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632-58-6

Basic Information
CAS No.: 632-58-6
Name: Tetrachlorophthalic acid
Article Data: 22
Molecular Structure:
Molecular Structure of 632-58-6 (Tetrachlorophthalic acid)
Formula: C8H2Cl4O4
Molecular Weight: 303.913
Synonyms: Phthalicacid, tetrachloro- (6CI,7CI,8CI);NSC 193510;Tetrachloro-1,2-benzenedicarboxylic acid;Tetrachlorophthalic acid;
EINECS: 211-181-2
Density: 1.872 g/cm3
Melting Point: 98°C
Boiling Point: 439.1 °C at 760 mmHg
Flash Point: 219.4 °C
Solubility: Sparingly soluble in water
Appearance: colourless crystals
Hazard Symbols: 36/37/38:;
Risk Codes: 36/37/38
Safety: 36/37/39
PSA: 74.60000
LogP: 3.69660
Synthetic route
85-44-9

phthalic anhydride

632-58-6

tetrachlorophthalic acid

Conditions
ConditionsYield
With antimonypentachloride; chlorine at 200℃;
With sulfuric acid; iodine; chlorine at 50 - 60℃; schliesslich bei 200grad;
2234-13-1

octachloronaphthalene

A

632-58-6

tetrachlorophthalic acid

B

58852-12-3

hexachloronaphthoquinone-(1,4)

Conditions
ConditionsYield
With nitric acid at 90℃;
58863-15-3

1,2,3,4,5,6,8-heptachloronaphthalene

A

632-58-6

tetrachlorophthalic acid

B

2,5,6,7,8-pentachloro-[1,4]naphthoquinone

Conditions
ConditionsYield
With nitric acid at 100℃; im geschlossenen Rohr;
With nitric acid at 100℃; im Druckrohr;
67922-25-2

1,2,3,4,5-Pentachloronaphthalene

632-58-6

tetrachlorophthalic acid

Conditions
ConditionsYield
With nitric acid at 180 - 200℃; im geschlossenen Rohr;

2,5,6,7,8-pentachloro-[1,4]naphthoquinone

632-58-6

tetrachlorophthalic acid

Conditions
ConditionsYield
With chromic acid
With nitric acid

2,3,4,5-tetrachloro-6-trichloroacetyl-benzoic acid

632-58-6

tetrachlorophthalic acid

Conditions
ConditionsYield
With sodium hydroxide

2,3,4,5-tetrachloro-6-pentachlorobenzoyl-benzoic acid

A

608-93-5

pentachlorobenzene

B

632-58-6

tetrachlorophthalic acid

Conditions
ConditionsYield
With sulfuric acid at 200 - 250℃;
88-95-9

Phthaloyl dichloride

632-58-6

tetrachlorophthalic acid

Conditions
ConditionsYield
With chlorine; iron at 120 - 170℃;
117-08-8

tetrachlorophthalic anhydride

632-58-6

tetrachlorophthalic acid

Conditions
ConditionsYield
With sodium hydroxide; water for 0.75h; Hydrolysis; Heating;
117-08-8

tetrachlorophthalic anhydride

632-58-6

tetrachlorophthalic acid

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Chemistry

Molecular Formula: C8H2Cl4O4
Molar mass: 303.9111 g/mol
Density: 1.872 g/cm3
Melting point: 98°C
Flash Point: 219.4 °C
Index of Refraction: 1.656
Water solubility: Sparingly soluble
Boiling Point: 439.1 °C at 760 mmHg
Vapour Pressure: 1.73E-08 mmHg at 25°C
Stability: Stable. Incompatible with strong oxidizing agents.
Structure of Tetrachlorophthalic acid(632-58-6):
                               
Synonyms of Tetrachlorophthalic acid(632-58-6): 3,4,5,6-Tetrachlorophthalic acid;Phthalic acid, perchloro-;Phthalic acid, tetrachloro-;1,2-benzenedicarboxylic acid, 3,4,5,6-tetrachloro-
Product Categories of Tetrachlorophthalic acid(632-58-6):Phthalic Acids, Esters and Derivatives

Uses

Tetrachlorophthalic acid(632-58-6) can be used for for medicines', dyes' and other organic synthesis' intermediates.

Toxicity Data With Reference

1. mouse LD50 oral 4640mg/kg (4640mg/kg)  
Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 1, Pg. 283, 1976.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Slightly toxic by ingestion. When heated to decomposition it emits toxic vapors of Cl.
Risk Statements:
36:  Irritating to the eyes
37:  Irritating to the respiratory system
38:  Irritating to the skin
Safety Statements:
36:  Wear suitable protective clothing 
37:  Wear suitable gloves
39:  Wear eye/face protection