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CAS No.: | 2814-20-2 |
---|---|
Name: | 2-ISOPROPYL-6-METHYL-4-PYRIMIDINOL |
Article Data: | 22 |
Molecular Structure: | |
Formula: | C8H12 N2 O |
Molecular Weight: | 152.196 |
Synonyms: | 4(1H)-Pyrimidinone,2-isopropyl-6-methyl- (8CI); 4(1H)-Pyrimidinone, 6-methyl-2-(1-methylethyl)-(9CI); 4-Pyrimidinol, 2-isopropyl-6-methyl- (6CI,7CI);2-Isopropyl-4-methyl-6-hydroxypyrimidine; 2-Isopropyl-4-methyl-6-pyrimidinone;2-Isopropyl-4-methylpyrimidin-6-ol; 2-Isopropyl-6-methyl-4(3H)-pyrimidone;2-Isopropyl-6-methyl-4-hydroxypyrimidine; 2-Isopropyl-6-methyl-4-pyrimidinol;2-Isopropyl-6-methyl-4-pyrimidone; 4-Hydroxy-2-isopropyl-6-methylpyrimidine; G27550; IMHP; Pyrimidinol |
EINECS: | 220-561-7 |
Density: | 1.11g/cm3 |
Melting Point: |
172-175 °C(lit.) |
Boiling Point: | 230.5°Cat760mmHg |
Flash Point: | 93.2°C |
Appearance: | BEIGE NEEDLES |
Hazard Symbols: | |
Risk Codes: | R36/37/38 |
Safety: | Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of NOx. |
PSA: | 46.01000 |
LogP: | 1.61400 |
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IUPAC Name: 2-Isopropyl-6-methyl-4-hydroxypyrimidine
The MF of 2-Isopropyl-6-methyl-4-hydroxypyrimidine (2814-20-2) is C8H12N2O.
The MW of 2-Isopropyl-6-methyl-4-hydroxypyrimidine (2814-20-2) is 152.19.
Synonyms of 2-Isopropyl-6-methyl-4-hydroxypyrimidine (2814-20-2): 2-Isopropyl-6-methylpyrimidin-4(1H)-one ; 6-Methyl-2-(1-methylethyl)pyrimidin-4(1H)-one ; Pyrimidinol ; 2-Isopropyl-4-hydroxy-6-methylpyrimidine
Product Categories: Heterocyclic Compounds;Pyrimidines;Building Blocks;Heterocyclic Building Blocks;Alpha sort;Alphabetic;H-MAnalytical Standards;IEnvironmental Standards;Metabolites;Pesticides&Metabolites
Index of Refraction: 1.545
Form: beige needles
EINECS: 220-561-7
Density: 1.11 g/ml
Flash Point: 93.2 °C
Boiling Point: 230.5 °C
Melting Point: 172-175 °C
2-Isopropyl-6-methyl-4-hydroxypyrimidine (2814-20-2) is used as rganophosphorus pesticide diazinon, pharmaceutical intermediates.
Its preparation is obtained by the different isobutyraldehyde nitrile with methanol and hydrogen chloride reaction, made imine ether hydrochloride. Reaction equation is as follows:
By the imine ether hydrochloride with ammonia to produce iso-Spd, and then with ethyl acetoacetate in the presence of sodium hydroxide, forming the ring 2 - isopropyl -4 - methyl -6 - hydroxypyrimidine .
1. | orl-rat LD50:2700 mg/kg | JAFCAU Journal of Agricultural and Food Chemistry. 18 (1970),208. | ||
2. | orl-mus LD50:2200 mg/kg | GISAAA Gigiena i Sanitariya. 52 (3)(1987),69. |
Reported in EPA TSCA Inventory.
Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of NOx.
Safety information of 2-Isopropyl-6-methyl-4-hydroxypyrimidine (2814-20-2):
Hazard Codes Xi
Risk Statements
36/37/38 Irritating to eyes, respiratory system and skin
Safety Statements
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
37/39 Wear suitable gloves and eye/face protection
WGK Germany 2
RTECS UW7525000
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.Store in a cool, dry place. Keep container closed when not in use.