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Basic Information
CAS No.: 59-85-8
Name: 4-CHLOROMERCURIBENZOIC ACID
Molecular Structure:
Molecular Structure of 59-85-8 (4-CHLOROMERCURIBENZOIC ACID)
Formula: C7H4 Cl Hg O2 . H
Molecular Weight: 357.159
Synonyms: Mercury,(p-carboxyphenyl)chloro- (8CI); (4-Carboxyphenyl)chloromercury;4-(Chloromercuri)benzoic acid; 4-Carboxyphenylmercuric chloride; NSC 32866;PCMB; p-(Chloromercuri)benzoic acid; p-Carboxyphenylmercuric chloride;p-Chlormercuribenzoic acid; p-Chloromercuric benzoic acid
Density: g/cm3
Melting Point: 287 °C (dec.)(lit.)
Boiling Point: °Cat760mmHg
Flash Point: °C
Appearance: White Solid
Hazard Symbols: T+,N
Risk Codes: R26/27/28; R33
Safety: Poison by intraperitoneal route. See also MERCURY COMPOUNDS, INORGANIC; MERCURY COMPOUNDS, ORGANIC. When heated to decomposition it emits very toxic fumes of Cl− and Hg.
PSA: 37.30000
LogP: 1.24640
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Chemistry

IUPAC Name:  (4-carboxyphenyl)-chloro-mercury
Synonyms of p-Chloromercuric benzoic acid (CAS NO.59-85-8) : (4-Carboxyphenyl)(chloro)mercury ; Benzoic acid, p-(chloromercuri)- ; Mercury, (4-carboxyphenyl)chloro- ; (4-Carboxyphenyl)chloromercury
InChI: InChI=1/C7H5O2.ClH.Hg/c8-7(9)6-4-2-1-3-5-6;;/h2-5H,(H,8,9);1H;/q;;+1/p-1/rC7H5ClHgO2/c8-9-6-3-1-5(2-4-6)7(10)11/h1-4H,(H,10,11)
Product Categories: Aromatics;MTS & Sulfhydryl Active Reagents
CAS NO: 59-85-8
Molecular Formula:C7H5ClHgO2          
Molecular Weight :357.1564               
Molecular Structure :
EINECS: 200-442-6
Melting Point: 287 °C (dec.)(lit.)
Appearance:White Solid

Uses

  p-Chloromercuric benzoic acid (CAS NO.59-85-8) is a useful sulfhydryl reagent that reacts with Histidine 225C, a residue of the NhaA-Na/H Antiporter of Escherichia Coli.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 25mg/kg (25mg/kg)   National Technical Information Service. Vol. AD277-689,

 

Consensus Reports

Reported in EPA TSCA Inventory. Mercury and its compounds are on the Community Right-To-Know List.

Safety Profile

Poison by intraperitoneal route. See also MERCURY COMPOUNDS, INORGANIC; MERCURY COMPOUNDS, ORGANIC. When heated to decomposition it emits very toxic fumes of Cl− and Hg.

Hazard Codes VeryT+DangerousN
Risk Statements 26/27/28-33-50/53
R26/27/28:Very toxic by inhalation, in contact with skin and if swallowed. 
R33:Danger of cumulative effects. 
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements 13-28-36-45-60-61
S13:Keep away from food, drink and animal foodstuffs. 
S28:After contact with skin, wash immediately with plenty of soap-suds. 
S36:Wear suitable protective clothing. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S60:This material and its container must be disposed of as hazardous waste. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR UN 2025 6.1/PG 2
WGK Germany 3
RTECS OV8050000
F 3-8-10
HazardClass 6.1(a)
PackingGroup II

Standards and Recommendations

OSHA PEL: CL 0.1 mg(Hg)/m3 (skin)
ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin); BEI: 35 µg/g creatinine total inorganic mercury in urine preshift; 15 µg/g creatinine total inorganic mercury in blood at end of shift at end of workweek.
DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans
NIOSH REL: (Mercury, Aryl and Inorganic) CL 0.1 mg/m3 (skin)