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CAS No.: | 55682-83-2 |
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Name: | METHYL 3-HYDROXYTETRADECANOATE |
Article Data: | 8 |
Cas Database | |
Molecular Structure: | |
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Formula: | C15H30 O3 |
Molecular Weight: | 258.401 |
Synonyms: | (?à)-Methyl 3-Hydroxytetradecanoate;Methyl 3-hydroxytetradecanoate |
Density: | 0.931g/cm3 |
Boiling Point: | 359.1°Cat760mmHg |
Flash Point: | 137.5°C |
PSA: | 46.53000 |
LogP: | 3.83130 |
methyl 3-oxotetradecanoate
(+/-)-3-hydroxytetradecanoic acid methyl ester
Conditions | Yield |
---|---|
With sodium tetrahydroborate In methanol at 0℃; | 86% |
With sodium tetrahydroborate In methanol at 5 - 10℃; for 2h; | |
With sodium tetrahydroborate In tetrahydrofuran; methanol |
Dodecanal
bromoacetic acid methyl ester
(+/-)-3-hydroxytetradecanoic acid methyl ester
Conditions | Yield |
---|---|
With zinc In benzene for 2h; Heating; | 82% |
lauric acid
(+/-)-3-hydroxytetradecanoic acid methyl ester
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: tetrahydrofuran / 0 - 20 °C 2: 14.72 g / 72 h / 20 °C 3: 86 percent / sodium borohydride / methanol / 0 °C View Scheme |
N-laurylimidazole
(+/-)-3-hydroxytetradecanoic acid methyl ester
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 14.72 g / 72 h / 20 °C 2: 86 percent / sodium borohydride / methanol / 0 °C View Scheme |
n-dodecanoyl chloride
(+/-)-3-hydroxytetradecanoic acid methyl ester
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: pyridine / CH2Cl2 / 0 deg C, 1 h then r.t., 4 h 2: 3 h / Heating 3: NaBH4 / methanol / 2 h / 5 - 10 °C View Scheme |
3-oxomyristic acid
(+/-)-3-hydroxytetradecanoic acid methyl ester
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 3 h / Heating 2: NaBH4 / methanol / 2 h / 5 - 10 °C View Scheme |
B
3-hydroxybutyric acid methyl ester
C
3-hydroxyoctanoic acid methyl ester
D
methyl 3-hydroxydecanoate
E
β-hydroxydodecanoic acid methyl ester
F
(+/-)-3-hydroxytetradecanoic acid methyl ester
G
3-hydroxy-5-phenyl-pentanoic acid methyl ester
Conditions | Yield |
---|---|
Product distribution / selectivity; |
B
3-hydroxybutyric acid methyl ester
C
3-hydroxyoctanoic acid methyl ester
D
methyl 3-hydroxyhexanoate
E
methyl 3-hydroxydecanoate
F
3-hydroxy valeric acid methyl ester
G
methyl 3-hydroxyheptanoate
H
methyl 3-hydroxy-nonanoate
I
β-hydroxydodecanoic acid methyl ester
J
(+/-)-3-hydroxytetradecanoic acid methyl ester
Conditions | Yield |
---|---|
Product distribution / selectivity; |
B
3-hydroxybutyric acid methyl ester
C
3-hydroxyoctanoic acid methyl ester
D
methyl 3-hydroxyhexanoate
E
methyl 3-hydroxydecanoate
F
β-hydroxydodecanoic acid methyl ester
G
(+/-)-3-hydroxytetradecanoic acid methyl ester
Conditions | Yield |
---|---|
Product distribution / selectivity; |
B
3-hydroxybutyric acid methyl ester
C
3-hydroxyoctanoic acid methyl ester
D
methyl 3-hydroxyhexanoate
E
methyl 3-hydroxydecanoate
F
methyl 3-hydroxyheptanoate
G
methyl 3-hydroxy-nonanoate
H
β-hydroxydodecanoic acid methyl ester
I
(+/-)-3-hydroxytetradecanoic acid methyl ester
Conditions | Yield |
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Product distribution / selectivity; |