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479-45-8

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Basic Information
CAS No.: 479-45-8
Name: TETRYL
Article Data: 48
Molecular Structure:
Molecular Structure of 479-45-8 (TETRYL)
Formula: C7H5 N5 O8
Molecular Weight: 287.145
Synonyms: Aniline,N-methyl-N,2,4,6-tetranitro- (8CI); 2,4,6,N-Tetranitro-N-methylaniline;2,4,6-Tetryl; 2,4,6-Trinitro-N-methyl-N-nitroaniline;2,4,6-Trinitrophenyl-N-methylnitramine; 2,4,6-Trinitrophenylmethylnitroamine;CE; N-Methyl-N,2,4,6-tetranitroaniline; N-Methyl-N-picrylnitramine;N-Picryl-N-methylnitramine; NSC 2166; Nitramine; Nitramine (indicator);Picrylmethylnitramine; Picrylnitromethylamine; Tetralit; Tetralite; Tetril;Tetryl
EINECS: 207-531-9
Density: 1.803g/cm3
Melting Point: 130 C
Boiling Point: 503.7°Cat760mmHg
Flash Point: 258.4°C
Solubility: Toxicity data
(The ">

Stability

    Stable. Incompatible with strong oxidizing agents.

Toxicology

    Harmful if swallowed, inhaled or absorbed through the skin. Irritant.

    Toxicity data
    (The

Appearance: solid
Hazard Symbols: Dangerous fire and explosion risk. Skin irritant, absorbed by skin. TLV: 1.5 mg/m3.
Risk Codes: 2-23/24/25-33-36/37/38-11
Safety: Mutation data reported. An irritant, sensitizer, and allergen. The chief effect from exposure is dermatitis. Conjunctivitis is followed by iridocyclitis, and keratitis can occur. Sensitization produced by exposure may play a part in these symptoms. Gastrointestinal effects and anemia have also been reported.

A powerful oxidant. A dangerous fire and explosion hazard. A high explosive sensitive to shock, friction, or heat. More sensitive to shock and friction than TNT. Explodes on contact with trioxygen difluoride. Ignites on contact with hydrazine. When heated to decomposition it emits toxic fumes of NOx. See also NITRATES and EXPLOSIVES, HIGH.

PSA: 186.52000
LogP: 3.13190
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Chemistry

Molecular formula: C7H5N5O8
Molar mass: 287.15 g/mol
Density: 1.73 g/cm3
Melting point: 129.5 °C, 403 K, 265 °F
Boiling point: Decomposes at 187 °C
Appearance: Odorless yellow crystalline solid
Other names: nitramine; tetralite; tetril; 2,4,6-trinitrophenylmethylnitramine;
Tetryl(479-45-8) is an odorless yellow crystalline solid that is not found naturally in the environment.
The Structure of Tetryl(479-45-8):

Uses

Tetryl(479-45-8) is a high explosive with intermediate sensitivity and is used as abase charge in blasting caps, as the booster explosive in high-explosive shells, and as an ingredient of binary explosives.

Production

Tetryl(479-45-8) is manufactured by the action of mixed sulfuric and nitric acid on dimethylaniline in a multiple-stage nitration。
 It may also be manufactured by alkylating 2,4-dinitrochlorobenzene with methylamine followed by nitration.

Toxicity Data With Reference

1.   

mmo-sat 2500 ng/plate

   TOLED5    Toxicology Letters. 5 (1980),11.
2.   

mma-sat 2500 ng/plate

   TOLED5    Toxicology Letters. 5 (1980),11.
3.   

mmo-nsc 5 µg/plate

   TOLED5    Toxicology Letters. 5 (1980),11.
4.   

mrc-smc 5 µg/plate

   TOLED5    Toxicology Letters. 5 (1980),11.
5.   

scu-dog LDLo:5000 mg/kg

   JIDHAN    Journal of Industrial Hygiene. 2 (1920),247.

Safety Profile

Mutation data reported. An irritant, sensitizer, and allergen. The chief effect from exposure is dermatitis. Conjunctivitis is followed by iridocyclitis, and keratitis can occur. Sensitization produced by exposure may play a part in these symptoms. Gastrointestinal effects and anemia have also been reported.

A powerful oxidant. A dangerous fire and explosion hazard. A high explosive sensitive to shock, friction, or heat. More sensitive to shock and friction than TNT. Explodes on contact with trioxygen difluoride. Ignites on contact with hydrazine. When heated to decomposition it emits toxic fumes of NOx. See also NITRATES and EXPLOSIVES, HIGH.

Standards and Recommendations

OSHA PEL: TWA 0.1 mg/m3 (skin)
ACGIH TLV: TWA 1.5 mg/m3
DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans
DOT Classification:  EXPLOSIVE 1.1D; Label: EXPLOSIVE 1.1D