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Basic Information
CAS No.: 5809-08-5
Name: 1,1,3,3-Tetramethylbutyl hydroperoxide
Article Data: 7
Molecular Structure:
Molecular Structure of 5809-08-5 (1,1,3,3-Tetramethylbutyl hydroperoxide)
Formula: C8H18 O2
Molecular Weight: 146.23
Synonyms: 1,1,3,3-Tetramethylbutylhydroperoxide; 2,4,4-Trimethyl-2-hydroperoxypentane; 2,4,4-Trimethyl-2-pentylhydroperoxide; 2-Neopentyl-2-propyl hydroperoxide; Lupersol 215; Perocta H;Trigonox TMBH; Trigonox TMPH; tert-Octyl hydroperoxide
Density: 0.888g/cm3
Boiling Point: 197.7°Cat760mmHg
Flash Point: 73.4°C
Solubility: 2.8g/L at 20℃
PSA: 29.46000
LogP: 2.69080
Related products
Synthetic route
690-37-9

2,4,4-trimethyl-2-pentanol

5809-08-5

1,1,3,3-tetramethylbutyl hydroperoxide

Conditions
ConditionsYield
With sulfuric acid; dihydrogen peroxide In water at 5 - 110℃; for 0.0533333h; Temperature; Flow reactor;76.4%
With dihydrogen peroxide In water
540-84-1

2,2,4-trimethylpentane

5809-08-5

1,1,3,3-tetramethylbutyl hydroperoxide

Conditions
ConditionsYield
With sulfuric acid; dihydrogen peroxide In water
540-84-1

2,2,4-trimethylpentane

A

5809-08-5

1,1,3,3-tetramethylbutyl hydroperoxide

B

1-isopropyl-2,2-dimethyl-propyl hydroperoxide

C

2,2,4-Trimethyl-pent-1-yl-hydroperoxide

D

2,4,4-Trimethyl-pent-1-yl-hydroperoxide

Conditions
ConditionsYield
With dihydrogen peroxide; oxygen; [n-Bu4N]VO3; 2,3,4,5,6-pentachloroaniline In acetonitrile at 50℃; Product distribution; Further Variations:; Reagents; Temperatures;
...Expand
540-84-1

2,2,4-trimethylpentane

A

5857-36-3

2,2,4-trimethylpentanone

B

5809-08-5

1,1,3,3-tetramethylbutyl hydroperoxide

C

1-isopropyl-2,2-dimethyl-propyl hydroperoxide

D

2,4,4-Trimethyl-pent-1-yl-hydroperoxide

Conditions
ConditionsYield
With 2-pyrazylcarboxylic acid; dihydrogen peroxide; [(1,4,7-triazacyclononane-Fe(II))2(O)][(CH3COO)2] In acetonitrile Product distribution; Further Variations:; Catalysts; Reagents;
...Expand
107-39-1

2,4,4-trimethyl-1-pentene

pyridine-BH3

pyridine-BH3

5809-08-5

1,1,3,3-tetramethylbutyl hydroperoxide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 65percent H2O2 / H2O / 0 - 5 °C
2: 50percent H2O2 / H2O
View Scheme
933-40-4

cycloxexanone dimethyl ketal

5809-08-5

1,1,3,3-tetramethylbutyl hydroperoxide

1,1-Bis-(1,1,3,3-tetramethyl-butylperoxy)-cyclohexane

Conditions
ConditionsYield
With toluene-4-sulfonic acid In dimethyl sulfoxide at 20℃; under 15 - 20 Torr;88.3%
933-40-4

cycloxexanone dimethyl ketal

5809-08-5

1,1,3,3-tetramethylbutyl hydroperoxide

1-methoxy-1-(1,1,3,3-tetramethylbutylperoxy)cyclohexane

Conditions
ConditionsYield
With toluene-4-sulfonic acid In dimethyl sulfoxide at 20℃;72.7%
5809-08-5

1,1,3,3-tetramethylbutyl hydroperoxide

690-37-9

2,4,4-trimethyl-2-pentanol

Conditions
ConditionsYield
With sulfuric acid; iron(II) sulfate
Multi-step reaction with 2 steps
1: Py / pyridine
2: CuBr / benzene
View Scheme
5809-08-5

1,1,3,3-tetramethylbutyl hydroperoxide

75-36-5

acetyl chloride

926-13-6

peroxyacetic acid 1,1,3,3-tetramethyl-butyl ester

Conditions
ConditionsYield
With Py In pyridine
558-30-5

2-methyl-1,2-epoxypropane

5809-08-5

1,1,3,3-tetramethylbutyl hydroperoxide

2-Methyl-2-(1,1,3,3-tetramethyl-butylperoxy)-propan-1-ol

Conditions
ConditionsYield
With trifluoroacetic acid In benzene at 35℃; for 0.5h;62 % Chromat.
Downstream Products
22288-41-1
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