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4895-65-2

Basic Information
CAS No.: 4895-65-2
Name: Phenyltetrachlorphosphorus
Article Data: 20
Molecular Structure:
Molecular Structure of 4895-65-2 (Phenyltetrachlorphosphorus)
Formula: C6H5Cl4P
Molecular Weight: 249.891
Synonyms: Phenylphosphorus tetrachloride;Tetrachloro(phenyl)-λ5-phosphane;
PSA: 13.59000
LogP: 4.48040
Synthetic route
644-97-3

Dichlorophenylphosphine

4895-65-2

phenyltetrachlorophosphorane

Conditions
ConditionsYield
With chlorine In tetrachloromethane at 20℃; for 5h;86%
With chlorine
With chlorine In benzene octane was used as well (as solvent);
With chlorine In chloroform at 30℃; for 0.333333h;
644-97-3

Dichlorophenylphosphine

A

4895-65-2

phenyltetrachlorophosphorane

B

3497-00-5

phenylthiophosphonic acid dichloride

Conditions
ConditionsYield
With sulphur monochloride
824-72-6

P,P-dichlorophenylphosphine oxide

4895-65-2

phenyltetrachlorophosphorane

Conditions
ConditionsYield
With chlorine
55045-25-5

phenyltrichlorophosphonium hexachlorophosphorate

A

2441-97-6

3-chloro-cyclohexene

B

4895-65-2

phenyltetrachlorophosphorane

822-86-6

trans-1,2-dichlorocyclohexane

Conditions
ConditionsYield
With cyclohexene In 1,2-dichloro-ethane at 60℃; for 2h; Yields of byproduct given. Title compound not separated from byproducts;
55045-25-5

phenyltrichlorophosphonium hexachlorophosphorate

4895-65-2

phenyltetrachlorophosphorane

Conditions
ConditionsYield
With cyclohexene In 1,2-dichloro-ethane at 60℃; for 2h; Mechanism;
603-35-0

triphenylphosphine

4895-65-2

phenyltetrachlorophosphorane

Conditions
ConditionsYield
With chlorine In toluene
110-83-8

cyclohexene

A

2441-97-6

3-chloro-cyclohexene

B

4895-65-2

phenyltetrachlorophosphorane

822-86-6

trans-1,2-dichlorocyclohexane

Conditions
ConditionsYield
With phenyltrichlorophosphonium hexachlorophosphorate In 1,2-dichloro-ethane at 60℃; for 2h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
7782-50-5

chlorine

644-97-3

Dichlorophenylphosphine

4895-65-2

phenyltetrachlorophosphorane

7790-99-0

Iodine monochloride

644-97-3

Dichlorophenylphosphine

4895-65-2

phenyltetrachlorophosphorane

587-85-9

diphenylmercury(II)

4895-65-2

phenyltetrachlorophosphorane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: phosphorus trichloride / 180 °C
2: chlorine
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Specification

The Phosphorane,tetrachlorophenyl-, with the CAS registry number 4895-65-2, is also known as Phenylphosphorus tetrachloride. This chemical's molecular formula is C6H5Cl4P and molecular weight is 249.89. What's more, its systematic name is tetrachloro(phenyl)-λ5-phosphane.

Physical properties of Phosphorane,tetrachlorophenyl- are: (1)#H bond acceptors: 0; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 1; (4)Polar Surface Area: 0 Å2.

You can still convert the following datas into molecular structure:
(1)SMILES: c1ccc(cc1)P(Cl)(Cl)(Cl)Cl
(2)Std. InChI: InChI=1S/C6H5Cl4P/c7-11(8,9,10)6-4-2-1-3-5-6/h1-5H
(3)Std. InChIKey: JRJVWTRZBBWEDZ-UHFFFAOYSA-N