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CAS No.: | 2602-34-8 |
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Name: | (3-Glycidyloxypropyl)triethoxysilane |
Article Data: | 24 |
Cas Database | |
Molecular Structure: | |
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Formula: | C12H26O5Si |
Molecular Weight: | 278.421 |
Synonyms: | Silane,[3-(2,3-epoxypropoxy)propyl]triethoxy- (6CI,7CI,8CI);3-(2,3-Epoxypropoxy)propyltriethoxysilane;3-(Triethoxysilyl)propyl glycidyl ether;3-Glycydoxylpropyltriethoxysilane;Dynasylan GLYEO;GF 82;GOPTS;Glycidyl 3-(triethoxysilyl)propyl ether;KBE 403;NB1115;NV 1115;Silan GF 82;Silquest A 1871;Triethoxy(3-glycidoxypropyl)silane;WD 60;Z 6041;[3-(Glycidyoxy)propyl]triethoxysilane;g-Glycidoxypropyltriethoxysilane;3-Glycidoxypropyltriethoxy silane; |
EINECS: | 220-011-6 |
Density: | 1.012 g/cm3 |
Melting Point: | < -50 ºC |
Boiling Point: | 303.6 ºC at 760 mmHg |
Flash Point: | 110.9 ºC |
Solubility: | 3.3g/L at 20℃ |
Appearance: | colorless clear liquid |
Hazard Symbols: |
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Risk Codes: | 36/37/38-20 |
Safety: | 26 |
PSA: | 49.45000 |
LogP: | 1.84030 |
Conditions | Yield |
---|---|
[siloxideRh(cod)](SBA-15) at 100℃; | 96% |
With silica supported poly-3-(2-aminoethylamino)propylsiloxane platinum complex at 110℃; for 2h; | 94.8% |
With (TFAPDI)Co(2-ethylhexanoate)2 at 0 - 20℃; for 1.08333h; Temperature; Inert atmosphere; Sealed tube; | 94% |
Allyl glycidyl ether
Triethoxysilane
B
glycidyl 1-propenyl ether
C
tetraethoxy orthosilicate
D
(3-glycidyloxypropyl)triethoxysilane
Conditions | Yield |
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Speier's catalyst at 70 - 90℃; for 1.5h; Further byproducts.; | A n/a B n/a C n/a D 78.9% |
Allyl glycidyl ether
triethyl hydrogen silicate
B
3-Propoxy-1,2-epoxypropan
C
(3-glycidyloxypropyl)triethoxysilane
Conditions | Yield |
---|---|
[rhodium(I)(1,5-cyclooctadien)(trimethylsiloxide)(P(cyclohexyl)3)] at 25℃; for 0.25h; Product distribution; Further Variations:; Reagents; Temperatures; |
Conditions | Yield |
---|---|
With (MeAPDI)Co(OAc)2 at 20℃; for 1h; Reagent/catalyst; Inert atmosphere; Sealed tube; Overall yield = 87 %; Overall yield = 217 mg; |
Allyl glycidyl ether
Triethoxysilane
A
glycidyl 1-propenyl ether
B
(3-glycidyloxypropyl)triethoxysilane
Conditions | Yield |
---|---|
With cobalt(II) 2-ethylhexanoate at 20℃; for 1.5h; Reagent/catalyst; Temperature; Inert atmosphere; Sealed tube; Overall yield = 326 mg; |
Allyl glycidyl ether
Triethoxysilane
A
glycidyl 1-propenyl ether
B
(3-glycidyloxypropyl)triethoxysilane
Conditions | Yield |
---|---|
With (PyBox)Co(2-ethylhexanoate)2 at 20℃; for 1h; Reagent/catalyst; Inert atmosphere; Sealed tube; Overall yield = 68 %; Overall yield = 168 mg; |
Conditions | Yield |
---|---|
With potassium carbonate at 20℃; for 3h; | 100% |
Conditions | Yield |
---|---|
at 85℃; for 2h; | 98.4% |
(3-glycidyloxypropyl)triethoxysilane
2-mercapto-5-methylbenzimidazole
Conditions | Yield |
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at 80 - 120℃; for 4h; Inert atmosphere; | 98.4% |
Conditions | Yield |
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at 85℃; for 2h; | 98.2% |
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The gamma-Glycidoxypropyltriethoxysilane, with the CAS registry number 2602-34-8, is also known as 3-(2,3-Epoxypropyloxy)propyltriethoxysilane. It belongs to the product categories of Epoxy; Epoxy Silanes. Its EINECS registry number is 220-011-6. This chemical's molecular formula is C12H26O5Si and molecular weight is 278.42. What's more, both its IUPAC name and systematic name are the same which is called Triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane. It is used as coupling agent.
Physical properties about gamma-Glycidoxypropyltriethoxysilane are: (1)ACD/LogP: 1.87; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.87; (4)ACD/LogD (pH 7.4): 1.87; (5)ACD/BCF (pH 5.5): 15.49; (6)ACD/BCF (pH 7.4): 15.49; (7)ACD/KOC (pH 5.5): 247.48; (8)ACD/KOC (pH 7.4): 247.48; (9)#H bond acceptors: 5; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 12; (12)Polar Surface Area: 49.45 Å2; (13)Index of Refraction: 1.442; (14)Molar Refractivity: 72.91 cm3; (15)Molar Volume: 275 cm3; (16)Surface Tension: 30.2 dyne/cm; (17) Density: 1.012 g/cm3; (18)Flash Point: 110.9 °C; (19)Enthalpy of Vaporization: 52.22 kJ/mol; (20)Boiling Point: 303.6 °C at 760 mmHg; (21)Vapour Pressure: 0.00166 mmHg at 25 °C.
When you are dealing with this chemical, you should be very careful. This chemical is inflammation to the skin, eyes and respiratory system or other mucous membranes. What's more, it's harmful by inhalation. In case of contacting with eyes, you should rinse immediately with plenty of water and seek medical advice.
You can still convert the following datas into molecular structure:
(1) SMILES: O(CCC[Si](OCC)(OCC)OCC)CC1OC1
(2) InChI: InChI=1S/C12H26O5Si/c1-4-15-18(16-5-2,17-6-3)9-7-8-13-10-12-11-14-12/h12H,4-11H2,1-3H3
(3) InChIKey: JXUKBNICSRJFAP-UHFFFAOYSA-N