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CAS No.: | 4895-65-2 |
---|---|
Name: | Phenyltetrachlorphosphorus |
Article Data: | 20 |
Molecular Structure: | |
Formula: | C6H5Cl4P |
Molecular Weight: | 249.891 |
Synonyms: | Phenylphosphorus tetrachloride;Tetrachloro(phenyl)-λ5-phosphane; |
PSA: | 13.59000 |
LogP: | 4.48040 |
Conditions | Yield |
---|---|
With chlorine In tetrachloromethane at 20℃; for 5h; | 86% |
With chlorine | |
With chlorine In benzene octane was used as well (as solvent); | |
With chlorine In chloroform at 30℃; for 0.333333h; |
Dichlorophenylphosphine
A
phenyltetrachlorophosphorane
B
phenylthiophosphonic acid dichloride
Conditions | Yield |
---|---|
With sulphur monochloride |
Conditions | Yield |
---|---|
With chlorine |
phenyltrichlorophosphonium hexachlorophosphorate
A
3-chloro-cyclohexene
B
phenyltetrachlorophosphorane
trans-1,2-dichlorocyclohexane
Conditions | Yield |
---|---|
With cyclohexene In 1,2-dichloro-ethane at 60℃; for 2h; Yields of byproduct given. Title compound not separated from byproducts; |
phenyltrichlorophosphonium hexachlorophosphorate
phenyltetrachlorophosphorane
Conditions | Yield |
---|---|
With cyclohexene In 1,2-dichloro-ethane at 60℃; for 2h; Mechanism; |
Conditions | Yield |
---|---|
With chlorine In toluene |
cyclohexene
A
3-chloro-cyclohexene
B
phenyltetrachlorophosphorane
trans-1,2-dichlorocyclohexane
Conditions | Yield |
---|---|
With phenyltrichlorophosphonium hexachlorophosphorate In 1,2-dichloro-ethane at 60℃; for 2h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: phosphorus trichloride / 180 °C 2: chlorine View Scheme |
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The Phosphorane,tetrachlorophenyl-, with the CAS registry number 4895-65-2, is also known as Phenylphosphorus tetrachloride. This chemical's molecular formula is C6H5Cl4P and molecular weight is 249.89. What's more, its systematic name is tetrachloro(phenyl)-λ5-phosphane.
Physical properties of Phosphorane,tetrachlorophenyl- are: (1)#H bond acceptors: 0; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 1; (4)Polar Surface Area: 0 Å2.
You can still convert the following datas into molecular structure:
(1)SMILES: c1ccc(cc1)P(Cl)(Cl)(Cl)Cl
(2)Std. InChI: InChI=1S/C6H5Cl4P/c7-11(8,9,10)6-4-2-1-3-5-6/h1-5H
(3)Std. InChIKey: JRJVWTRZBBWEDZ-UHFFFAOYSA-N