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| CAS No.: | 489-41-8 | ||
|---|---|---|---|
| Name: | (-)-GLOBULOL | ||
| Molecular Structure: | |||
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|
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| Formula: | C15H26 O | ||
| Molecular Weight: | 222.371 | ||
| Synonyms: | 1H-Cycloprop[e]azulen-4-ol,decahydro-1,1,4,7-tetramethyl-, [1aR-(1aa,4a,4aa,7a,7ab,7ba)]-; Globulol (6CI,7CI);(-)-Globulol; NSC 152470 | ||
| Density: | 0.962g/cm3 | ||
| Melting Point: |
87-88 °C |
||
| Boiling Point: | 283°C | ||
| Flash Point: | 123.1°C | ||
| Safety: |
|
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| PSA: | 20.23000 | ||
| LogP: | 3.46570 | ||
- 5156-58-1N-(1-Benzyl-4-pipperidinyl)-N-phenylpropanamide HCl
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- 186318-55-8
Toluene-4-sulfonic acid (1aR,4R,4aR,7R,7aS,7bS)-4-hydroxy-1,1,7-trimethyl-decahydro-cyclopropa[e]azulen-4-ylmethyl ester
- 489-41-8
(-)-globulol
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride In tetrahydrofuran for 3h; Heating; | 160 mg |
| Conditions | Yield |
|---|---|
| Multi-step reaction with 3 steps 1: 900 mg / K3, K2CO3, OsO4 / 2-methyl-propan-2-ol; H2O / 24 h / Ambient temperature 2: pyridine / Ambient temperature 3: 160 mg / LiAlH4 / tetrahydrofuran / 3 h / Heating View Scheme |
- 145988-09-6
(1S,2S,4R,7R,8R,11R)-3,3,11-trimethyl-7-hydroxymethyl-tricyclo<6.3.0.02,4>undecan-7-ol
- 489-41-8
(-)-globulol
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: pyridine / Ambient temperature 2: 160 mg / LiAlH4 / tetrahydrofuran / 3 h / Heating View Scheme |
- 489-39-4
(+)-aromadendrene
A
- 489-41-8
(-)-globulol
B
- 88728-58-9
1,1,4,7-tetramethyldecahydro-1H-cyclopropa[e]azulen-4-ol
| Conditions | Yield |
|---|---|
| With iron(III)-acetylacetonate; 1,3-dibromo-5-fluoro-2-nitrobenzene; phenylsilane; sodium hydrogencarbonate In methanol at 0 - 20℃; for 12h; Reagent/catalyst; Schlenk technique; Inert atmosphere; Overall yield = 61 percent; diastereoselective reaction; | A n/a B n/a |
- 489-41-8
(-)-globulol
A
- 123735-83-1
6β,7α,14-trihydroxyaromadendrane
B
- 123808-27-5
7α,14-dihydroxyaromadendrane
C
- 186318-53-6
5α,7α-dihydroxyaromadendrane
| Conditions | Yield |
|---|---|
| In ethanol for 144h; Mucor plumbeus; | A 1% B 58% C 1% |
- 489-41-8
(-)-globulol
- 145941-01-1
(1S,2S,3S,4R,7R,8R,11R)-7-hydroxy-3,7,11-trimethyltricyclo<6.3.0.02,4>undecane-3-carboxylic acid
| Conditions | Yield |
|---|---|
| In N,N-dimethyl-formamide for 96h; Mycobacterium smegmatis DSM 43061; | 46% |
| Conditions | Yield |
|---|---|
| With pyridine; trichlorophosphate |
- 489-41-8
(-)-globulol
A
- 145940-99-4
9-hydroxyglobulol
B
- 123735-83-1
6β,7α,14-trihydroxyaromadendrane
C
- 145941-00-0
9,14-exo-dihydroxyglobulol
D
- 123808-27-5
7α,14-dihydroxyaromadendrane
| Conditions | Yield |
|---|---|
| In N,N-dimethyl-formamide for 28h; Bacillus megaterium DSM 32; Further byproducts given; | A 4 mg B 31 mg C 6 mg D 60 mg |
- 489-41-8
(-)-globulol
A
- 145940-98-3
6-hydroxyglobulol
B
- 123735-83-1
6β,7α,14-trihydroxyaromadendrane
C
- 145941-00-0
9,14-exo-dihydroxyglobulol
D
- 123808-27-5
7α,14-dihydroxyaromadendrane
| Conditions | Yield |
|---|---|
| In N,N-dimethyl-formamide for 28h; Bacillus megaterium DSM 32; Further byproducts given; | A 8 mg B 31 mg C 6 mg D 60 mg |
- 489-41-8
(-)-globulol
A
- 145940-98-3
6-hydroxyglobulol
B
- 123735-83-1
6β,7α,14-trihydroxyaromadendrane
C
- 123808-26-4
14-endohydroxyglobulol
D
- 123808-27-5
7α,14-dihydroxyaromadendrane
| Conditions | Yield |
|---|---|
| In N,N-dimethyl-formamide for 28h; Bacillus megaterium DSM 32; Further byproducts given; | A 8 mg B 31 mg C 2 mg D 60 mg |
