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Basic Information
| CAS No.: | 27914-60-9 |
|---|---|
| Name: | 4-(ALLYLOXY)BENZOIC ACID |
| Article Data: | 59 |
| Molecular Structure: | |
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|
|
| Formula: | C10H10 O3 |
| Molecular Weight: | 178.188 |
| Synonyms: | Benzoicacid, 4-(2-propenyloxy)- (9CI); Benzoic acid, p-(allyloxy)- (6CI,8CI);4-(2-Propenyloxy)benzoic acid; 4-Allyloxybenzoic acid; p-Allyloxybenzoic acid |
| Melting Point: | 163-166°C |
| Hazard Symbols: | Xn |
| Risk Codes: | 22 |
| PSA: | 46.53000 |
| LogP: | 1.94960 |
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Synthetic route
- 26595-60-8
allyl (4-allyloxy)benzoate
- 27914-60-9
4-allyloxybenzoic acid
Conditions
| Conditions | Yield |
|---|---|
| With 2,2'-azobis(isobutyronitrile) In benzene at 65 - 70℃; for 3h; | 100% |
| Stage #1: allyl (4-allyloxy)benzoate With sodium hydroxide for 3h; Heating; Stage #2: With hydrogenchloride at 20℃; pH=3; Further stages.; | 97% |
| With sodium hydroxide In water for 6h; Reflux; | 95% |
| With potassium hydroxide In methanol at 20℃; | 83% |
- 40663-68-1
4-(2-propenyloxy)benzaldehyde
- 27914-60-9
4-allyloxybenzoic acid
Conditions
| Conditions | Yield |
|---|---|
| With 2-methyl-but-2-ene; polymer-supported chlorite; acetic acid In tert-butyl alcohol at 25℃; | 98% |
| With copper acetylacetonate; oxygen; sodium hydroxide; 1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene In water at 50℃; under 760.051 Torr; for 12h; Sealed tube; | 93% |
| With 4H3N*4H(1+)*CuMo6O18(OH)6(4-); water; oxygen; sodium carbonate at 50℃; under 760.051 Torr; for 12h; | 90% |
- 106-95-6
allyl bromide
- 176700-52-0
2'-(trimethylsilyl)ethyl-4-hydroxybenzoate
- 27914-60-9
4-allyloxybenzoic acid
Conditions
| Conditions | Yield |
|---|---|
| With sodium hydride In N,N-dimethyl-formamide at 20℃; | 95% |
- 27914-60-9
4-allyloxybenzoic acid
Conditions
| Conditions | Yield |
|---|---|
| With sodium hydrogen sulfate; silica gel In dichloromethane at 20℃; for 4h; | 94% |
| With cerium(III) chloride; sodium iodide In acetonitrile for 2h; Heating; | 87% |
Conditions
| Conditions | Yield |
|---|---|
| With aniline; (ϖ-allyl)palladium triflate based catalyst In toluene at 30℃; for 0.5h; | A 92% B 8% |
Conditions
| Conditions | Yield |
|---|---|
| With n-Bu4POH In tetrahydrofuran; water at 0 - 20℃; | 91% |
| Stage #1: allyl bromide; 4-hydroxy-benzoic acid With potassium carbonate In N,N-dimethyl-formamide at 60℃; for 3h; Stage #2: With sodium hydroxide In 1,4-dioxane; water at 60℃; for 0.25h; | 91% |
| With potassium carbonate In N,N-dimethyl-formamide at 40℃; for 10h; | 91% |
Conditions
| Conditions | Yield |
|---|---|
| With n-Bu4POH In tetrahydrofuran; water at 0 - 20℃; | 86% |
- 35750-24-4
methyl 4-allyloxybenzoate
- 27914-60-9
4-allyloxybenzoic acid
Conditions
| Conditions | Yield |
|---|---|
| With sodium hydroxide In 1,4-dioxane; water Reflux; | 85.4% |
| With sodium hydroxide In methanol; water for 1.5h; Reflux; | 51% |
| With sodium hydroxide In tetrahydrofuran; methanol; ethyl acetate | 50% |
| With sodium hydroxide In tetrahydrofuran; methanol; ethyl acetate | 50% |
| With sodium hydroxide In methanol |
- 33148-47-9
4-allyloxy-benzonitrile
- 27914-60-9
4-allyloxybenzoic acid
Conditions
| Conditions | Yield |
|---|---|
| Stage #1: 4-allyloxy-benzonitrile With water; sodium hydroxide In ethanol at 20 - 110℃; Sealed; Stage #2: With hydrogenchloride In ethanol; dichloromethane; water pH=1; | 85% |
| Stage #1: 4-allyloxy-benzonitrile With sodium hydroxide In ethanol; water at 20 - 110℃; Stage #2: With hydrogenchloride; water In ethanol; dichloromethane pH=1; | 85% |
- 5443-37-8
ethyl 4-(n-prop-2'-enyloxy)benzoate
- 27914-60-9
4-allyloxybenzoic acid
Conditions
| Conditions | Yield |
|---|---|
| With sodium hydroxide In ethanol; water Heating; | 82% |
| With potassium carbonate | |
| Stage #1: ethyl 4-(n-prop-2'-enyloxy)benzoate With potassium hydroxide In ethanol for 4h; Reflux; Stage #2: With hydrogenchloride In water |
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4-(ALLYLOXY)BENZOIC ACID
