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Basic Information
| CAS No.: | 421-17-0 |
|---|---|
| Name: | TRIFLUOROMETHYLSULPHENYL CHLORIDE |
| Article Data: | 57 |
| Molecular Structure: | |
|
|
|
| Formula: | CCl F3 S |
| Molecular Weight: | 136.525 |
| Synonyms: | Perfluoromethylsulfenylchloride; Trifluoromethanesulfenyl chloride; Trifluoromethylsulfenyl chloride;Trifluoromethylsulphenyl chloride |
| Density: | 1.573g/cm3 |
| Boiling Point: | °Cat760mmHg |
| Flash Point: | °C |
| Hazard Symbols: |
|
| Risk Codes: | 26-34 |
| Safety: | Explosive reaction with chlorine fluorides. When heated to decomposition it emits toxic fumes of F−, Cl−, and SOx. See also FLUORIDES. |
| PSA: | 25.30000 |
| LogP: | 2.39320 |
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Synthetic route
- 7664-39-3
hydrogen fluoride
- 594-42-3
chlorothio-trichloro-methane
A
- 421-17-0
Trifluoromethylsulfenyl chloride
B
- 372-64-5
Bis(trifluoromethyl)disulfid
C
- 358-15-6
Trifluoro-methanethiosulfonic acid S-trifluoromethyl ester
Conditions
| Conditions | Yield |
|---|---|
| 180°C; chrom oxide fluoride catalyst; | A 74% B n/a C n/a |
...Expand
Conditions
| Conditions | Yield |
|---|---|
| In further solvent(s) in tetramethylsulphone at 170-250°C; | 47% |
| In acetonitrile 170-250°C; | 47% |
| In acetonitrile 170-250°C; | 47% |
| In further solvent(s) in tetramethylsulphone at 170-250°C; | 47% |
| In acetonitrile 170-250°C; | 47% |
- 993-38-4
chlorodifluoromethansulfenylchloride
A
- 421-17-0
Trifluoromethylsulfenyl chloride
B
- 17742-03-9
chlorodifluoromethanesulphenic acid fluoride
Conditions
| Conditions | Yield |
|---|---|
| at 150°C; | A 25% B 5% |
| at 150°C; | A 25% B 5% |
...Expand
- 993-38-4
chlorodifluoromethansulfenylchloride
- 7783-56-4
antimony(III) fluoride
- 421-17-0
Trifluoromethylsulfenyl chloride
Conditions
| Conditions | Yield |
|---|---|
| 11% | |
| 11% |
Conditions
| Conditions | Yield |
|---|---|
| With antimonypentachloride; antimony(III) fluoride |
Conditions
| Conditions | Yield |
|---|---|
| With chlorine Irradiation.bei mehrtaegiger Bestrahlung mit UV-Licht; | |
| With chlorine Irradiation (UV/VIS); | |
| With chlorine Irradiation (UV/VIS); |
Conditions
| Conditions | Yield |
|---|---|
| With chlorine at -30℃; for 0.5h; Product distribution; |
- 594-42-3
chlorothio-trichloro-methane
A
- 993-38-4
chlorodifluoromethansulfenylchloride
B
- 421-17-0
Trifluoromethylsulfenyl chloride
...Expand
Conditions
| Conditions | Yield |
|---|---|
| With hydrogenchloride; water byproducts: HF; | |
| With HCl; H2O byproducts: HF; |
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TRIFLUOROMETHYLSULPHENYL CHLORIDE
Chemistry
Trifluoromethanesulfonyl chloride(421-17-0)'s molecular formula is CClF3S and its formula weight is 136.52.
Trifluoromethanesulfonyl chloride(421-17-0)'s chemical synonyms are Methanesulfenyl chloride, trifluoro-;Perfluoromethylsulfenyl chloride;perfluoromethylsulfenylchloride;trifluoro-methanesulfenylchlorid;trifluoromethanesulfenylchloride;trifluoromethane-sulfenylchloride;TRIFLUOROMETHYLSULFENYL CHLORIDE;TRIFLUOROMETHYLSULPHENYL CHLORIDE
The molecular structure of trifluoromethanesulfonyl chloride(421-17-0):
Trifluoromethanesulfonyl chloride(421-17-0)'s chemical synonyms are Methanesulfenyl chloride, trifluoro-;Perfluoromethylsulfenyl chloride;perfluoromethylsulfenylchloride;trifluoro-methanesulfenylchlorid;trifluoromethanesulfenylchloride;trifluoromethane-sulfenylchloride;TRIFLUOROMETHYLSULFENYL CHLORIDE;TRIFLUOROMETHYLSULPHENYL CHLORIDE
The molecular structure of trifluoromethanesulfonyl chloride(421-17-0):
Safety Profile
Explosive reaction with chlorine fluorides. When heated to decomposition it emits toxic fumes of F−, Cl−, and SOx. See also FLUORIDES.
Hazard Codes T
Risk Statements 26-34
Safety Statements 23-24/25-26-36/37/39-45
RIDADR 3308
Hazard Note Highly Toxic/Lachrymatory
Hazard Codes T
Risk Statements 26-34
Safety Statements 23-24/25-26-36/37/39-45
RIDADR 3308
Hazard Note Highly Toxic/Lachrymatory
Specification
Descriptors Computed from Structure
IUPAC Name: trifluoromethyl thiohypochlorite(421-17-0)
Canonical SMILES: C(F)(F)(F)SCl
InChI: InChI=1/CClF3S/c2-6-1(3,4)5
IUPAC Name: trifluoromethyl thiohypochlorite(421-17-0)
Canonical SMILES: C(F)(F)(F)SCl
InChI: InChI=1/CClF3S/c2-6-1(3,4)5