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6705-03-9

Basic Information
CAS No.: 6705-03-9
Name: Benzoic acid,2-amino-5-methoxy-
Article Data: 47
Cas Database
Molecular Structure:
Molecular Structure of 6705-03-9 (Benzoic acid,2-amino-5-methoxy-)
Formula: C8H9NO3
Molecular Weight: 167.164
Synonyms: Anthranilicacid, 5-methoxy- (4CI);m-Anisic acid, 6-amino- (6CI,7CI,8CI);5-Methoxy-2-aminobenzoic acid;5-Methoxyanthranilic acid;6-Amino-m-anisic acid;NSC 126996;
EINECS: N/A
Density: 1.303 g/cm3
Melting Point: 148-152 °C
Boiling Point: 349.9 °C at 760 mmHg
Flash Point: 165.4 °C
Solubility: N/A
Appearance: white to light yellow crystal powder
Hazard Symbols: HarmfulXn, IrritantXi
Risk Codes: 22-36/37/38-20/21/22
Safety: 26-36/37/39-36
Transport Information: N/A
PSA: 72.55000
LogP: 1.55680
Synthetic route
1882-69-5

5-methoxy-2-nitro-benzoic acid

6705-03-9

2-Amino-5-methoxybenzoic acid

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In methanol at 20℃; for 24h;100%
With hydrogen; palladium on activated charcoal In methanol at 20℃; for 24h;100%
With 5%-palladium/activated carbon; hydrogen In methanol under 775.743 Torr; for 15h; Inert atmosphere;100%
2475-80-1

methyl 2-amino-5-methoxybenzoate

6705-03-9

2-Amino-5-methoxybenzoic acid

Conditions
ConditionsYield
With lithium hydroxide In tetrahydrofuran; methanol; water at 20℃;99%
1006-94-6

5-methoxylindole

6705-03-9

2-Amino-5-methoxybenzoic acid

Conditions
ConditionsYield
Stage #1: 5-methoxylindole With bromamine B; sodium hydroxide; palladium dichloride In water; acetonitrile at 60℃; for 3.33333h; pH=12;
Stage #2: In water Acidic conditions;
96%
With ruthenium trichloride; osmium(VIII) oxide; bromamine B; sodium hydroxide In water; acetonitrile at 39.84℃; for 4.5h;96%
100174-55-8

5,5′-dimethoxyindigo

6705-03-9

2-Amino-5-methoxybenzoic acid

Conditions
ConditionsYield
Stage #1: 5,5′-dimethoxyindigo With bromamine B; sodium hydroxide; palladium dichloride In water; acetonitrile at 60℃; for 2.16667h; pH=12;
Stage #2: In water Acidic conditions;
96%
180690-91-9

2-(3,3-Dimethyl-ureido)-5-methoxy-benzoic acid methyl ester

6705-03-9

2-Amino-5-methoxybenzoic acid

Conditions
ConditionsYield
With hydrogenchloride at 100℃; for 24h;89%
6335-41-7

2-hydroxyimino-N-(4-methoxyphenyl)acetamide

6705-03-9

2-Amino-5-methoxybenzoic acid

Conditions
ConditionsYield
With sulfuric acid Behandeln des erhaltenen 5-Methoxy-isatins mit wss. Natronlauge und wss. Wasserstoffperoxid;
101351-28-4

6-methoxy-3-(4-methoxy-phenyl)-1H-quinazoline-2,4-dione

6705-03-9

2-Amino-5-methoxybenzoic acid

Conditions
ConditionsYield
With sodium hydroxide
1882-71-9

2-amino-5-methoxybenzamide

6705-03-9

2-Amino-5-methoxybenzoic acid

Conditions
ConditionsYield
With potassium hydroxide Hydrolysis;
38985-80-7

2-(acetylamino)-5-methoxybenzoic acid

6705-03-9

2-Amino-5-methoxybenzoic acid

Conditions
ConditionsYield
With hydrogenchloride
With sodium hydroxide
201230-82-2

carbon monoxide

79069-37-7

1-(acetamino)-2-bromo-4-methoxybenzene

6705-03-9

2-Amino-5-methoxybenzoic acid

Conditions
ConditionsYield
With sodium hydroxide; tributyl-amine; water; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride 1) 110-125 deg C, 2-3 atm, 7 h, 2) H2O, EtOH, 95 deg C, 18 h; Yield given. Multistep reaction;
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Chemistry

IUPAC Name: 2-Amino-5-methoxybenzoic acid 
Molecular Formula: C8H9NO3
Molecular Weight: 167.162g/mol
Density: 1.303 g/cm3 
Melting Point: 150-152°C
Boiling Point: 349.9 °C at 760 mmHg
Flash Point: 165.4 °C
Freely Rotating Bonds: 3 
Polar Surface Area: 38.77Å2 
Index of Refraction: 1.603 
Molar Refractivity: 44.09 cm3 
Molar Volume: 128.2 cm3 
Polarizability: 17.48 ×10-24 cm3 
Surface Tension: 56.6 dyne/cm 
Enthalpy of Vaporization: 62.73 kJ/mol 
Vapour Pressure: 1.71E-05 mmHg at 25°C
  2-Amino-5-methoxybenzoic acid ,its Cas Register Number is 6705-03-9.The chemical synonyms of 2-Amino-5-methoxybenzoic acid (CAS No.6705-03-9) are  2-Amino-5-methoxybenzoic acid ; 5-Methoxyanthranilic acid ; 5-Methoxyanththranillic acid ; 2-Amino-5-methoxylbenzoic acid ; 2-Amino-5-MethoxybenzoicAcid98% ; 2-Amino-5-Methoxybenzoic .Product categories of 2-Amino-5-methoxybenzoic acid (CAS No.6705-03-9) are Aromatic Carboxylic acids, amides, anilides,anhydrides & salts ; Carboxylic acids ; Phenyls & phenyl-het ; Organic acids ; Carboxylic acids ; Phenyls & phenyl-het ; Aromatic amino acids ; Peptide synthesis ; Unnatural amino acid derivatives .The molecular structure of 2-Amino-5-methoxybenzoic acid (CAS No.6705-03-9) is .

Uses

It is used in organic synthesis.

Safety Profile

Hazard Codes:  HarmfulXn,Xi
Xn:  Harmful
Xi:  Irritant
Risk Statements:  22-36/37/38-20/21/22
22:  Harmful if swallowed
36/37/38:  Irritating to eyes, respiratory system and skin
20/21/22:  Harmful by inhalation, in contact with skin and if swallowed
Safety Statements:  26-36/37/39-36
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice  
36:  Wear suitable protective clothing
36/37/39:  Wear suitable protective clothing, gloves and eye/face protection