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| CAS No.: | 3652-90-2 |
|---|---|
| Name: | 2-Bromo-9H-carbazole |
| Article Data: | 64 |
| Cas Database | |
| Molecular Structure: | |
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|
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| Formula: | C12H8BrN |
| Molecular Weight: | 246.106 |
| Synonyms: | 9H-Carbazole, 2-bromo-;2-Bromocarbazole; |
| EINECS: | 807-979-0 |
| Density: | 1.617 g/cm3 |
| Melting Point: | 253.0 to 257.0 °C |
| Boiling Point: | 409.228 °C at 760 mmHg |
| Flash Point: | 201.294 °C |
| Solubility: | N/A |
| Appearance: | N/A |
| Hazard Symbols: | N/A |
| Risk Codes: | N/A |
| Safety: | |
| Transport Information: | N/A |
| PSA: | 15.79000 |
| LogP: | 4.08360 |
- 36530-06-0BORON SUBPHTHALOCYANINE CHLORIDE
- 36530-24-2Iridate(2-),hexabromo-, ammonium (1:2), (OC-6-11)-
- 36531-26-7Phenol, 3-(2-(1,4,5,6-tetrahydro-1-methyl-2-pyrimidinyl)ethenyl)-, (E)-
- 36531-78-9Karugamycin
- 3653-34-7Hexanoic acid,3-amino-5-methyl-
- 365-34-4Hydrazine,[2-(trifluoromethyl)phenyl]-
- 36536-69-3Palladate(2-), di-m-chlorotetrakis(P,P-diphenylphosphinito-kP)di-, hydrogen (1:2)
- 365411-50-3Indeno[4,5-d]-1,3-dioxin,4,4a,5,6,7,8,9,9b-octahydro-7,7,8,9,9-pentamethyl-
- 365413-00-91-Piperidinecarboxylicacid, 4-(4-carboxy-2-thiazolyl)-, 1-(1,1-dimethylethyl) ester
- 365413-31-61-Piperidinecarboxylicacid, 4-[4-(ethoxycarbonyl)-2-thiazolyl]-, 1,1-dimethylethyl ester
- 3652-90-2
2-bromo-9H-carbazole
| Conditions | Yield |
|---|---|
| With N1-(4-hydroxy-2,6-dimethylphenyl)-N2-(4-hydroxy-3,5-dimethylphenyl)oxalamide; water; copper(l) chloride; sodium t-butanolate In dimethyl sulfoxide at 110℃; for 24h; Schlenk technique; Inert atmosphere; | 99% |
- 35450-34-1
4'-bromo-2-nitrobiphenyl
- 3652-90-2
2-bromo-9H-carbazole
| Conditions | Yield |
|---|---|
| With triphenylphosphine In 1,2-dichloro-benzene at 170℃; for 12h; Inert atmosphere; | 89% |
| With triethyl phosphite In 1,2-dichloro-benzene at 80 - 150℃; Inert atmosphere; | 75% |
| Stage #1: 4'-bromo-2-nitrobiphenyl With triethyl phosphite at 160℃; for 2h; Stage #2: With hydrogenchloride In water for 1h; Reflux; | 67.6% |
| Conditions | Yield |
|---|---|
| With potassium fluoride; tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos; potassium bromide In 1,4-dioxane at 130℃; for 16h; Inert atmosphere; | 83% |
| Conditions | Yield |
|---|---|
| With triethylphosphine for 12h; Reflux; | 82.4% |
| With triphenylphosphine In 1,2-dichloro-benzene at 200℃; | 77% |
| With triphenylphosphine In 1,2-dichloro-benzene Inert atmosphere; Reflux; | 77% |
- 88284-48-4
2-(trimethylsilyl)phenyl trifluoromethanesulfonate
- 3652-90-2
2-bromo-9H-carbazole
| Conditions | Yield |
|---|---|
| With cesium fluoride In acetonitrile at 20℃; regioselective reaction; | 80% |
- 3652-90-2
2-bromo-9H-carbazole
| Conditions | Yield |
|---|---|
| In tetrahydrofuran for 4h; Solvent; Inert atmosphere; Irradiation; | 80% |
A
- 3652-90-2
2-bromo-9H-carbazole
| Conditions | Yield |
|---|---|
| With N1-(4-hydroxy-2,6-dimethylphenyl)-N2-(4-hydroxy-3,5-dimethylphenyl)oxalamide; water; copper(l) chloride; sodium hydroxide In dimethyl sulfoxide at 110℃; for 24h; Schlenk technique; Inert atmosphere; | A 74% B 26% |
- 3652-90-2
2-bromo-9H-carbazole
| Conditions | Yield |
|---|---|
| With sodium azide; copper(I) thiophene-2-carboxylate; sodium hydrogencarbonate; triphenylphosphine In N,N-dimethyl acetamide at 100℃; for 12h; Inert atmosphere; Schlenk technique; | 63% |
| With sodium azide; copper(I) thiophene-2-carboxylate; sodium hydrogencarbonate; triphenylphosphine In N,N-dimethyl acetamide at 100℃; for 12h; Inert atmosphere; Schlenk technique; | 63% |
- 62532-98-3
4'-bromo-[1,1'-biphenyl]-2-amine
- 3652-90-2
2-bromo-9H-carbazole
| Conditions | Yield |
|---|---|
| With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; copper diacetate; Trimethylacetic acid In 1-methyl-pyrrolidin-2-one at 120℃; for 12h; | 33% |
| Multi-step reaction with 2 steps 1.1: acetic acid; sodium nitrite / water / 1 h / 0 °C 1.2: Sandmeyer Reaction / 1 h / 0 - 20 °C / Inert atmosphere 2.1: tetrahydrofuran / 4 h / Inert atmosphere; Irradiation View Scheme | |
| Multi-step reaction with 3 steps 1.1: hydrogenchloride; sodium nitrite / water; tetrahydrofuran / 1 h / 0 - 5 °C 1.2: 20 °C 2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 0 - 20 °C 3.1: copper(I) thiophene-2-carboxylate; triphenylphosphine; sodium azide; sodium hydrogencarbonate / N,N-dimethyl acetamide / 12 h / 100 °C / Inert atmosphere; Schlenk technique View Scheme |
- 78863-99-7
7-bromo-2,3,4,9-tetrahydro-1H-carbazole
- 3652-90-2
2-bromo-9H-carbazole
| Conditions | Yield |
|---|---|
| With chloranil; xylene |
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Specification
1.Introduction of 2-Bromocarbazole
The 2-Bromocarbazole with the CAS number 3652-90-2 is also called 9H-Carbazole, 2-bromo-. The systematic name is 2-bromo-9H-carbazole. Its molecular formula is C12H8BrN. This chemical is a kind of organics. It should be stored in dry and cool environment.
2.The properties of the 2-Bromocarbazole
(1)ACD/LogP: 4.59; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 4; (4)ACD/LogD (pH 7.4): 4; (5)ACD/BCF (pH 5.5): 1527; (6)ACD/BCF (pH 7.4): 1527; (7)ACD/KOC (pH 5.5): 6614; (8)ACD/KOC (pH 7.4): 6614; (9)#H bond acceptors: 1; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 0; (12)Polar Surface Area: 15.79 Å2; (13)Index of Refraction: 1.784; (14)Molar Refractivity: 64.061 cm3; (15)Molar Volume: 152.172 cm3; (16)Polarizability: 25.396×10-24cm3; (17)Surface Tension: 60.866 dyne/cm; (18)Enthalpy of Vaporization: 63.566 kJ/mol; (19)Vapour Pressure: 0 mmHg at 25°C.
3.Structure descriptors of 2-Bromocarbazole
(1)SMILES: Brc1ccc2c3ccccc3nc2c1
(2)InChI: InChI=1/C12H8BrN/c13-8-5-6-10-9-3-1-2-4-11(9)14-12(10)7-8/h1-7,14H
(3)InChIKey: PJRGCJBBXGNEGD-UHFFFAOYAK