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56467-43-7

Basic Information
CAS No.: 56467-43-7
Name: 4-benzoylphenyl 2-methylprop-2-enoate
Article Data: 12
Molecular Structure:
Molecular Structure of 56467-43-7 (4-benzoylphenyl 2-methylprop-2-enoate)
Formula: C17H14O3
Molecular Weight: 266.296
Synonyms: 4-(methacryloyloxy)benzophenone;4-methacryloyloxybenzophenone;
PSA: 43.37000
LogP: 3.39910
Synthetic route
760-93-0

methacryloyl anhydride

1137-42-4

4-Hydroxybenzophenone

56467-43-7

4-hydroxybenzophenone ester of metacrylic acid

Conditions
ConditionsYield
With 2,4-dimethyl-6-tert-butylphenol; sulfuric acid; 4-methoxy-phenol at 90℃; for 6h; Air introduction;99.4%
With sulfuric acid In methanol at 90℃; for 2h; Temperature; Large scale;99.7%
With tempol; 2,4-dimethyl-6-tert-butylphenol; 4-methoxy-phenol; magnesium bromide at 90℃; for 6h; Reagent/catalyst;
1137-42-4

4-Hydroxybenzophenone

920-46-7

Methacryloyl chloride

56467-43-7

4-hydroxybenzophenone ester of metacrylic acid

Conditions
ConditionsYield
In acetone at 0℃;90%
With triethylamine at 0 - 20℃; for 48h;86%
With triethylamine In dichloromethane at 0 - 20℃; for 19h;71.9%
67-56-1

methanol

760-93-0

methacryloyl anhydride

1137-42-4

4-Hydroxybenzophenone

A

80-62-6

methacrylic acid methyl ester

B

56467-43-7

4-hydroxybenzophenone ester of metacrylic acid

Conditions
ConditionsYield
Stage #1: methacryloyl anhydride; 4-Hydroxybenzophenone With 2,4-dimethyl-6-tert-butylphenol; sulfuric acid; 4-methoxy-phenol at 90℃; for 6h; Air introduction;
Stage #2: methanol With sodium hydroxide In water at 60℃; for 1h;
80-62-6

methacrylic acid methyl ester

1137-42-4

4-Hydroxybenzophenone

56467-43-7

4-hydroxybenzophenone ester of metacrylic acid

Conditions
ConditionsYield
With methacryloyl anhydride; 2,4-dimethyl-6-tert-butylphenol; sodium methylate In methanol at 60 - 90℃; for 6h; Reagent/catalyst;1320.4 g
2680-03-7

N,N-Dimethylacrylamide

56467-43-7

4-hydroxybenzophenone ester of metacrylic acid

polymer, Mw 155000 Da, Mw/Mn 2.5; monomer(s): N,N-dimethylacrylamide; 4-methacryloyloxybenzophenone

polymer, Mw 155000 Da, Mw/Mn 2.5; monomer(s): N,N-dimethylacrylamide; 4-methacryloyloxybenzophenone

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In N,N-dimethyl-formamide at 60℃; for 15h;
2680-03-7

N,N-Dimethylacrylamide

56467-43-7

4-hydroxybenzophenone ester of metacrylic acid

polymer, Mw 113000 Da, Mw/Mn 3.3; monomer(s): N,N-dimethylacrylamide; 4-methacryloyloxybenzophenone, 1.0 mol percent

polymer, Mw 113000 Da, Mw/Mn 3.3; monomer(s): N,N-dimethylacrylamide; 4-methacryloyloxybenzophenone, 1.0 mol percent

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In N,N-dimethyl-formamide at 60℃; for 15h;
2680-03-7

N,N-Dimethylacrylamide

56467-43-7

4-hydroxybenzophenone ester of metacrylic acid

polymer, Mw 92800 Da, Mw/Mn 3.0; monomer(s): N,N-dimethylacrylamide; 4-methacryloyloxybenzophenone, 3.6 mol percent

polymer, Mw 92800 Da, Mw/Mn 3.0; monomer(s): N,N-dimethylacrylamide; 4-methacryloyloxybenzophenone, 3.6 mol percent

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In N,N-dimethyl-formamide at 60℃; for 15h;
2680-03-7

N,N-Dimethylacrylamide

56467-43-7

4-hydroxybenzophenone ester of metacrylic acid

polymer, Mw 134000 Da, Mw/Mn 5.4; monomer(s): N,N-dimethylacrylamide; 4-methacryloyloxybenzophenone, 14.3 mol percent

polymer, Mw 134000 Da, Mw/Mn 5.4; monomer(s): N,N-dimethylacrylamide; 4-methacryloyloxybenzophenone, 14.3 mol percent

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In N,N-dimethyl-formamide at 60℃; for 15h;
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