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Basic Information
CAS No.: 55682-83-2
Name: METHYL 3-HYDROXYTETRADECANOATE
Molecular Structure:
Molecular Structure of 55682-83-2 (METHYL 3-HYDROXYTETRADECANOATE)
Formula: C15H30 O3
Molecular Weight: 258.401
Synonyms: (?à)-Methyl 3-Hydroxytetradecanoate;Methyl 3-hydroxytetradecanoate
Density: 0.931g/cm3
Boiling Point: 359.1°Cat760mmHg
Flash Point: 137.5°C
PSA: 46.53000
LogP: 3.83130
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Synthetic route
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methyl 3-oxotetradecanoate

55682-83-2

(+/-)-3-hydroxytetradecanoic acid methyl ester

Conditions
ConditionsYield
With sodium tetrahydroborate In methanol at 0℃;86%
With sodium tetrahydroborate In methanol at 5 - 10℃; for 2h;
With sodium tetrahydroborate In tetrahydrofuran; methanol
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Dodecanal

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bromoacetic acid methyl ester

55682-83-2

(+/-)-3-hydroxytetradecanoic acid methyl ester

Conditions
ConditionsYield
With zinc In benzene for 2h; Heating;82%
143-07-7

lauric acid

monomethoxy poly(ethylene glycol)

monomethoxy poly(ethylene glycol)

55682-83-2

(+/-)-3-hydroxytetradecanoic acid methyl ester

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: tetrahydrofuran / 0 - 20 °C
2: 14.72 g / 72 h / 20 °C
3: 86 percent / sodium borohydride / methanol / 0 °C
View Scheme
3867-67-2

N-laurylimidazole

55682-83-2

(+/-)-3-hydroxytetradecanoic acid methyl ester

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 14.72 g / 72 h / 20 °C
2: 86 percent / sodium borohydride / methanol / 0 °C
View Scheme
112-16-3

n-dodecanoyl chloride

glycerol-1-caprinate-3-stearate

glycerol-1-caprinate-3-stearate

55682-83-2

(+/-)-3-hydroxytetradecanoic acid methyl ester

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: pyridine / CH2Cl2 / 0 deg C, 1 h then r.t., 4 h
2: 3 h / Heating
3: NaBH4 / methanol / 2 h / 5 - 10 °C
View Scheme
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3-oxomyristic acid

55682-83-2

(+/-)-3-hydroxytetradecanoic acid methyl ester

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 3 h / Heating
2: NaBH4 / methanol / 2 h / 5 - 10 °C
View Scheme
polyhydroxyalkanoate

polyhydroxyalkanoate

A

C14H20O4

B

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3-hydroxybutyric acid methyl ester

C

7367-87-5

3-hydroxyoctanoic acid methyl ester

D

62675-82-5

methyl 3-hydroxydecanoate

E

72864-23-4

β-hydroxydodecanoic acid methyl ester

F

55682-83-2

(+/-)-3-hydroxytetradecanoic acid methyl ester

G

129880-16-6

3-hydroxy-5-phenyl-pentanoic acid methyl ester

Conditions
ConditionsYield
Product distribution / selectivity;
...Expand
polyhydroxyalkanoate

polyhydroxyalkanoate

A

C13H15FO4

B

1487-49-6

3-hydroxybutyric acid methyl ester

C

7367-87-5

3-hydroxyoctanoic acid methyl ester

D

21188-58-9

methyl 3-hydroxyhexanoate

E

62675-82-5

methyl 3-hydroxydecanoate

F

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3-hydroxy valeric acid methyl ester

G

15889-95-9

methyl 3-hydroxyheptanoate

H

83968-06-3

methyl 3-hydroxy-nonanoate

I

72864-23-4

β-hydroxydodecanoic acid methyl ester

J

55682-83-2

(+/-)-3-hydroxytetradecanoic acid methyl ester

Conditions
ConditionsYield
Product distribution / selectivity;
...Expand
polyhydroxyalkanoate

polyhydroxyalkanoate

A

C13H15FO4

B

1487-49-6

3-hydroxybutyric acid methyl ester

C

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3-hydroxyoctanoic acid methyl ester

D

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methyl 3-hydroxyhexanoate

E

62675-82-5

methyl 3-hydroxydecanoate

F

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β-hydroxydodecanoic acid methyl ester

G

55682-83-2

(+/-)-3-hydroxytetradecanoic acid methyl ester

Conditions
ConditionsYield
Product distribution / selectivity;
...Expand
polyhydroxyalkanoate

polyhydroxyalkanoate

A

C13H15FO4

B

1487-49-6

3-hydroxybutyric acid methyl ester

C

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3-hydroxyoctanoic acid methyl ester

D

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methyl 3-hydroxyhexanoate

E

62675-82-5

methyl 3-hydroxydecanoate

F

15889-95-9

methyl 3-hydroxyheptanoate

G

83968-06-3

methyl 3-hydroxy-nonanoate

H

72864-23-4

β-hydroxydodecanoic acid methyl ester

I

55682-83-2

(+/-)-3-hydroxytetradecanoic acid methyl ester

Conditions
ConditionsYield
Product distribution / selectivity;
...Expand
Raw Materials
62673-11-4
3867-67-2
88222-72-4
22348-97-6
143-07-7
112-16-3
112-54-9
96-32-2
Downstream Products
28715-21-1
1961-72-4
35683-15-9
76835-67-1
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