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CAS No.: | 63521-90-4 |
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Name: | Acetic acid, (methylthio)-, anhydride |
Article Data: | 3 |
Molecular Structure: | |
Formula: | C6H10O3S2 |
Molecular Weight: | 194.276 |
Synonyms: | (methylthio)acetic anhydride;2-(methylthio)acetic anhydride;methylsulfanyl-acetic acid-anhydride;Acetic acid,(methylthio)-,anhydride;Methylmercapto-essigsaeure-anhydrid; |
PSA: | 93.97000 |
LogP: | 0.78220 |
methylsulfanyl-acetic acid
α-(methylthio)acetic acid anhydride
Conditions | Yield |
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With acetic anhydride for 4h; Dehydration; acylation; Heating; | 84% |
With dicyclohexyl-carbodiimide In diethyl ether for 24h; Inert atmosphere; |
α-(methylthio)acetic acid anhydride
11β,21-dihydroxy-6α-methyl-17α-(methylthio)acetoxy-1,4-pregnadiene-3,20-dione
11β-hydroxy-6α-methyl-17α-21-bis<(methylthio)acetoxy>-1,4-pregnadiene-3,20-dione
Conditions | Yield |
---|---|
With triethylamine In dichloromethane for 5h; Ambient temperature; | 77% |
(OC-6-43)-amminedichloro(cyclohexanamine)dihydroxyplatinum(IV)
α-(methylthio)acetic acid anhydride
(OC-6-43)-amminedichloro(cyclohexanamine)bis((methylthio)acetato-O)platinum(IV)
Conditions | Yield |
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In diethyl ether; dichloromethane excess of anhydride, stirring in CH2Cl2/Et2O=4:1 for 24 h; pptn. on Et2O addn. (stirring), collection, drying (vac.); elem. anal.; | 73% |
α-(methylthio)acetic acid anhydride
(1-Phenethyl-piperidin-4-yl)-phenyl-amine
N-(1-(2-phenylethyl)-4-piperidinyl)-2-(methylthio)acetanilide
Conditions | Yield |
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In benzene Heating; | 70% |
α-(methylthio)acetic acid anhydride
3-<2-(3,4-Dimethoxyphenyl)ethylamino>-2-cyclohexen-1-on
N-<2-(3,4-dimethoxyphenyl)ethyl>-N-(3-oxo-1-cyclohexen-1-yl)-α-(methylthio)acetamide
Conditions | Yield |
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With pyridine at 70 - 80℃; for 1h; | 60% |
α-(methylthio)acetic acid anhydride
3-<3-(3,4-dimethoxyphenyl)propylamino>-2-cyclohexen-1-one
N-<3-(3,4-dimethoxyphenyl)propyl>-N-(3-oxo-1-cyclohexen-1-yl)-α-(methylthio)acetamide
Conditions | Yield |
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With pyridine at 70 - 80℃; for 1h; | 57% |
α-(methylthio)acetic acid anhydride
5,5-dimethyl-3-(phenylamino)cyclohex-2-en-1-one
N-(5,5-dimethyl-3-oxo-1-cyclohexen-1-yl)-N-phenyl-α-(methylthio)acetamide
Conditions | Yield |
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With pyridine at 160℃; for 1h; | 54% |
α-(methylthio)acetic acid anhydride
Conditions | Yield |
---|---|
In tetrahydrofuran Ambient temperature; | 54% |
α-(methylthio)acetic acid anhydride
acetic acid 5-oxo-2,5-dihydro-1H-pyrrol-2-yl ester
Conditions | Yield |
---|---|
With pyridine; dmap at 20℃; Acylation; | 53% |
α-(methylthio)acetic acid anhydride
N-cyclohexylidene-2-(3,4-dimethoxyphenyl)ethylamine
N-(cyclohex-1-enyl)-N-<2-(3,4-dimethoxyphenyl)ethyl>-α-(methylthio)acetamide
Conditions | Yield |
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In pyridine | 46% |
In pyridine | |
With pyridine In benzene 0 deg C to room temp. overnight; Yield given; |