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2469-55-8

Basic Information
CAS No.: 2469-55-8
Name: 1,3-Bis(3-aminopropyl)tetramethyldisiloxane
Article Data: 12
Molecular Structure:
Molecular Structure of 2469-55-8 (1,3-Bis(3-aminopropyl)tetramethyldisiloxane)
Formula: C10H28N2OSi2
Molecular Weight: 248.516
Synonyms: 1,3-Bis(3-aminopropyl)-1,1,3,3-tetramethyl-1,3-disiloxane;1,3-Bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane;1,3-Bis(3-aminopropyl)tetramethyldisiloxane;1,3-Bis(aminopropyl)-1,1,3,3-tetramethyldisiloxane;TSL 9306;1,3-Bis(g-aminopropyl)tetramethyldisiloxane;B 1710;BY 16-871EG;H-PAM;PAM-E (siloxane);5-Oxa-4,6-disilanonane-1,9-diamine,4,4,6,6-tetramethyl- (6CI,7CI,8CI);
EINECS: 219-588-7
Density: 0.891 g/cm3
Boiling Point: 258.721 °C at 760 mmHg
Flash Point: 110.271 °C
Solubility: Slightly soluble in water.
Hazard Symbols: CorrosiveC
Risk Codes: 34
Safety: 26-28-36/37/39-45
Transport Information: UN 3267 8/PG 2
PSA: 61.27000
LogP: 3.51140
Synthetic route
67-56-1

methanol

151565-10-5

bis(trimethylsilylaminopropyl)tetramethyldisiloxane

59384-10-0

bis(hexamethyldisilylaminopropyl)tetramethyldisiloxane

A

107-46-0

Hexamethyldisiloxane

B

2469-55-8

1,3-bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane

Conditions
ConditionsYield
for 2h; Product distribution / selectivity; Heating / reflux;A n/a
B 94.1%
1070740-24-7

bis(methylcarbamatopropyl)tetra-methyldisiloxane

2469-55-8

1,3-bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane

Conditions
ConditionsYield
Stage #1: bis(methylcarbamatopropyl)tetra-methyldisiloxane With water; sulfuric acid at 100℃; for 16h;
Stage #2: With sodium hydroxide In water Product distribution / selectivity;
94%
151565-10-5

bis(trimethylsilylaminopropyl)tetramethyldisiloxane

59384-10-0

bis(hexamethyldisilylaminopropyl)tetramethyldisiloxane

A

107-46-0

Hexamethyldisiloxane

B

2469-55-8

1,3-bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane

Conditions
ConditionsYield
With water at 78 - 80℃; for 1h; Product distribution / selectivity;A n/a
B 92.7%

silyl carbamate

2627-95-4

tetramethyldivinyldisiloxane

7440-06-4

platinum

2469-55-8

1,3-bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane

Conditions
ConditionsYield
chloroplatinic acid84%
3277-26-7

1,1,3,3-Tetramethyldisiloxane

107-11-9

1-amino-2-propene

2469-55-8

1,3-bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane

Conditions
ConditionsYield
at 80 - 110℃; under 3750.38 Torr; for 6h; Concentration; Pressure; Temperature; Inert atmosphere;80.56%
3277-26-7

1,1,3,3-Tetramethyldisiloxane

allylaminotrimethylsilane

2469-55-8

1,3-bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane

Conditions
ConditionsYield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex at 95 - 125℃; Inert atmosphere;58%
10519-97-8

allylamino-trimethyl-silane

3277-26-7

1,1,3,3-Tetramethyldisiloxane

2469-55-8

1,3-bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane

Conditions
ConditionsYield
With dihydrogen hexachloroplatinate; ethanol
18306-79-1

(3-aminopropyl)(ethoxy)dimethylsilane

2469-55-8

1,3-bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane

Conditions
ConditionsYield
With potassium hydroxide
2603-88-5

α,ω-Bis-(2-cyan-ethyl)-tetramethyldisiloxan

2469-55-8

1,3-bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane

Conditions
ConditionsYield
With hydrogen; Co catalyst
13508-63-9

chloropropyl(dimethyl)ethoxysilane

2469-55-8

1,3-bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: NH3
2: aqueous KOH
View Scheme
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Chemistry

Product Name: Oxybis((3-aminopropyl)dimethylsilane) (2469-55-8)


Molecular Formula: C10H28N2OSi2
Molecular Weight: 248.51g/mol
Mol File: 2469-55-8.mol
Einecs: 219-588-7
Boiling point: 132 °C11 mm Hg(lit.)
Storage Temperature: 2-8°C
Flash Point: 91°C
Density: 0.901 g/mL at 20 °C(lit.)
Product Categories: Si(classes of silicon compounds) ; Siloxanes ; Si-o compounds
Synonyms of  Oxybis((3-aminopropyl)dimethylsilane) (2469-55-8): 1,3-Bis(aminopropyl)tetramethyldisiloxane ; 1,3-Bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane ; 1,3-Bis(3-aminopropyl)tetramethyldisiloxane ; Bis(3-aminopropyl)tetramethyldisiloxane ; Bis(aminopropyl)tetramethyldisiloxane ; Tetramethyl-1,3-bis(3-aminopropyl)disiloxane ; 1,3-Bis(3-aminopropyl)-1,1,3,3-tetramethyl-disiloxan ; 1,3-Bis(3-aminopropyl)tetramethyldislloxane.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 80mg/kg (80mg/kg)   Russian Chemical Reviws Vol. 38, Pg. 975, 1969.
rabbit LD skin > 2gm/kg (2000mg/kg)   National Technical Information Service. Vol. OTS0535667,
rat LDLo oral 500mg/kg (500mg/kg)   National Technical Information Service. Vol. OTS0535667,

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intraperitoneal route. When heated to decomposition it emits toxic vapors of NOx.Safety Information of Oxybis((3-aminopropyl)dimethylsilane) (2469-55-8):
Hazard Codes: C
Risk Statements: 34 
34:  Causes burns
Safety Statements: 26-28-36/37/39-45
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
28:  After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
36:  Wear suitable protective clothing 
37:  Wear suitable gloves 
39:  Wear eye/face protection
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)