2217-02-9
(1R)-endo-(+)-fenchol

...Expand

: (1R)-2-ethenyl-1,3,3-trimethylbicyclo[2.2.1]heptan-2-ol

A: 2217-02-9
(1R)-endo-(+)-fenchol

B: (1R,2R)-2-(hydroxymethyl)-1,3,3-trimethylbicyclo[2.2.1]heptan-2-ol

C: (1R,2S)-2-(hydroxymethyl)-1,3,3-trimethylbicyclo[2.2.1]heptan-2-ol

Conditions

Conditions	Yield
Stage #1: (1R)-2-ethenyl-1,3,3-trimethylbicyclo[2.2.1]heptan-2-ol With oxygen; ozone In diethyl ether at -78℃; Oxidation; Stage #2: With lithium aluminium tetrahydride In diethyl ether at -78 - 20℃; Reduction;	A 0.05 g B 0.07 g C n/a

...Expand

: (1R)-1,3,3-trimethyl-2-(2-methylprop-2-enyl)bicyclo[2.2.1]heptan-2-ol

: 2217-02-9
(1R)-endo-(+)-fenchol

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: O3/O2 / diethyl ether / -78 - 20 °C 2: LiAlH4 View Scheme
Multi-step reaction with 2 steps 1.1: O3/O2 / diethyl ether / -78 °C 1.2: 8.28 g / Et3N / diethyl ether / -78 - 20 °C 2.1: LiAlH4 View Scheme

: 18084-01-0, 21696-69-5, 131062-94-7, 137255-12-0, 137255-14-2
(1R,4S)-2-Ethynyl-1,3,3-trimethyl-bicyclo[2.2.1]heptan-2-ol

: 2217-02-9
(1R)-endo-(+)-fenchol

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 59 percent Chromat. / N-methylpyrrolidone, potassium hydroxide / 4 h / 20 °C 2: 84 percent Chromat. / diethyl ether / 8 h / Heating View Scheme

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Chemistry

Chemical Name: (+)-Fenchol
IUPAC NAME: (1S,4R,6S)-1,5,5-Trimethylbicyclo[2.2.1]heptan-6-ol
CAS No.: 2217-02-9
EINECS: 216-639-5
Molecular Formula: C₁₀H₁₈O
Molecular Weight: 154.25 g/mol
Melting Point: 43-46 °C
Density: 0.992 g/cm³
Flash Point: 73.9 °C
Boiling Point: 202.9 °C at 760 mmHg
Following is the structure of Fenchol (CAS No.:2217-02-9):

Product Categories about Fenchol (CAS No.:2217-02-9) is refer to Miscellaneous
The chemical synonymous of Fenchol (CAS No.:2217-02-9) are (+)-Fenchol ; Fenchol ; Fenchyl alcohol ; Fema 2480 ; Alpha Fenchol ; (1r)-1,3,3-Trimethylbicyclo[2.2.1]heptan-2-Ol ; (1r)-(+)-Fenchyl alcohol ; (1r)-Endo-(+)-fenchol

Safety Profile

Risk Statements about Fenchol (CAS No.:2217-02-9):
R36/38:Irritating to eyes and skin.
Safety Statements about Fenchol (CAS No.:2217-02-9):
S22:Do not breathe dust.
S24/25:Avoid contact with skin and eyes.
Attention:
1. Storage: Store in a cool, dry place. Keep container closed when not in use.
2. Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.