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477-47-4

Basic Information
CAS No.: 477-47-4
Name: (-)PPP
Article Data: 38
Molecular Structure:
Molecular Structure of 477-47-4 ((-)PPP)
Formula: C22H22O8
Molecular Weight: 414.412
Synonyms: Furo[3',4':6,7]naphtho[2,3-d]-1,3-dioxol-6(5aH)-one,5,8,8a,9-tetrahydro-9-hydroxy-5-(3,4,5-trimethoxyphenyl)-, [5R-(5a,5aa,8aa,9a)]-;Picropodophyllin(6CI,7CI,8CI);NSC 36407;Picropodophyllotoxin;
Density: 1.37g/cm3
Melting Point: 225-227℃
Boiling Point: 597.9°Cat760mmHg
Flash Point: 210.2°C
Hazard Symbols: A poison.
Risk Codes: 36/37/38-68-25-21
Safety: A poison by intraperitoneal route. When heated to decomposition it emits acrid smoke and irritating vapors.
PSA: 92.68000
LogP: 2.40920
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Chemistry

IUPAC Name: (5R,5aR,8aR,9R)-5-Hydroxy-9-(3,4,5-trimethoxyphenyl)-5a,6,8a,9-tetrahydro-5H-isobenzofurano[5,6-f][1,3]benzodioxol-8-one
Synonyms: (5R,5aR,8aR,9R)-5,8,8a,9-Tetrahydro-9-hydroxy-5-(3,4,5-trimethoxyphenyl)furo[3',4':6,7]naphtho[2,3-d]-1,3-dioxol-6(5aH)-one ; (5R,5aR,8aR,9R)-9-Hydroxy-5-(3,4,5-trimethoxyphenyl)-5,8,8a,9-tetrahydrofuro[3',4':6,7]naphtho[2,3-d][1,3]dioxol-6(5aH)-on ; (5R,5aR,8aR,9R)-9-Hydroxy-5-(3,4,5-trimethoxyphenyl)-5,8,8a,9-tetrahydrofuro[3',4':6,7]naphtho[2,3-d][1,3]dioxol-6(5aH)-one ; (5R,5aR,8aR,9R)-9-Hydroxy-5-(3,4,5-triméthoxyphényl)-5,8,8a,9-tétrahydrofuro[3',4':6,7]naphto[2,3-d][1,3]dioxol-6(5aH)-one
CAS NO:477-47-4
Molecular Formula of Picropodophyllotoxin (CAS NO.477-47-4) :C22H22O8
Molecular Weight of Picropodophyllotoxin (CAS NO.477-47-4) :414.4053
Molecular structure of Picropodophyllotoxin (CAS NO.477-47-4) :
Index of Refraction:1.605
Surface Tension: 52.7 dyne/cm
Density: 1.37 g/cm3
Flash Point: 210.2 °C
Enthalpy of Vaporization: 93.64 kJ/mol
Boiling Point: 597.9 °C at 760 mmHg
Vapour Pressure: 3.82E-15 mmHg at 25°C
Storage temp. 2-8°C
Solubility H2O: soluble

Toxicity Data With Reference

 

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 280mg/kg (280mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: TREMOR

LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION
Proceedings of the Society for Experimental Biology and Medicine. Vol. 77, Pg. 269, 1951.

Safety Profile

A poison by intraperitoneal route. When heated to decomposition it emits acrid smoke and irritating vapors.
Hazard Codes IrritantXi,ToxicT
Risk Statements 36/37/38-68-25-21
R21:Harmful in contact with skin. 
R25 :Toxic if swallowed. 
R68:Possible risk of irreversible effects. 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements 26-36-45-36/37
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36:Wear suitable protective clothing. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S36/37:Wear suitable protective clothing and gloves.
RIDADR UN 3462 6.1/PG 2
WGK Germany 3
RTECS LV2510000