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502-37-4

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Basic Information
CAS No.: 502-37-4
Name: HYPOGLYCINB
Molecular Structure:
Molecular Structure of 502-37-4 (HYPOGLYCINB)
Formula: C12H18 N2 O5
Molecular Weight: 270.285
Synonyms: Alanine,L-g-glutamyl-3-[(1R)-methylenecyclopropyl]-(9CI); Alanine, N-L-g-glutamyl-3-(methylenecyclopropyl)-, (R)-; Glutamine,N-[1-carboxy-2-(methylenecyclopropyl)ethyl]- (7CI); Hypoglycine B (6CI,8CI);Hypoglycin B; g-L-Glutamyl-a-amino-b-(2-methylenecyclopropyl)propionicacid
Density: 1.33g/cm3
Melting Point: 194-195°, 200-206°
Boiling Point: 592.8°Cat760mmHg
Flash Point: 312.3°C
Safety: Poison by intravenous route. An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits toxic fumes of NOx.
PSA: 133.21000
LogP: 1.25470
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    HYPOGLYCINB

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Chemistry

IUPAC Name: (2S)-2-Amino-5-[[2-hydroxy-1-[[(1R)-2-methylenecyclopropyl]methyl]-2-oxo-ethyl]amino]-5-oxo-pentanoic acid
Synonyms of Hypoglycine B (CAS NO.502-37-4) : g-L-Glutamyl-a-amino-b-(2-methylenecyclopropyl)propionic Acid Dipeptide ; g-L-Glutamylhypoglycine ; Hypoglycine B
CAS NO: 502-37-4
Molecular Formula:C12H18N2O5
Molecular Weight :270.2817
Molecular Structure :
Index of Refraction: 1.562
Surface Tension: 61.7 dyne/cm
Density: 1.33 g/cm3
Flash Point: 312.3 °C
Enthalpy of Vaporization: 96.56 kJ/mol
Boiling Point: 592.8 °C at 760 mmHg
Vapour Pressure: 1.38E-15 mmHg at 25°C

Uses

  Hypoglycine B (CAS NO.502-37-4) is toxic if ingested and is a causative agent of Jamaican Vomiting Sickness. It is an amino acid and chemically related to lysine.

Production

Hypoglycin B is a naturally occurring organic compound in the species Blighia sapida. It is particularly concentrated in the fruit of the plant especially in the seeds.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LDLo intravenous 160mg/kg (160mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA		 Journal of Pharmacology and Experimental Therapeutics. Vol. 121, Pg. 272, 1957.
rabbit LDLo intravenous 25mg/kg (25mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: ATAXIA

ENDOCRINE: HYPOGLYCEMIA		 Journal of Pharmacology and Experimental Therapeutics. Vol. 121, Pg. 272, 1957.
rat LDLo intravenous 200mg/kg (200mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA		 Journal of Pharmacology and Experimental Therapeutics. Vol. 121, Pg. 272, 1957.

Safety Profile

Poison by intravenous route. An experimental teratogen. Other experimental reproductive effects. When  Hypoglycine B (CAS NO.502-37-4) is heated to decomposition,S37/39:Wear suitable gloves and eye/face protection.  it emits toxic fumes of NOx.