CAS No.4316-51-2,4-Methoxytriphenylamine 97 Suppliers,MSDS download

Products Categories

Pharmaceutical (21)
Organic Chemicals (13)
Others (9)
Materials (4)
Reagent (2)
Basic Inorganic Chemicals (2)

Basic Information

Molecular Structure:
CAS No.:	4316-51-2
Name:	4-Methoxytriphenylamine 97
Article Data:	90

Formula:	C₁₉H₁₇NO
Molecular Weight:	275.35
Synonyms:	p-Anisidine,N,N-diphenyl- (6CI,7CI,8CI);(4-Methoxyphenyl)diphenylamine;4-Diphenylaminoanisole;4-Methoxy-N,N-diphenylbenzenamine;4-Methoxytriphenylamine;N,N-Diphenyl-4-methoxyaniline;N,N-Diphenyl-p-anisidine;N-(4-Methoxyphenyl)-N,N-diphenylamine;N-(4-Methoxyphenyl)-N-phenylbenzenamine;p-Anisyldiphenylamine;
Density:	1.126 g/cm³
Melting Point:	102-106 °C(lit.)
Boiling Point:	415.435 °C at 760 mmHg
Flash Point:	121.934 °C
Hazard Symbols:	Xi
Risk Codes:	36/37/38-43
Safety:	26-36/37/39
PSA:	12.47000
LogP:	5.16500

Synthetic route

: 623-12-1
4-chloromethoxybenzene

: 122-39-4
diphenylamine

: 4316-51-2
N,N-diphenyl-4-methoxyaniline

Conditions

Conditions	Yield
With monophosphine 1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 80℃; for 12h;	99%
With bis(η3-allyl-μ-chloropalladium(II)); 2,6-bis(2,4,6-triisopropylphenyl)phenyl(dicyclohexylphosphine); sodium t-butanolate In dodecane; toluene at 100℃; for 6h; Catalytic behavior; Reagent/catalyst; Glovebox;	99%
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 70℃; for 16h;	97%

: 104-92-7
1-bromo-4-methoxy-benzene

: 122-39-4
diphenylamine

: 4316-51-2
N,N-diphenyl-4-methoxyaniline

Conditions

Conditions	Yield
With potassium hydroxide; bis(tri-tert-butylphosphine)palladium(0); cetyltrimethylammonim bromide In water; toluene at 90℃; for 6h;	99%
With palladium diacetate; sodium t-butanolate; ruphos In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Green chemistry;	99%
With sodium t-butanolate; tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane In toluene at 50℃;	97%

: 696-62-8
para-iodoanisole

: 122-39-4
diphenylamine

: 4316-51-2
N,N-diphenyl-4-methoxyaniline

Conditions

Conditions	Yield
With copper(l) iodide; 5,6,9,10-tetrahydro-4H,8H-pyrido[3,2,1-ij][1,6]naphthyridine; sodium t-butanolate In toluene at 110℃; for 40h; post-Ullmann reaction;	96%
With [Pd{C6H4(CH2N(CH2Ph)2)}(μ-Br)]2; potassium hydroxide In dimethyl sulfoxide at 120℃; for 3h;	96%
With sodium t-butanolate; tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane In toluene at 30℃;	93%

: 108-86-1
bromobenzene

: 104-94-9
4-methoxy-aniline

: 4316-51-2
N,N-diphenyl-4-methoxyaniline

Conditions

Conditions	Yield
With dichloro{1,10-[di-(2-diizopropylaminoethyl)]-3,3'-o-xylyldibenzimidazolidin-2,2'-diylidene}palladium (II); potassium tert-butylate In 1,2-dimethoxyethane at 80℃; for 15h; Buchwald-Hartwig amination; Inert atmosphere;	95%
With (6-Dipp)PdCl2-SPhos; sodium t-butanolate In neat (no solvent) at 110℃; for 24h; Reagent/catalyst; Buchwald-Hartwig Coupling; Inert atmosphere;	90%
With potassium hydroxide In water for 24h; Buchwald-Hartwig reaction; Reflux; Inert atmosphere;	85%

: 591-50-4
iodobenzene

: 104-94-9
4-methoxy-aniline

: 4316-51-2
N,N-diphenyl-4-methoxyaniline

Conditions

Conditions	Yield
With [2,2]bipyridinyl; potassium tert-butylate; copper(l) iodide In toluene at 115℃; for 3.5h;	94%
With tetraethoxy orthosilicate; caesium carbonate; copper(l) iodide at 145℃; for 38h; Ullmann coupling reaction;	85%
With C39H33CuF3N2P2(1+)*ClO4(1-); potassium tert-butylate In toluene at 90℃; for 12h; Inert atmosphere;	80%

: 104-92-7
1-bromo-4-methoxy-benzene

: 17425-91-1
N-(trimethylsilyl)-diphenylamine

: 4316-51-2
N,N-diphenyl-4-methoxyaniline

Conditions

Conditions	Yield
With cesium fluoride; bis(dibenzylideneacetone)-palladium(0); XPhos at 100℃; for 1h; Inert atmosphere;	94%
With cesium fluoride; bis(dibenzylideneacetone)-palladium(0); XPhos at 100℃; for 1h; Time; Reagent/catalyst; Inert atmosphere;	94%
With bis(1,5-cyclooctadiene)nickel (0); 1,3-bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene hydrochloride; potassium tert-butylate; cesium fluoride at 100℃; for 36h; Inert atmosphere;	67%

: 104-94-9
4-methoxy-aniline

: 88284-48-4
2-(trimethylsilyl)phenyl trifluoromethanesulfonate

: 4316-51-2
N,N-diphenyl-4-methoxyaniline

Conditions

Conditions	Yield
With cesium fluoride In acetonitrile at 20℃; for 72h;	90%

: 108-86-1
bromobenzene

: 104-94-9
4-methoxy-aniline

A: 1208-86-2
N-(4-methoxyphenyl)phenylamine

B: 4316-51-2
N,N-diphenyl-4-methoxyaniline

Conditions

Conditions	Yield
With C46H58Br2N4O10Pd; potassium tert-butylate In 1,2-dimethoxyethane at 80℃; for 15h; Inert atmosphere; Buchwald-Hartwig amination;	A 11% B 89%
With potassium tert-butylate; copper(l) iodide; tributylphosphine In toluene at 135℃; for 10.5h; high pressure;	A 2% B 86%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; palladium 10% on activated carbon; sodium t-butanolate In 1,3,5-trimethyl-benzene for 24h; Inert atmosphere; Reflux;	A 41% B 45%

...Expand

: 104-94-9
4-methoxy-aniline

: 88284-48-4
2-(trimethylsilyl)phenyl trifluoromethanesulfonate

A: 1208-86-2
N-(4-methoxyphenyl)phenylamine

B: 4316-51-2
N,N-diphenyl-4-methoxyaniline

Conditions

Conditions	Yield
With cesium fluoride In acetonitrile at 20℃; for 10h;	A 89% B 4%

...Expand

: 104-94-9
4-methoxy-aniline

: 108-90-7
chlorobenzene

A: 1208-86-2
N-(4-methoxyphenyl)phenylamine

B: 4316-51-2
N,N-diphenyl-4-methoxyaniline

Conditions

Conditions	Yield
With potassium tert-butylate; copper(l) iodide; tributylphosphine In toluene at 135℃; for 10.5h; high pressure;	A 3% B 85%

...Expand

Total:42 Page 1 of 2 1 2 Next>>

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

What can I do for you?
Get Best Price

Get Best Price for 4316-51-2

Chemistry

Molecule structure of 4-Methoxytriphenylamine 97 (CAS NO.4316-51-2):

Molecular Weight: 275.3444 g/mol
Molecular Formula: C₁₉H₁₇NO
Density: 1.126 g/cm³
Melting Point: 102-106 °C(lit.)
Boiling Point: 415.435 °C at 760 mmHg
Flash Point: 121.934 °C
Index of Refraction: 1.628
Molar Refractivity: 86.775 cm³
Molar Volume: 244.596 cm³
Surface Tension: 45.39 dyne/cm
Enthalpy of Vaporization: 66.852 kJ/mol
InChI: InChI=1/C19H17NO/c1-21-19-14-12-18(13-15-19)20(16-8-4-2-5-9-16)17-10-6-3-7-11-17/h2-15H,1H3 InChIKey of 4-Methoxytriphenylamine 97 (CAS NO.4316-51-2): KIGTXAWIOISJOG-UHFFFAOYAO

Safety Profile

Hazard Codes: Irritant Xi
Risk Statements: 36/37/38-43
R36/37/38:Irritating to eyes, respiratory system and skin.
R43:May cause sensitization by skin contact.
Safety Statements: 26-36/37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
WGK Germany: 3

Specification

4-Methoxytriphenylamine 97 (CAS NO.4316-51-2) is also named as 4-methoxy-n,n-diphenylaniline ; Diphenyl(4-methoxyphenyl)amine ; Diphenyl(p-methoxyphenyl)amine ; N,N-Diphenyl-4-methoxyaniline ; N,N-Diphenyl-p-anisidine ; p-Anisyldiphenylamine .