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Basic Information
CAS No.: 3923-79-3
Name: 4,5-dihydroxy-1,3-dimethylimidazolidin-2-one
Molecular Structure:
Molecular Structure of 3923-79-3 (4,5-dihydroxy-1,3-dimethylimidazolidin-2-one)
Formula: C5H10N2O3
Molecular Weight: 146.146
Synonyms: 1,3-Dimethyl-4,5-dihydroxyethyleneurea;1,3-dimethyl-4,5-dihydroxy-2-imidazolidinone;4,5-Dihydroxy-1,3-dimethyl-2-imidazolidinone;2-Imidazolidinone,4,5-dihydroxy-1,3-dimethyl;4,5-Dihydroxy-1,3-dimethyl-2-imidazalidinone;N,N'-dihydroxy ethylene urea;1,3-dimethyl-4,5-dihydroxyimidazolidin-2-one;2,6-dimethyl-4,5-dihydroxyimidazolidin-2-one;4,5-dihydroxy-1,3-dimethyl-imidazolidin-2-one;
Density: 1.442
Melting Point: 132-134℃
Boiling Point: 300.7°C at 760 mmHg
Flash Point: 135.7°C
Solubility: 1000g/L at 20℃
PSA: 64.01000
LogP: -1.50380
Synthetic route
598-94-7

1,1-Dimethylurea

3923-79-3

4,5-dihydroxy-1,3-dimethylimidazolidin-2-one

Conditions
ConditionsYield
In methanol83%
96-31-1

N,N'-Dimethylurea

3923-79-3

4,5-dihydroxy-1,3-dimethylimidazolidin-2-one

Conditions
ConditionsYield
With hydrogenchloride In water at 60℃; for 4h; pH=3;
With triethylamine In water at 25 - 35℃; pH=9;
In water at 50℃; for 4h; pH=4;
With triethylamine In water at 25 - 35℃; for 16h;
3923-79-3

4,5-dihydroxy-1,3-dimethylimidazolidin-2-one

24039-08-5

1,3-dimethylimidazolidine-2,4-dione

Conditions
ConditionsYield
sulfuric acid In 1,3-dimethyl-2-imidazolidinone at 150℃; for 2h; Product distribution / selectivity;100%
In water at 80 - 90℃; pH=1;
With sodium hydrogencarbonate In water at 60℃; for 4h;115 mg
With sulfuric acid In water at 95 - 100℃; for 6h;161 g
79-19-6

thiosemicarbazide

3923-79-3

4,5-dihydroxy-1,3-dimethylimidazolidin-2-one

A

5,7-dimethyl-3-thioxoperhydroimidazo[4,5-e]-1,2,4-triazin-6-one

B

24039-08-5

1,3-dimethylimidazolidine-2,4-dione

Conditions
ConditionsYield
With hydrogenchloride In methanol at 80℃; for 1h;A 96%
B n/a
79-19-6

thiosemicarbazide

3923-79-3

4,5-dihydroxy-1,3-dimethylimidazolidin-2-one

(4aRS,7aSR)-5,7-dimethyl-3-thioxooctahydroimidazo[4,5-e]-1,2,4-triazin-6-one

Conditions
ConditionsYield
With hydrogenchloride In methanol for 0.5h; Heating;94%
698-90-8

N'-cyclohexylurea

3923-79-3

4,5-dihydroxy-1,3-dimethylimidazolidin-2-one

4,5-bis(3-cyclohexylureido)-1,3-dimethyl-imidazolidin-2-one

Conditions
ConditionsYield
With hydrogenchloride at 80℃; for 1h; pH=1;92%
536-57-2

p-toluene sulfinic acid

3923-79-3

4,5-dihydroxy-1,3-dimethylimidazolidin-2-one

trans-4-hydroxy-1,3-dimethyl-5-(p-tolylsulfonyl)-2-imidazolidinone

Conditions
ConditionsYield
In water Ambient temperature;90.5%
79-19-6

thiosemicarbazide

3923-79-3

4,5-dihydroxy-1,3-dimethylimidazolidin-2-one

A

1,3-dimethyl-4,5-bis(3-thiosemicarbazido)imidazolidin-2-one

B

24039-08-5

1,3-dimethylimidazolidine-2,4-dione

Conditions
ConditionsYield
With hydrogenchloride In water at 80℃; for 1h; pH=2;A 90%
B n/a
536-57-2

p-toluene sulfinic acid

3923-79-3

4,5-dihydroxy-1,3-dimethylimidazolidin-2-one

1,3-dimethyl-4-(p-tolylsulfonyl)-2-imidazolinone

Conditions
ConditionsYield
In water for 0.5h; Heating;88.6%
70-55-3

toluene-4-sulfonamide

3923-79-3

4,5-dihydroxy-1,3-dimethylimidazolidin-2-one

N-[1,3-Dimethyl-2-oxo-imidazolidin-(4E)-ylidene]-4-methyl-benzenesulfonamide

Conditions
ConditionsYield
With hydrogenchloride In methanol at 60 - 70℃; for 0.5h;83%
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