Name: PTOEP
SKU: 31248-39-2

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Basic Information

Molecular Structure:
CAS No.:	31248-39-2
Name:	PTOEP
Article Data:	2

Formula:	C36H44 N4 Pt
Molecular Weight:	727.852
Synonyms:	Platinum,[2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]-,(SP-4-1)-; Platinum, [2,3,7,8,12,13,17,18-octaethylporphinato(2-)]- (8CI);21H,23H-Porphine, 2,3,7,8,12,13,17,18-octaethyl-, platinum complex;(2,3,7,8,12,13,17,18-Octaethylporphyrinato)platinum;2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphyrinplatinum; Platinum2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine; Platinum2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphyrin; Platinum octaethylporphyrin;Platinum(2+) octaethylporphyrin; Platinum(II) octaethylporphyrin; PtOEP
Melting Point:	>300 °C
PSA:	50.50000
LogP:	5.81830

Synthetic route

Conditions	Yield
With sodium proprionate In chlorobenzene under 760.051 Torr; for 3.5h; Reflux;	98%

Conditions	Yield
In further solvent(s) reflux of 2,3,7,8,12,13,17,18-octaethylporphine, H2PtCl6*6H2O and phenolfor 9 h; cooling, dissolving in DMF, pouring into H2O, pptn., filtration, washingwith H2O, drying, chromy. on silica gel (CHCl3:C6H12 (1:2) as eluent); elem. anal.;	76%

Conditions	Yield
With hydrogenchloride; dihydrogen peroxide In chloroform refluxed; 30 min;; cooled; washed with water; organic layer dried over MgSO4; filtered; chromd. (SiO2, CH2Cl2, then CHCl3); recrystd. from CHCl3/MeOH;;	95%

Conditions	Yield
for 0.5h; Heating;	86%

: 99685-96-8, 161105-99-3, 161106-00-9, 111138-12-6, 133318-63-5, 134053-11-5, 134931-35-4, 134931-36-5, 139703-76-7, 145633-27-8, 175414-73-0, 175414-74-1, 175414-75-2, 175519-12-7, 175519-13-8, 175519-14-9, 175519-15-0, 136376-46-0, 144906-37-6, 144906-38-7, 151767-00-9, 152882-97-8, 152882-98-9, 152882-99-0, 153062-34-1, 154171-74-1, 154171-75-2, 154333-99-0, 154334-00-6, 154397-63-4, 154460-59-0, 199456-56-9, 108739-25-9, 120329-57-9, 120329-58-0
fullerene-C60

Conditions	Yield
In benzene satd. soln. of C60 in benzene was diffused into satd. soln. of Pt complex in benzene;

poly(9,9-dioctylfluorene) doped with platinum(II) octaethylporphine: poly(9,9-dioctylfluorene) doped with platinum(II) octaethylporphine

Conditions	Yield
In tetrahydrofuran; water Sonication; polymer dissolved in THF by stirring overnight in inert atmosphere, soln. of polymer and Pt-complex in THF added quickly to water while sonicated, sonicated for additional 10 s;

poly(9,9-dihexylfluorene) doped with platinum(II) octaethylporphine: poly(9,9-dihexylfluorene) doped with platinum(II) octaethylporphine

Conditions	Yield
In tetrahydrofuran; water Sonication; polymer dissolved in THF by stirring overnight in inert atmosphere, soln. of polymer and Pt-complex in THF added quickly to water while sonicated, sonicated for additional 10 s;